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Title: Safety enhanced li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting

Patent ·
OSTI ID:1632417

Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.

Research Organization:
PolyPlus Battery Company, Berkeley, CA (United States)
Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
DOE Contract Number:
AR0000349
Assignee:
PolyPlus Battery Company (Berkeley, CA)
Patent Number(s):
10,529,971
Application Number:
15/487,364
OSTI ID:
1632417
Resource Relation:
Patent File Date: 04/13/2017
Country of Publication:
United States
Language:
English

References (283)

Primary Sodium-Water Battery patent November 1972
Microporous materials incorporating a nucleating agent and methods for making same patent February 1988
Lithium battery having a protected lithium electrode and an ionic liquid catholyte patent September 2014
Use of amorphous carbon to promote adhesion between electroactive polymer films and conductive substrates patent March 1992
Lithium anodes for electrochemical cells patent July 2007
Process for forming an argentic oxide containing bipolar electrode and product produced thereby and deferred actuated battery assembly employing same patent November 1992
Method for forming lithium metal anode protective layer for lithium battery and lithium battery having such protective layer patent December 2004
Cathodes and reservoirs for aqueous lithium/air battery cells patent June 2013
Sputtering of lithium compounds for preparation of electrolyte thin films journal July 1992
Lithium anodes for electrochemical cells patent-application January 2002
Electrochemical device component with protected alkali metal electrode patent December 2010
Continuous consumable anode patent April 1990
Negative active material for rechargeable lithium battery and method of preparing the same patent-application January 2002
Electrochemical behaviour of intermetallic-based metal hydrides used in Ni/metal hydride (MH) batteries: a review journal July 2001
Battery patent-application September 2009
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture patent November 2010
Method and electrode for electrochemical recovery of lithium value from aqueous solution patent March 1993
Catholytes for aqueous lithium/air battery cells patent February 2014
Refuelable electrochemical power source capable of being maintained in a substantially constant full condition and method of using the same patent October 2001
Mixed ionic electronic conductor coatings for redox electrodes patent April 2001
Battery Cells with Lithium Ion Conducting Tape-cast Ceramic, Glass and Glass-ceramic Membranes patent-application November 2015
Method for forming encapsulated lithium electrodes having glass protective layers patent April 2001
Ionic Conductivity of LiTi 2 (PO 4 ) 3 Mixed with Lithium Salts journal March 1990
ELECTROCHEMICAL DEVICE WITH PROTECTIVE MEMBRANE ARCHITECTURE patent-application February 2014
Fluid conduction utilizing a reversible unsaturated siphon with tubarc porosity action patent July 2004
Lithium/air batteries with LiPON as separator and protective barrier and method patent-application May 2005
Microporous sheet material, method of making and articles made therewith patent September 1985
Plating metal negative electrodes under protective coatings patent June 2002
Electrochemical device separator structures with barrier layer on non-swelling membrane patent July 2006
Metal-air battery patent September 1997
Ionically conductive membranes for protection of active metal anodes and battery cells patent-application September 2004
POLYMER COMPOSITIONS BASED ON PXE patent-application March 2013
Rechargeable lithium battery for use in applications requiring a low to high power output patent March 1997
Active metal fuel cells patent August 2011
Electrical properties and crystal structure of solid electrolyte based on lithium hafnium phosphate LiHf2(PO4)3 journal August 1993
Saltwater Battery patent September 1967
Electrochemical Lithium Intercalation in  VO 2 (  B  )  in Aqueous Electrolytes journal January 1996
Sealed lithium electrochemical cell with sodium beta-alumina electrolyte patent May 1978
Sound and heat insulation having little odor patent December 1997
Overcharge protection systems for rechargeable batteries patent March 1999
Solid electrolytes based on lithium hafnium phosphate for active metal anode protection patent-application April 2006
High Li+ Conducting Ceramics journal September 1994
Lithium/air batteries with LiPON as separator and protective barrier and method patent May 2007
Protective composite battery separator and electrochemical device component with red phosphorus patent November 2010
Non-aqueous electrolyte secondary cell patent-application August 2002
Metal-air battery with ion-conducting inorganic glass electrolyte patent-application March 2006
Liquid electrolyte lithium-sulfur batteries patent March 2002
Zinc sulfur battery patent March 2001
Active metal/aqueous electrochemical cells and systems patent-application March 2008
Catholytes for aqueous lithium/air battery cells patent December 2012
Organic phosphate additives for nonaqueous electrolyte in alkali metal electrochemical cells patent May 2000
Protected Lithium Electrodes Based on Ceramic Membranes patent-application September 2014
Electrochemical cell having an electrode with a phosphate additive in the electrode active mixture patent January 2003
Inactive electrochemical cell having an ionically nonconductive polymeric composition activated by electrolyte salt solution patent April 1995
Lithium ion conductive glass-ceramics patent December 1997
Rechargeable positive electrodes patent September 1998
Lithium-water battery patent June 1995
Protective coating for separators for electrochemical cells patent February 2001
Lithium secondary battery patent December 2002
Semiconductor memory drive patent September 1983
Glass-polymer composite electrolyte and a method of preparing the same patent May 2000
Active metal electrolyzer patent October 2009
Coated lithium electrodes patent October 2005
Electrolyte for an electrochemical cell patent January 1997
Phosphonate additives for nonaqueous electrolyte in rechargeable cells patent March 2001
Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors journal September 2012
High capacity/high discharge rate rechargeable positive electrode patent March 2001
Method for making an electrochemical cell patent October 1996
Active metal / aqueous electrochemical cells and systems patent November 2011
Solid gel membrane separator in rechargeable electrochemical cells patent March 2002
Active metal fuel cells patent February 2009
Battery cells with lithium ion conducting tape-cast ceramic, glass and glass-ceramic membranes patent August 2016
Process for producing porous products patent April 1976
Electric cells and gas sensors using alkali ion conductive glass ceramic patent November 2001
Means for improving contact between Li and the anode current collector patent July 1979
Generation of DC Voltage patent October 1971
Electrochemical timer patent March 2001
Solid composite electrolyte membrane and method of making patent-application May 2007
Protected Active Metal Electrode And Battery Cell Structures With Non-Aqueous Interlayer Architecture patent-application January 2015
Ionic conductivity and sinterability of lithium titanium phosphate system journal August 1990
Fuel Cell patent December 1971
Electrolytes with strong oxidizing additives for lithium/sulfur batteries patent October 2003
Lithium/organosulfur redox cell having protective solid electrolyte barrier formed on anode and method of making same patent April 1990
Solid gel membrane separator in electrochemical cells patent-application August 2002
Ionically conductive membranes for protection of active metal anodes and battery cells patent June 2008
Compositions and methods for protection of active metal anodes and polymer electrolytes patent October 2008
Ionically conductive composites for protection of active metal anodes patent-application July 2004
A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride journal January 1997
Ionically conductive composites for protection of active metal anodes patent-application July 2004
Composition useful in electrolytes of secondary battery cells patent October 1999
Moisture-permeable waterproof coated fabric and method of making the same patent January 1984
Reinforced Microporous FIlm patent July 1972
COMPOSITE SOLID ELECTROLYTE FOR PROTECTION OF ACTIVE METAL ANODES patent-application July 2007
Anodization of magnesium and magnesium based alloys patent August 2001
Methods of fabricating rechargeable positive electrodes patent December 1996
Secondary battery patent May 2002
Non-aqueous electrolyte and electrochemical device comprising the same patent-application March 2002
Electrochemically stable cathode patent July 1979
Glass-ceramic composite electrolyte and lithium secondary cell patent November 2002
CATHOLYTES FOR AQUEOUS LITHIUM/AIR BATTERY CELLS patent-application May 2013
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture patent-application August 2005
Alkali metal carbon dioxide electrochemical system for energy storage and/or conversion of carbon dioxide to oxygen patent May 1993
GARNET-TYPE LITHIUM ION-CONDUCTING OXIDE AND ALL-SOLID-STATE LITHIUM ION SECONDARY BATTERY CONTAINING THE SAME patent-application October 2011
Investigation of a novel aqueous aluminum/sulfur battery journal July 1993
Liquid electrolyte lithium-sulfur batteries patent February 2000
Electrical properties of amorphous lithium electrolyte thin films journal July 1992
Bi-Polar Protected Electrodes and Multi-Cell Stacks patent-application November 2014
CATHODES AND RESERVOIRS FOR AQUEOUS LITHIUM/AIR BATTERY CELLS patent-application December 2009
HIGH ENERGY DENSITY AQUEOUS LITHIUM/AIR BATTERY CELLS patent-application December 2009
Separator material for electrochemical cells patent March 1991
Ionically Conductive Membranes For Protection Of Active Metal Anodes And Battery Cells patent-application December 2009
Active Metal Fuel Cells patent-application November 2009
Metal-air battery with improved air supply patent July 1997
Active metal fuel cells patent April 2014
Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5 journal December 1997
A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery journal January 1996
Thin film battery and method for making same patent August 1994
Method for reducing voltage delay in alkali metal electrochemical cells activated with a nonaqueous electrolyte having a phosphate additive patent August 2001
Rechargeable lithium battery for use in applications requiring a low to high power output patent October 1996
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture patent September 2015
Sulfur/aluminum electrochemical batteries patent November 1996
Superionic conductivity of glass-ceramics in the system Li 2 O- Al 2 O 3 -TiO 2 -P 2 O 5 journal April 1997
All-solid-state lithium secondary battery with ceramic/polymer composite electrolyte journal December 2002
Polymer adhesive seals for protected anode architectures patent-application March 2007
Secondary cell using organosulfur/metal charge transfer materials as positive electrode patent May 1996
Ionically conductive composites for protection of active metal anodes patent October 2007
Methods and reagents for enhancing the cycling efficiency of lithium polymer batteries patent January 2000
PROTECTED ACTIVE METAL ELECTRODE AND BATTERY CELL WITH IONICALLY CONDUCTIVE PREOTECTIVE ARCHITECTURE patent-application January 2011
Battery Cell patent September 1971
Coated lithium electrodes patent March 2003
Lithium fuel cells: journal June 2002
Bipolar battery patent November 1992
Aluminum and sulfur electrochemical batteries and cells patent July 1997
Plating metal negative electrodes under protective coatings patent-application November 2001
Cell for making secondary batteries patent November 1992
Treatment of lithium anodes patent September 1983
Dioxolane as a proctector for lithium electrodes patent May 2001
Stabilized anode for lithium-polymer batteries patent July 1997
DC Conductivity of Li 1.3 Al 0.3 Ti 1.7 (P 4 ) 3 Ceramic with Li Electrodes journal September 1991
Active Metal Fuel Cells patent-application January 2014
Batteries patent-application June 2007
Composite Sheet and Production Method Thereof patent-application July 2012
Solid polymer electrolyte composite membrane comprising porous ceramic support patent-application August 2006
Hydrogels for aqueous lithium/air battery cells patent March 2013
Active metal/aqueous electrochemical cells and systems patent February 2010
Metal-sulfur type cell having improved positive electrode patent May 1989
Chemical protection of a lithium surface patent June 2005
Lithium ion conductive solid electrolyte and production process thereof patent-application October 2007
Overcharge protection systems for rechargeable batteries patent June 2001
Methods and reagents for enhancing the cycling efficiency of lithium polymer batteries patent December 2000
Alkali metal battery patent June 1996
Lithium oxygen batteries and method of producing same patent-application September 2005
HIGH RATE SEAWATER ACTIVATED LITHIUM BATTERY CELLS BI-POLAR PROTECTED ELECTRODES AND MULTI-CELL STACKS patent-application November 2011
High ionic conductivity in lithium lanthanum titanate journal June 1993
Porous products and process therefor patent February 1980
Cell comprising an alkali metal and aqueous electrolyte patent February 1977
In Situ Formed Ionically Conductive Membranes For Protection Of Active Metal Anodes And Battery Cells patent-application February 2011
Active metal fuel cells patent August 2010
Negative electrode for solid electrolyte cells patent October 1975
Rechargeable positive electrodes patent November 1997
Water Durable Lithium Ion Conducting Composite Membranes from the Li[sub 2]O-Al[sub 2]O[sub 3]-TiO[sub 2]-P[sub 2]O[sub 5] Glass-Ceramic journal January 2007
Method of making an electrolyte for an electrochemical cell patent April 1996
Rechargeable Li 2 O 2 Electrode for Lithium Batteries journal February 2006
ACTIVE METAL / AQUEOUS ELECTROCHEMICAL CELLS AND SYSTEMS patent-application March 2012
SMALL DOMAIN-SIZE MULTIBLOCK COPOLYMER ELECTROLYTES patent-application October 2013
Layered arrangements of lithium electrodes patent July 2002
Encapsulated lithium alloy electrodes having barrier layers patent July 2002
Renewable, energetic, nanodimensional dispersion patent-application October 2003
Active metal/aqueous electrochemical cells and systems patent January 2010
Method for forming encapsulated lithium electrodes having glass protective layers patent August 2002
High temperature rechargeable molten salt battery patent July 1991
Aluminum and sulfur electrochemical batteries and cells patent May 1995
Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method patent May 1994
Ionically conductive membranes for protection of active metal anodes and battery cells patent-application March 2008
Structural disorder and enhanced ion transport in amorphous conductors journal December 1983
Ionically conductive composites for protection of active metal anodes patent-application March 2008
Protected Lithium Electrodes Having a Porous Electrolyte Interlayer and Associated Battery Cells patent-application December 2016
Stabilized anode for lithium-polymer batteries patent October 1999
Advanced Lithium Ion Batteries Based on Solid State Protected Lithium Electrodes patent-application December 2016
Air-Depolarized Cells Utilizing a Cyanate or Thiocyanate-Containing Electrolyte patent January 1974
Chemical stability enhancement of lithium conducting solid electrolyte plates using sputtered LiPON thin films journal February 2004
Chemical protection of a lithium surface patent-application August 2005
Electra-optical device including a nitrogen containing electrolyte patent October 1995
Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions patent December 1997
Lithium/air batteries with LiPON as separator and protective barrier and method patent March 2008
Liquid fuel cell patent-application February 2002
LI/AIR NON-AQUEOUS BATTERIES patent-application May 2007
Encapsulated alloy electrodes patent January 2006
High Energy Density Vanadium Electrolyte Solutions, Methods of Preparation Thereof and All-Vanadium Redox Cells and Batteries Containing High Energy Vanadium Electrolyte Solutions patent-application October 2001
Composite coating for electrochemical electrode and method patent January 1991
Active Metal Fuel Cells patent-application November 2011
CATHOLYTES FOR AQUEOUS LITHIUM/AIR BATTERY CELLS patent-application December 2009
Parasitic corrosion resistant anode for use in metal/air or metal/O.sub.2 cells patent November 1983
Polysulfide battery patent May 1989
Electrochemical cell and negative electrode therefor patent-application June 2002
Lithium ion conductive solid electrolyte and method for manufacturing the same patent-application April 2007
Das Design-Desaster journal January 2010
Solid electrolyte composite for electrochemical reaction apparatus patent June 2001
Method of preparing electrodes having evenly distributed component mixtures patent August 2000
Organic electrolytic solution and lithium secondary battery employing the same patent-application July 2003
Electrodes for rechargeable lithium batteries patent February 1995
Metal/air batteries: Their status and potential — a review journal January 1979
Magnesium solution phase catholyte seawater electrochemical system patent May 2001
Phosphonate additives for nonaqueous electrolyte in alkali metal electrochemical cells patent August 2000
Phosphonate additives for nonaqueous electrolyte in rechargeable electrochemical cells patent December 2002
HIGH IONIC CONDUCTIVITY ELECTROLYTES FROM BLOCK COPOLYMERS OF GRAFTED POLY(SILOXANES-CO-ETHYLENE OXIDE) patent-application December 2011
Rechargeable positive electrode patent July 1996
Plating metal negative electrodes under protective coatings patent April 2004
Active metal/aqueous electrochemical cells and systems patent June 2012
Commentary journal April 2006
Rechargeable positive electrodes patent August 1998
Protected Active Metal Electrode and Battery Cell Structures with Non-Aqueous Interlayer Architecture patent-application January 2016
Safety enhanced Li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting patent May 2017
Active metal electrolyzer patent-application May 2005
Active metal fuel cells patent-application May 2005
Protected active metal electrode and battery cell structures with non-aqueous interplayer architecture patent-application February 2008
Solid electrolyte and battery employing the same patent-application May 2004
Rechargeable positive electrodes patent April 2002
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture patent October 2007
Battery cells with lithium ion conducting tape-cast ceramic, glass and glass-ceramic membranes patent March 2017
Ionically conductive composites for protection of active metal anodes patent October 2007
Metal-air semi-fuel cell with an aqueous acid based cathode patent-application November 2007
Process for producing permeable membranes patent July 1978
ION CONDUCTIVE LAMINATE AND PRODUCTION METHOD AND USE THEREOF patent-application August 2001
The Lithium-Oxygen Battery with Ether-Based Electrolytes journal July 2011
Electrolyte compositions and methods patent April 1992
Electrochemical cell having an electrode with a phosphonate additive in the electrode active mixture patent March 2003
Substantially impervious lithium super ion conducting membranes patent December 2012
Alkali ion conductive glass-ceramics and electric cells and gas sensors using the same patent May 2007
Electrode protection in both aqueous and non-aqueous electrochemical cells, including rechargeable lithium batteries patent August 2010
Organic/inorganic composite porous film and electrochemical device prepared thereby patent-application March 2006
Active Metal / Aqueous Electrochemical Cells and Systems patent-application April 2010
Long cycle-life alkali metal battery patent March 2001
Novel Fast Lithium Ion Conduction in Garnet-Type Li 5 La 3 M 2 O 12 (M = Nb, Ta) journal March 2003
Solid polymer electrolyte-based oxygen batteries patent April 1996
Molten salt lithium cells patent September 1983
Thin film rechargeable Li batteries journal August 1994
Encapsulated lithium alloy electrodes having barrier layers patent May 2004
Ionically conductive composites for protection of active metal anodes patent-application March 2008
Solid polymer battery electrolyte and reactive metal-water battery patent November 2000
Thermoelectric Device and Method of Manufacture patent September 1970
All solid-state nickel/metal hydride battery with a proton-conductive phosphoric acid-doped silica gel electrolyte journal May 2003
Phosphate additives for nonaqueous electrolyte rechargeable electrochemical cells patent March 2001
CERAMIC MATERIAL AND PREPARATION METHOD THEREFOR patent-application March 2011
Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same patent February 2000
Protected Active Metal Electrodes patent-application July 2017
Forming an impermeable sintered ceramic electrolyte layer on a metallic foil substrate for solid oxide fuel cell patent-application December 2003
Method for electrochemically producing an alkali metal from an aqueous solution patent August 2004
Non-aqueous safe secondary cell patent April 1996
Protected lithium electrodes having a polymer electrolyte interlayer and battery cells thereof patent August 2013
Thin-film rechargeable lithium batteries journal March 1995
Reactions in the Rechargeable Lithium–O 2 Battery with Alkyl Carbonate Electrolytes journal May 2011
Membrane-electrode structure for electrochemical cells patent August 1994
A Solid Sulfur Cathode for Aqueous Batteries journal August 1993
Solid State Battery patent-application April 2012
Battery electrode and manufacturing method thereof patent February 2000
Protective coatings for negative electrodes patent February 2000
Lithium-Ion Cells with Aqueous Electrolytes journal January 1995
Sealed lithium-type electrochemical cell patent July 1980
Lithium ion-conductive solid electrolyte containing lithium titanium phosphate patent January 1991
Lithium peroxide primary element patent March 1985
Integrated battery patent-application September 2004
Manufacturing method for electrode patent March 1994
Electrolyte compositions patent August 1976
Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same patent November 2002
Compliant seal structures for protected active metal anodes patent-application February 2007
HYDROGELS FOR AQUEOUS LITHIUM/AIR BATTERY CELLS patent-application December 2009
Li/Air non-aqueous batteries patent February 2014
Electrolytes with strong oxidizing additives for lithium/sulfur batteries patent-application April 2004
Lithium anodes for electrochemical cells patent May 2004
Ion Conductor Having a Garnet Structure patent-application August 2010
Active metal/aqueous electrochemical cells and systems patent-application October 2004
Characterization of the Lithium/Oxygen Organic Electrolyte Battery journal January 2002
Electrical Properties of Sintered Lithium Titanium Phosphate Ceramics (Li1+XMXTi2−X(PO4)3, M3+= Al3+, Sc3+, or Y3+) journal October 1990
Rechargeable positive electrode patent June 1996
Composite solid electrolyte for protection of active metal anodes patent May 2012
Substantially impervious lithium super ion conducting membranes patent February 2014
Primary Sodium Batteries with Beta-Alumina Solid Electrolyte journal January 1975
Lithium battery having a protected lithium electrode and an ionic liquid catholyte patent-application February 2014
Encapsulated lithium alloy electrodes having barrier layers patent-application March 2002
In situ formed ionically conductive membranes for protection of active metal anodes and battery cells patent February 2012
Lakyer for stabilization of lithium anode patent August 1994
Lithium anodes for electrochemical cells patent September 2004