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Title: Negative thermal quenching of photoluminescence in a copper–organic framework emitter

Abstract

This work reports the observation of the NTQ effect in a copper–organic framework emitter through delocalization–localization transition of its imidazole ligand.

Authors:
 [1];  [2]; ORCiD logo [3];  [1];  [1];  [1];  [3];  [1];  [2];  [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]
  1. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University, Changzhou
  2. Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, Synergetic Innovation Center of Quantum Information & Quantum Physics, University of Science and Technology of China, Hefei
  3. Interdisciplinary Center for Nanotoxicity, Department of Chemistry and Biochemistry, Jackson State University, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1658989
Grant/Contract Number:  
SC0018322
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 56 Journal Issue: 80; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Wu, Ting, Jiang, Shenlong, Samanta, Pabitra Narayan, Xie, Yangbin, Li, Jipeng, Wang, Xiaoling, Devashis, Majumdar, Gu, Xiangwei, Wang, Yusong, Huang, Wei, Zhang, Qun, Leszczynski, Jerzy, and Wu, Dayu. Negative thermal quenching of photoluminescence in a copper–organic framework emitter. United Kingdom: N. p., 2020. Web. doi:10.1039/D0CC04788K.
Wu, Ting, Jiang, Shenlong, Samanta, Pabitra Narayan, Xie, Yangbin, Li, Jipeng, Wang, Xiaoling, Devashis, Majumdar, Gu, Xiangwei, Wang, Yusong, Huang, Wei, Zhang, Qun, Leszczynski, Jerzy, & Wu, Dayu. Negative thermal quenching of photoluminescence in a copper–organic framework emitter. United Kingdom. doi:10.1039/D0CC04788K.
Wu, Ting, Jiang, Shenlong, Samanta, Pabitra Narayan, Xie, Yangbin, Li, Jipeng, Wang, Xiaoling, Devashis, Majumdar, Gu, Xiangwei, Wang, Yusong, Huang, Wei, Zhang, Qun, Leszczynski, Jerzy, and Wu, Dayu. Fri . "Negative thermal quenching of photoluminescence in a copper–organic framework emitter". United Kingdom. doi:10.1039/D0CC04788K.
@article{osti_1658989,
title = {Negative thermal quenching of photoluminescence in a copper–organic framework emitter},
author = {Wu, Ting and Jiang, Shenlong and Samanta, Pabitra Narayan and Xie, Yangbin and Li, Jipeng and Wang, Xiaoling and Devashis, Majumdar and Gu, Xiangwei and Wang, Yusong and Huang, Wei and Zhang, Qun and Leszczynski, Jerzy and Wu, Dayu},
abstractNote = {This work reports the observation of the NTQ effect in a copper–organic framework emitter through delocalization–localization transition of its imidazole ligand.},
doi = {10.1039/D0CC04788K},
journal = {ChemComm},
issn = {1359-7345},
number = 80,
volume = 56,
place = {United Kingdom},
year = {2020},
month = {10}
}

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Works referenced in this record:

A zero-thermal-quenching phosphor
journal, February 2017

  • Kim, Yoon Hwa; Arunkumar, Paulraj; Kim, Bo Young
  • Nature Materials, Vol. 16, Issue 5
  • DOI: 10.1038/nmat4843

Luminescence Temperature Antiquenching of Water-Soluble CdTe Quantum Dots:  Role of the Solvent
journal, August 2004

  • Wuister, Sander F.; de Mello Donegá, Celso; Meijerink, Andries
  • Journal of the American Chemical Society, Vol. 126, Issue 33
  • DOI: 10.1021/ja048222a

Temperature dependence of luminescence from Cu(NN)2+ systems in fluid solution. Evidence for the participation of two excited states
journal, August 1983

  • Kirchhoff, Jon R.; Gamache, Roland E.; Blaskie, Marcus W.
  • Inorganic Chemistry, Vol. 22, Issue 17
  • DOI: 10.1021/ic00159a008

The triplet state of organo-transition metal compounds. Triplet harvesting and singlet harvesting for efficient OLEDs
journal, November 2011

  • Yersin, Hartmut; Rausch, Andreas F.; Czerwieniec, Rafał
  • Coordination Chemistry Reviews, Vol. 255, Issue 21-22
  • DOI: 10.1016/j.ccr.2011.01.042

Copper(I) Complexes for Thermally Activated Delayed Fluorescence: From Photophysical to Device Properties
journal, April 2016

  • Leitl, Markus J.; Zink, Daniel M.; Schinabeck, Alexander
  • Topics in Current Chemistry, Vol. 374, Issue 3
  • DOI: 10.1007/s41061-016-0019-1

Highly efficient organic light-emitting diodes from delayed fluorescence
journal, December 2012

  • Uoyama, Hiroki; Goushi, Kenichi; Shizu, Katsuyuki
  • Nature, Vol. 492, Issue 7428
  • DOI: 10.1038/nature11687

Highly Efficient Luminescence of Cu(I) Compounds: Thermally Activated Delayed Fluorescence Combined with Short-Lived Phosphorescence
journal, January 2015

  • Hofbeck, Thomas; Monkowius, Uwe; Yersin, Hartmut
  • Journal of the American Chemical Society, Vol. 137, Issue 1
  • DOI: 10.1021/ja5109672

Highly efficient thermally activated fluorescence of a new rigid Cu(i) complex [Cu(dmp)(phanephos)]+
journal, January 2013

  • Czerwieniec, Rafał; Kowalski, Konrad; Yersin, Hartmut
  • Dalton Transactions, Vol. 42, Issue 27
  • DOI: 10.1039/c3dt51006a

Direct observation of intersystem crossing in a thermally activated delayed fluorescence copper complex in the solid state
journal, January 2016

  • Bergmann, Larissa; Hedley, Gordon J.; Baumann, Thomas
  • Science Advances, Vol. 2, Issue 1
  • DOI: 10.1126/sciadv.1500889

Bridging the Efficiency Gap: Fully Bridged Dinuclear Cu(I)-Complexes for Singlet Harvesting in High-Efficiency OLEDs
journal, March 2015

  • Volz, Daniel; Chen, Ying; Wallesch, Manuela
  • Advanced Materials, Vol. 27, Issue 15
  • DOI: 10.1002/adma.201405897

Temperature dependence of the photoluminescence emission from thiol-capped PbS quantum dots
journal, March 2007

  • Turyanska, L.; Patanè, A.; Henini, M.
  • Applied Physics Letters, Vol. 90, Issue 10
  • DOI: 10.1063/1.2711529

Exciton–phonon scattering and nonradiative relaxation of excited carriers in hydrothermally synthesized CdTe quantum dots
journal, January 2015

  • Jagtap, Amardeep M.; Khatei, Jayakrishna; Koteswara Rao, K. S. R.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 41
  • DOI: 10.1039/C5CP04654H

Negative Thermal Quenching of Efficient White‐Light Emission in a 1D Ladder‐Like Organic/Inorganic Hybrid Material
journal, July 2019

  • Barkaoui, Hamdi; Abid, Haitham; Zelewski, Szymon
  • Advanced Optical Materials, Vol. 7, Issue 20
  • DOI: 10.1002/adom.201900763

Negative thermal quenching of photoluminescence in ZnO
journal, April 2006


Blue-Light Emission of Cu(I) Complexes and Singlet Harvesting
journal, September 2011

  • Czerwieniec, Rafał; Yu, Jiangbo; Yersin, Hartmut
  • Inorganic Chemistry, Vol. 50, Issue 17
  • DOI: 10.1021/ic200811a

Temperature Antiquenching of the Luminescence from Capped CdSe Quantum Dots
journal, June 2004

  • Wuister, Sander F.; van Houselt, Arie; de Mello Donegá, Celso
  • Angewandte Chemie International Edition, Vol. 43, Issue 23
  • DOI: 10.1002/anie.200353532

Rational Design of Strongly Blue-Emitting Cuprous Complexes with Thermally Activated Delayed Fluorescence and Application in Solution-Processed OLEDs
journal, September 2013

  • Chen, Xu-Lin; Yu, Rongmin; Zhang, Qi-Kai
  • Chemistry of Materials, Vol. 25, Issue 19
  • DOI: 10.1021/cm4024309

Light-Emitting Self-Assembled Materials Based on d 8 and d 10 Transition Metal Complexes
journal, July 2015


Simple and extremely efficient blue emitters based on mononuclear Cu( i )-halide complexes with delayed fluorescence
journal, January 2014

  • Ohara, Hiroki; Kobayashi, Atsushi; Kato, Masako
  • Dalton Trans., Vol. 43, Issue 46
  • DOI: 10.1039/C4DT02709D

Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime
journal, February 2019


High-performance light-emitting diodes based on carbene-metal-amides
journal, March 2017


Analysis of the Effects of N -Substituents on Some Aspects of the Aromaticity of Imidazoles and Pyrazoles
journal, August 2011

  • Curutchet, Carles; Poater, Jordi; Solà, Miquel
  • The Journal of Physical Chemistry A, Vol. 115, Issue 30
  • DOI: 10.1021/jp204263p

Bright Coppertunities: Multinuclear Cu I Complexes with N-P Ligands and Their Applications
journal, April 2014

  • Wallesch, Manuela; Volz, Daniel; Zink, Daniel M.
  • Chemistry - A European Journal, Vol. 20, Issue 22
  • DOI: 10.1002/chem.201402060

Temperature-Dependent Photoluminescence of CdSe-Core CdS/CdZnS/ZnS-Multishell Quantum Dots
journal, July 2009

  • Jing, Pengtao; Zheng, Jinju; Ikezawa, Micho
  • The Journal of Physical Chemistry C, Vol. 113, Issue 31
  • DOI: 10.1021/jp902080p

E-Type Delayed Fluorescence of a Phosphine-Supported Cu 2 (μ-NAr 2 ) 2 Diamond Core: Harvesting Singlet and Triplet Excitons in OLEDs
journal, July 2010

  • Deaton, Joseph C.; Switalski, Steven C.; Kondakov, Denis Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 27
  • DOI: 10.1021/ja1004575

Phosphorescence versus Thermally Activated Delayed Fluorescence. Controlling Singlet–Triplet Splitting in Brightly Emitting and Sublimable Cu(I) Compounds
journal, October 2014

  • Leitl, Markus J.; Krylova, Valentina A.; Djurovich, Peter I.
  • Journal of the American Chemical Society, Vol. 136, Issue 45
  • DOI: 10.1021/ja508155x

Simple Cu(I) Complexes with Unprecedented Excited-State Lifetimes
journal, January 2002

  • Cuttell, Douglas G.; Kuang, Shan-Ming; Fanwick, Phillip E.
  • Journal of the American Chemical Society, Vol. 124, Issue 1
  • DOI: 10.1021/ja012247h

Cu(I) complexes – Thermally activated delayed fluorescence. Photophysical approach and material design
journal, October 2016

  • Czerwieniec, Rafał; Leitl, Markus J.; Homeier, Herbert H. H.
  • Coordination Chemistry Reviews, Vol. 325
  • DOI: 10.1016/j.ccr.2016.06.016

Core-dependent properties of copper nanoclusters: valence-pure nanoclusters as NIR TADF emitters and mixed-valence ones as semiconductors
journal, January 2019

  • Zhang, Leon Li-Min; Zhou, Guodong; Zhou, Guoqing
  • Chemical Science, Vol. 10, Issue 43
  • DOI: 10.1039/C9SC03455B

New copper(I) iodides with bisimidazole molecules: Synthesis, structural characterization and photoluminescence property
journal, July 2017