Three-dimensional deterministic graphene architectures formed using three-dimensional templates

Title: Three-dimensional deterministic graphene architectures formed using three-dimensional templates

Abstract

In one embodiment, a composition of matter includes: a plurality of ligaments each independently comprising one or more layers of graphene; where the plurality of ligaments are arranged according to a deterministic three-dimensional (3D) pattern. In another embodiment, a method of forming a deterministic three-dimensional (3D) architecture of graphene includes: forming or providing a substrate structurally characterized by a predefined 3D pattern; forming one or more layers of metal on surfaces of the substrate; and forming one or more layers of graphene on surfaces of the metal.

Inventors:: Ye, Jianchao; Biener, Juergen; Campbell, Patrick; Chen, Wen; Jackson, Julie A.; Moran, Bryan D.; Oakdale, James; Smith, William; Spadaccini, Christopher; Worsley, Marcus A.; Zheng, Xiaozhen

Publication Date:: 2020-05-12

Research Org.:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1650884

Patent Number(s):: 10,647,580

Application Number:: 15/417,134

Assignee:: Lawrence Livermore National Security, LLC (Livermore, CA)

DOE Contract Number:: AC52-07NA27344

Resource Type:: Patent

Resource Relation:: Patent File Date: 01/26/2017

Country of Publication:: United States

Language:: English

Citation Formats


                    Ye, Jianchao, Biener, Juergen, Campbell, Patrick, Chen, Wen, Jackson, Julie A., Moran, Bryan D., Oakdale, James, Smith, William, Spadaccini, Christopher, Worsley, Marcus A., and Zheng, Xiaozhen. Three-dimensional deterministic graphene architectures formed using three-dimensional templates.  United States: N. p., 2020. 
        Web.

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                    Ye, Jianchao, Biener, Juergen, Campbell, Patrick, Chen, Wen, Jackson, Julie A., Moran, Bryan D., Oakdale, James, Smith, William, Spadaccini, Christopher, Worsley, Marcus A., & Zheng, Xiaozhen. Three-dimensional deterministic graphene architectures formed using three-dimensional templates.  United States.

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                    Ye, Jianchao, Biener, Juergen, Campbell, Patrick, Chen, Wen, Jackson, Julie A., Moran, Bryan D., Oakdale, James, Smith, William, Spadaccini, Christopher, Worsley, Marcus A., and Zheng, Xiaozhen. Tue .  
        "Three-dimensional deterministic graphene architectures formed using three-dimensional templates".  United States.  https://www.osti.gov/servlets/purl/1650884.

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@article{osti_1650884,

  title        = {Three-dimensional deterministic graphene architectures formed using three-dimensional templates},

  author       = {Ye, Jianchao and Biener, Juergen and Campbell, Patrick and Chen, Wen and Jackson, Julie A. and Moran, Bryan D. and Oakdale, James and Smith, William and Spadaccini, Christopher and Worsley, Marcus A. and Zheng, Xiaozhen},

  abstractNote = {In one embodiment, a composition of matter includes: a plurality of ligaments each independently comprising one or more layers of graphene; where the plurality of ligaments are arranged according to a deterministic three-dimensional (3D) pattern. In another embodiment, a method of forming a deterministic three-dimensional (3D) architecture of graphene includes: forming or providing a substrate structurally characterized by a predefined 3D pattern; forming one or more layers of metal on surfaces of the substrate; and forming one or more layers of graphene on surfaces of the metal.},

  doi          = {},

  url          = {https://www.osti.gov/biblio/1650884},
  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {5}

}

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Works referenced in this record:

Patterned structures of graphene and graphitic carbon and methods for their manufacture
patent, January 2017

Polsky, Ronen; Xiao, Xiaoyin; Burckel, David Bruce
US Patent Document 9,533,887
https://doi.org/http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=9533887

System and method for 3D printing of aerogels
patent, March 2016

Worsley, Marcus A.; Duoss, Eric B.; Kuntz, Joshua D.
US Patent Document 9,278,465
https://doi.org/http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=9278465

Direct growth of graphene films on non-catalyst surfaces
patent-application, May 2014

Tour, James; Yan, Zheng; Peng, Zhiwei
US Patent Application 14/113856; 20140120270
https://doi.org/http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220140120270%22.PGNR.&OS=DN/20140120270&RS=DN/20140120270

Reticulated and controlled porosity battery structures
patent, August 2010

Chiang, Yet-Ming; Hellweg, Benjamin
US Patent Document 7,781,098
https://doi.org/http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=7781098

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Title: Three-dimensional deterministic graphene architectures formed using three-dimensional templates

Abstract

Citation Formats

Patterned structures of graphene and graphitic carbon and methods for their manufacture patent, January 2017

System and method for 3D printing of aerogels patent, March 2016

Direct growth of graphene films on non-catalyst surfaces patent-application, May 2014

Reticulated and controlled porosity battery structures patent, August 2010

Patterned structures of graphene and graphitic carbon and methods for their manufacture
patent, January 2017

System and method for 3D printing of aerogels
patent, March 2016

Direct growth of graphene films on non-catalyst surfaces
patent-application, May 2014

Reticulated and controlled porosity battery structures
patent, August 2010