Safety enhanced li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting

Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.

Safety enhanced li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting

Patent · 07 January 2020

OSTI ID:1632417

Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.

Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.

View Patent

Research Organization:: PolyPlus Battery Company, Berkeley, CA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: AR0000349

Assignee:: PolyPlus Battery Company (Berkeley, CA)

Patent Number(s):: 10,529,971

Application Number:: 15/487,364

OSTI ID:: 1632417

Country of Publication:: United States

Language:: English

References (38)

The Lithium-Oxygen Battery with Ether-Based Electrolytes Freunberger, Stefan A.; Chen, Yuhui; Drewett, Nicholas E. Angewandte Chemie International Edition, Vol. 50, Issue 37, p. 8609-8613 https://doi.org/10.1002/anie.201102357	journal	July 2011
Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors Choi, Nam-Soon; Chen, Zonghai; Freunberger, Stefan A. Angewandte Chemie International Edition, Vol. 51, Issue 40 https://doi.org/10.1002/anie.201201429	journal	September 2012
Das Design-Desaster Beckham, Barbara working@office, Vol. 11, Issue 1 https://doi.org/10.1007/BF03250200	journal	January 2010
High ionic conductivity in lithium lanthanum titanate Inaguma, Yoshiyuki; Liquan, Chen; Itoh, Mitsuru Solid State Communications, Vol. 86, Issue 10, p. 689-693 https://doi.org/10.1016/0038-1098(93)90841-A	journal	June 1993
Structural disorder and enhanced ion transport in amorphous conductors Button, D. P.; Mason, L. S.; Tuller, H. L. Solid State Ionics, Vol. 9-10, Issue Part 1, p. 585-592 https://doi.org/10.1016/0167-2738(83)90299-0	journal	December 1983
Ionic conductivity and sinterability of lithium titanium phosphate system Aono, Hiromichi; Sugimoto, Eisuke; Sadaoka, Yoshihiko Solid State Ionics, Vol. 40-41, Issue Part 1, p. 38-42 https://doi.org/10.1016/0167-2738(90)90282-V	journal	August 1990
Electrical properties of amorphous lithium electrolyte thin films Bates, J. B.; Dudney, N. J.; Gruzalski, G. R. Solid State Ionics, Vol. 53-56, Issue Part 1, p. 647-654 https://doi.org/10.1016/0167-2738(92)90442-R	journal	July 1992
Sputtering of lithium compounds for preparation of electrolyte thin films Dudney, N. J.; Bates, J. B.; Zuhr, R. A. Solid State Ionics, Vol. 53-56, Issue Part 1, p. 655-661 https://doi.org/10.1016/0167-2738(92)90443-S	journal	July 1992
Electrical properties and crystal structure of solid electrolyte based on lithium hafnium phosphate LiHf₂(PO₄)₃ Aono, Hiromichi; Sugimoto, Eisuke; Sadaoka, Yoshihiko Solid State Ionics, Vol. 62, Issue 3-4, p. 309-316 https://doi.org/10.1016/0167-2738(93)90387-I	journal	August 1993
Thin film rechargeable Li batteries Jones, Steven D.; Akridge, James R.; Shokoohi, Frough K. Solid State Ionics, Vol. 69, Issue 3-4, p. 357-368 https://doi.org/10.1016/0167-2738(94)90423-5	journal	August 1994
Metal/air batteries: Their status and potential — a review Blurton, Keith F.; Sammells, Anthony F. Journal of Power Sources, Vol. 4, Issue 4, p. 263-279 https://doi.org/10.1016/0378-7753(79)80001-4	journal	January 1979
Investigation of a novel aqueous aluminum/sulfur battery Peramunage, Dharmasena; Dillon, Rensl; Licht, Stuart Journal of Power Sources, Vol. 45, Issue 3 https://doi.org/10.1016/0378-7753(93)80020-P	journal	July 1993
Thin-film rechargeable lithium batteries Bates, J. B.; Dudney, N. J.; Lubben, D. C. Journal of Power Sources, Vol. 54, Issue 1, p. 58-62 https://doi.org/10.1016/0378-7753(94)02040-A	journal	March 1995
Secondary Batteries – Metal-air Systems \| Lithium-air Visco, S. J.; Nimon, E.; De Jonghe, L. C. Encyclopedia of Electrochemical Power Sources, p. 376-383 https://doi.org/10.1016/B978-044452745-5.00184-2	book	January 2009
Lithium fuel cells: Urquidi-Macdonald, Mirna; Castaneda, Homero; Cannon, Angela M. Electrochimica Acta, Vol. 47, Issue 15 https://doi.org/10.1016/S0013-4686(02)00109-3	journal	June 2002
All solid-state nickel/metal hydride battery with a proton-conductive phosphoric acid-doped silica gel electrolyte Iwakura, Chiaki; Kumagae, Kiyoshi; Yoshiki, Kazuya Electrochimica Acta, Vol. 48, Issue 11, p. 1499-1503 https://doi.org/10.1016/S0013-4686(03)00032-X	journal	May 2003
All-solid-state lithium secondary battery with ceramic/polymer composite electrolyte Kobayashi, Y. Solid State Ionics, Vol. 152-153 https://doi.org/10.1016/S0167-2738(02)00366-1	journal	December 2002
Superionic conductivity of glass-ceramics in the system Li 2 O- Al 2 O 3 -TiO 2 -P 2 O 5 Fu, Jie Solid State Ionics, Vol. 96, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00018-0	journal	April 1997
Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5 Fu, J. Solid State Ionics, Vol. 104, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00434-7	journal	December 1997
Cultivation of petunia (T Ohtani et al, JP) No authors listed Biofutur, Vol. 1997, Issue 173, p. 40 https://doi.org/10.1016/S0294-3506(97)82201-6	journal	November 1997
Electrochemical behaviour of intermetallic-based metal hydrides used in Ni/metal hydride (MH) batteries: a review Feng, F. International Journal of Hydrogen Energy, Vol. 26, Issue 7 https://doi.org/10.1016/S0360-3199(00)00127-0	journal	July 2001
Chemical stability enhancement of lithium conducting solid electrolyte plates using sputtered LiPON thin films West, W. C.; Whitacre, J. F.; Lim, J. R. Journal of Power Sources, Vol. 126, Issue 1-2, p. 134-138 https://doi.org/10.1016/j.jpowsour.2003.08.030	journal	February 2004
High Li+ Conducting Ceramics Aono, Hiromichi; Imanaka, Nobuhito; Adachi, Gin-ya Accounts of Chemical Research, Vol. 27, Issue 9 https://doi.org/10.1021/ar00045a002	journal	September 1994
Rechargeable Li ₂ O ₂ Electrode for Lithium Batteries Ogasawara, Takeshi; Débart, Aurélie; Holzapfel, Michael Journal of the American Chemical Society, Vol. 128, Issue 4 https://doi.org/10.1021/ja056811q	journal	February 2006
Reactions in the Rechargeable Lithium–O ₂ Battery with Alkyl Carbonate Electrolytes Freunberger, Stefan A.; Chen, Yuhui; Peng, Zhangquan Journal of the American Chemical Society, Vol. 133, Issue 20 https://doi.org/10.1021/ja2021747	journal	May 2011
Commentary Erkmen, Kadir; Al-Mefty, Ossama Skull Base, Vol. 16, Issue 2 https://doi.org/10.1055/s-2006-934105	journal	April 2006
Novel Fast Lithium Ion Conduction in Garnet-Type Li ₅ La ₃ M ₂ O ₁₂ (M = Nb, Ta) Thangadurai, Venkataraman; Kaack, Heiko; Weppner, Werner J. F. Journal of the American Ceramic Society, Vol. 86, Issue 3 https://doi.org/10.1111/j.1151-2916.2003.tb03318.x	journal	March 2003
A Solid Sulfur Cathode for Aqueous Batteries Peramunage, D.; Licht, S. Science, Vol. 261, Issue 5124 https://doi.org/10.1126/science.261.5124.1029	journal	August 1993
Characterization of the Lithium/Oxygen Organic Electrolyte Battery Read, J. Journal of The Electrochemical Society, Vol. 149, Issue 9, p. A1190-A1195 https://doi.org/10.1149/1.1498256	journal	January 2002
A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery Abraham, K. M.; Jiang, Z. Journal of The Electrochemical Society, Vol. 143, Issue 1, p. 1-5 https://doi.org/10.1149/1.1836378	journal	January 1996
Electrochemical Lithium Intercalation in VO ₂ ( B ) in Aqueous Electrolytes Zhang, Meijie; Dahn, J. R. Journal of The Electrochemical Society, Vol. 143, Issue 9, p. 2730-2735 https://doi.org/10.1149/1.1837099	journal	January 1996
A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride Yu, Xiaohua; Bates, J. B.; Jellison, G. E. Journal of The Electrochemical Society, Vol. 144, Issue 2, p. 524-532 https://doi.org/10.1149/1.1837443	journal	January 1997
Lithium-Ion Cells with Aqueous Electrolytes Li, W.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 142, Issue 6, p. 1742-1746 https://doi.org/10.1149/1.2044187	journal	January 1995
Primary Sodium Batteries with Beta-Alumina Solid Electrolyte Will, F. G.; Mitoff, S. P. Journal of The Electrochemical Society, Vol. 122, Issue 4, p. 457-461 https://doi.org/10.1149/1.2134239	journal	January 1975
Water Durable Lithium Ion Conducting Composite Membranes from the Li[sub 2]O-Al[sub 2]O[sub 3]-TiO[sub 2]-P[sub 2]O[sub 5] Glass-Ceramic Thokchom, Joykumar S.; Kumar, Binod Journal of The Electrochemical Society, Vol. 154, Issue 4 https://doi.org/10.1149/1.2452822	journal	January 2007
Electrical Properties of Sintered Lithium Titanium Phosphate Ceramics (Li_1+XM_XTi_2−X(PO₄)₃, M³⁺= Al³⁺, Sc³⁺, or Y³⁺) Aono, Hiromichi; Sugimoto, Eisuke; Sadaoka, Yoshihiko Chemistry Letters, Vol. 19, Issue 10 https://doi.org/10.1246/cl.1990.1825	journal	October 1990
Ionic Conductivity of LiTi ₂ (PO ₄ ) ₃ Mixed with Lithium Salts Aono, Hiromichi; Sugimoto, Eisuke; Sadaoka, Yoshihiko Chemistry Letters, Vol. 19, Issue 3 https://doi.org/10.1246/cl.1990.331	journal	March 1990
DC Conductivity of Li _1.3 Al _0.3 Ti _1.7 (P ₄ ) ₃ Ceramic with Li Electrodes Aono, Hiromichi; Sugimoto, Eisuke; Sadaoka, Yoshihiko Chemistry Letters, Vol. 20, Issue 9 https://doi.org/10.1246/cl.1991.1567	journal	September 1991

Similar Records

Lithium metal—seawater battery cells having protected lithium electrodes

Patent · 2021 · OSTI ID:1805500

Making lithium metal—seawater battery cells having protected lithium electrodes

Patent · 2023 · OSTI ID:1998366

Energy efficient electrolyzer for the production of hydrogen

Patent · 1982 · OSTI ID:6594053

Related Subjects

25 ENERGY STORAGE

Safety enhanced li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting

Citation Formats

References (38)

Similar Records

Related Subjects