Effect of Block Length and Side Chain Length Ratios on Determining a Multicompartment Micelle Structure

Callaway, Connor P.; Lee, Seung Min; Mallard, Mackenzie; Clark, Benjamin; Jang, Seung Soon

doi:10.1021/acs.jpcb.9b02231

Title: Effect of Block Length and Side Chain Length Ratios on Determining a Multicompartment Micelle Structure

Journal Article · Mon May 13 00:00:00 EDT 2019 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry

DOI:https://doi.org/10.1021/acs.jpcb.9b02231· OSTI ID:1657069

Callaway, Connor P. ^[1]; Lee, Seung Min ^[1]; Mallard, Mackenzie ^[1]; Clark, Benjamin ^[1];

^[1]

Georgia Institute of Technology, Atlanta, GA (United States)

Previous work has identified the importance of the lipophilic-fluorophilic block length ratio R_l in predicting the morphology of linear lipophilic-hydrophilic-fluorophilic (hereafter referred to as BAC) micelle systems. Here, a generalized form R of this structural parameter is developed that makes no assumption of BAC triblock copolymer linearity, while still providing accurate predictions of micelle morphology. Here, the morphologies of BAC micelles formed by triblock copolymers with R <<1 or R >>1 have similar features, with the only notable difference being an inversion of the lipophilic and fluorophilic regions. A destabilization of the single-core micelle structure occurs as R approaches unity from either direction. Finally, the extent to which micelle morphology depends on polymer architecture instead of composition alone is examined, with decreased patchiness observed in BAC systems with very long block lengths. Through modification of both the R-value and the polymer architecture, the micelle morphology can be effectively tuned for use in immobilized catalysis and nanoreactor applications.

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Research Organization:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-03ER15459

OSTI ID:: 1657069

Journal Information:: Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry, Vol. 123, Issue 22; ISSN 1520-6106

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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Multicompartment Micelle
Effect of block length
Side chain length
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Title: Effect of Block Length and Side Chain Length Ratios on Determining a Multicompartment Micelle Structure

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