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Title: Magnetoelectric Interactions in Lead-Based and Lead-Free Composites

Journal Article · · Materials
DOI:https://doi.org/10.3390/ma4040651· OSTI ID:1628428
 [1];  [1];  [1];  [1];  [2];  [2];  [2]
  1. Novgorod State University (Russian Federation)
  2. Virginia Polytechnic Institute and State University (Virginia Tech), Blacksburg, VA (United States)

Magnetoelectric (ME) composites that simultaneously exhibit ferroelectricity and ferromagnetism have recently gained significant attention as evident by the increasing number of publications. These research activities are direct results of the fact that multiferroic magnetoelectrics offer significant technological promise for multiple devices. Appropriate choice of phases with co-firing capability, magnetostriction and piezoelectric coefficient, such as Ni-PZT and NZFO-PZT, has resulted in fabrication of prototype components that promise transition. In this manuscript, we report the properties of Ni-PZT and NZFO-PZT composites in terms of ME voltage coefficients as a function of frequency and magnetic DC bias. In order to overcome the problem of toxicity of lead, we have conducted experiments with Pb-free piezoelectric compositions. Results are presented on the magnetoelectric performance of Ni-NKN, Ni-NBTBT and NZFO-NKN, NZFO-NBTBT systems illustrating their importance as an environmentally friendly alternative.

Research Organization:
Virginia Polytechnic Institute and State University (Virginia Tech), Blacksburg, VA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Russian Foundation for Basic Research; Russian Ministry of Education and Science; Russian Academy of Sciences
Grant/Contract Number:
08-02-91359-SNF_a
OSTI ID:
1628428
Journal Information:
Materials, Vol. 4, Issue 4; ISSN 1996-1944
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
English

References (160)

Processing and Piezoelectric Properties of Lead-Free (K,Na) (Nb,Ta) O3 Ceramics journal May 2005
Effect of bismuth excess on ferroelectric and piezoelectric properties of a (Na0.5Bi0.5)TiO3–BaTiO3 composition near the morphotropic phase boundary journal March 2009
Structure, electrical properties and depolarization temperature of (Bi0.5Na0.5)TiO3–BaTiO3 lead-free piezoelectric ceramics journal July 2008
Sodium Bismuth Titanate-Based Lead-Free Piezoceramics Prepared by Aqueous Gelcasting journal September 2008
Effect of gradient composite structure in cofired bilayer composites of Pb(Zr0.56Ti0.44)O3–Ni0.6Zn0.2Cu0.2Fe2O4 system on magnetoelectric coefficient journal September 2008
Compositional Modifications of 10%-Pb-Doped Bi0.5Na0.5Tio3 for High-Temperature Dielectrics journal August 1995
Detection of pico-Tesla magnetic fields using magneto-electric sensors at room temperature journal February 2006
Ferroelectric and piezoelectric properties of (Na, K) 0.5 Bi 0.5 TiO 3 lead free ceramics journal May 2006
Effect of uniaxial stress on ferroelectric behavior of (Bi1/2Na1/2)TiO3-based lead-free piezoelectric ceramics journal August 2009
Sodium-bismuth titanate based lead-free ferroelectric materials journal January 2004
Phase Transition Temperatures and Piezoelectric Properties of (Bi 1/2 Na 1/2 )TiO 3 -and (Bi 1/2 K 1/2 )TiO 3 -Based Bismuth Perovskite Lead-Free Ferroelectric Ceramics journal August 2009
Templated Grain Growth of Textured Piezoelectric Ceramics journal April 2004
Magnetoelectric effect in metal-PZT laminates journal August 2005
Development of texture in Bi0.5Na0.5TiO3 prepared by reactive-templated grain growth process journal January 2007
Vortex magnetic field sensor based on ring-type magnetoelectric laminate journal September 2004
Dielectric, electromechanical coupling properties of Mn-doped Na0.5Bi0.5TiO3–BaTiO3 lead-free single crystal journal August 2010
AC conductivity and magnetoelectric effect in CuFe1.6Cr0.4O4–BaTiO3 composite ceramics journal June 2000
Magnetoelectric coupling, efficiency, and voltage gain effect in piezoelectric-piezomagnetic laminate composites journal January 2006
Na0.5Bi0.5TiO3–K0.5Bi0.5TiO3 (NBT-KBT) system: A structural and electrical study journal October 1996
Circumferentially magnetized and circumferentially polarized magnetostrictive/piezoelectric laminated rings journal September 2004
Phase diagram and enhanced piezoelectricity in the strontium titanate doped potassium-sodium niobate solid solution journal May 2005
High-frequency ultrasonic transducer fabricated with lead-free piezoelectric single crystal journal November 2010
High piezoelectric d33 coefficient in Li-modified lead-free (Na,K)NbO3 ceramics sintered at optimal temperature journal June 2007
Electrical Properties and Depolarization Temperature of (Bi 1/2 Na 1/2 )TiO 3 –(Bi 1/2 K 1/2 )TiO 3 Lead-free Piezoelectric Ceramics journal May 2006
Magnetoelectric effect of Pb(Zr,Ti)O3 rod arrays in a (Tb,Dy)Fe2∕epoxy medium journal July 2005
Dielectric and piezoelecrtic properties of lead-free (Na0.5Bi0.5)TiO3–NaNbO3 ceramics journal September 2004
Origin of the large strain response in (K0.5Na0.5)NbO3-modified (Bi0.5Na0.5)TiO3–BaTiO3 lead-free piezoceramics journal May 2009
The origin of ferroelectricity in magnetoelectric YMnO3 journal February 2004
Effect of CoO additive on structure and electrical properties of (Na0.5Bi0.5)0.93Ba0.07TiO3 ceramics prepared by the citrate method journal February 2008
Calculations of giant magnetoelectric effects in ferroic composites of rare-earth–iron alloys and ferroelectric polymers journal March 2001
A new family of magnetoelectric materials: A2M4O9(A  Ta, Nb; M  Mn, Co) journal June 1972
Large magnetoelectric coefficient in Co-fired Pb (Zr0.52Ti0.48)O3–Pb (Zn1/3Nb2/3)O3–Ni0.6Cu0.2Zn0.2Fe2O4 trilayer magnetoelectric composites journal March 2008
Effect of the Magnetostrictive Layer on Magnetoelectric Properties in Lead Zirconate Titanate/Terfenol-D Laminate Composites journal December 2001
⟨001⟩ textured (K0.5Na0.5)(Nb0.97Sb0.03)O3 piezoelectric ceramics with high electromechanical coupling over a broad temperature range journal December 2009
Effect of intensive and extensive loss factors on the dynamic response of magnetoelectric laminates journal November 2010
Extremely low frequency response of magnetoelectric multilayer composites journal March 2005
Magnetoelectric interactions in hot-pressed nickel zinc ferrite and lead zirconante titanate composites journal September 2004
Magnetic phase control by an electric field journal July 2004
(Na0.5K0.5)NbO3–LiTaO3 lead-free piezoelectric ceramics journal February 2005
Multiferroic magnetoelectric composites: Historical perspective, status, and future directions journal February 2008
Synthesis and characterization of in situ grown magnetoelectric composites in the BaO–TiO–FeO–CoO system journal January 2004
Effect of piezoelectric grain size on magnetoelectric coefficient of Pb(Zr0.52Ti0.48)O3–Ni0.8Zn0.2Fe2O4 particulate composites journal May 2008
Thermodynamics and ferroelectric properties of KNbO3 journal November 2009
Core–shell structures in pressureless-sintered undoped Pb(Fe2/3W1/3)O3 ceramics journal August 2001
Design and characterization of broadband magnetoelectric sensor journal May 2009
Electric-field-induced phase transformation at a lead-free morphotropic phase boundary: Case study in a 93%(Bi0.5Na0.5)TiO3–7% BaTiO3 piezoelectric ceramic journal July 2009
Electric polarization reversal and memory in a multiferroic material induced by magnetic fields journal May 2004
Growth, domain dynamics and piezoelectric properties of some lead-free ferroelectric crystals journal January 2009
An in situ grown eutectic magnetoelectric composite material: Part I Composition and unidirectional solidification journal October 1974
Magnetic control of ferroelectric polarization journal November 2003
Fabrication and electrical properties of textured Na1/2Bi1/2TiO3-BaTiO3 ceramics by reactive-templated grain growth journal May 2007
Piezoelectric properties of PbTiO3 thin films characterized with piezoresponse force and high resolution transmission electron microscopy journal March 2009
Magnetoelectric Microwave Devices journal January 2002
Space-time parity violation and magnetoelectric interactions in antiferromagnets journal June 2004
Effect of Mechanical Boundary Conditions on Phase Diagrams of Epitaxial Ferroelectric Thin Films journal March 1998
Piezoelectric properties of (Bi1/2Na1/2)TiO3-based ceramics journal June 1990
Dielectric properties of some low-lead or lead-free perovskite-derived materials: Na0.5Bi0.5TiO3–PbZrO3, Na0.5Bi0.5TiO3–BiScO3 and Na0.5Bi0.5TiO3–BiFeO3 ceramics journal January 2006
Structure and electrical properties of (Na0.5Bi0.5)1−xBaxTiO3 piezoelectric ceramics journal January 2008
The magnetoelectric effect: Some likely candidates journal August 1969
Correlation between Phase Transitions and Piezoelectric Properties in Lead-Free (K,Na,Li)NbO 3 –BaTiO 3 Ceramics journal December 2008
A sintered magnetoelectric composite material BaTiO3-Ni(Co, Mn) Fe2O4 journal July 1978
Dielectric and piezoelectric properties of (1 − x)(Na0.5K0.5)NbO3–xBaTiO3 ceramics journal October 2008
Influence of mechanical boundary conditions and microstructural features on magnetoelectric behavior in a three-phase multiferroic particulate composite journal October 2004
Piezoelectric properties of (Li, Sb, Ta) modified (Na,K)NbO3 lead-free ceramics journal March 2007
Sinterability and Piezoelectric Properties of (K,Na)NbO 3 Ceramics with Novel Sintering Aid journal October 2004
Recent advancements in magnetoelectric particulate and laminate composites journal February 2007
Electric-field-induced magnetization in Pb(Zr,Ti)O3/Terfenol-D composite structures journal May 2006
Observation of coupled magnetic and electric domains journal October 2002
Dimensionally gradient magnetoelectric bimorph structure exhibiting wide frequency and magnetic dc bias operating range journal December 2009
Phase Transition and Temperature Dependences of Electrical Properties of [Bi 0.5 (Na 1- x - y K x Li y ) 0.5 ]TiO 3 Ceramics journal February 2006
Time dependence of electric permittivity in na 0.5 Bi 0.5 TiO 3 single crystals journal January 1989
Perovskite (Na0.5K0.5)1−x(LiSb)xNb1−xO3 lead-free piezoceramics journal May 2006
Phase Diagram of the (Na 0.5 K 0.5 )NbO 3 -ATiO 3 Solid Solution journal July 2006
The physics of magnetoelectric composites journal July 2008
Improved magnetoelectric properties of piezoelectric–magnetostrictive nanocomposites synthesized using high-pressure compaction technique journal April 2009
Magnetoelectric properties of multiferroic composites with pseudo-1-3-type structure journal June 2006
Phase relation and dielectric properties in (Bi1/2 Na1/2)1−x Bax TiO3 TiO3 lead-free ceramics journal August 2006
Giant magnetoelectric effect in sintered multilayered composite structures journal August 2008
Magnetoelectric properties of the lead–free cofired BaTiO3–(Ni0.8Zn0.2)Fe2O4 bilayer composite journal October 2006
Enhanced magnetoelectric properties in three-phase composites with 2-1-2 connectivity journal November 2010
Inhomogeneity issues in the growth of Na1/2Bi1/2TiO3–BaTiO3 single crystals journal January 2008
Magnetoelectric effect in magnetostrictive/piezoelectric laminate composite Terfenol-D∕LiNbO3 [(zxtw)−129°∕30°] journal April 2006
Piezoelectric and Dielectric Properties of Ceramics in the System Potassium-Sodium Niobate journal September 1959
Push-pull mode magnetostrictive/piezoelectric laminate composite with an enhanced magnetoelectric voltage coefficient journal August 2005
Influence of MnO 2 Doping on the Dielectric and Piezoelectric Properties and the Domain Structure in (K 0.5 Na 0.5 )NbO 3 Single Crystals journal April 2010
Compositional dependence of phase structure and electrical properties in (K0.42Na0.58)NbO3-LiSbO3 lead-free ceramics journal December 2007
Current status and prospects of lead-free piezoelectric ceramics journal January 2005
Dielectric/piezoelectric properties and temperature dependence of domain structure evolution in lead free single crystal journal October 2009
A longitudinal-longitudinal mode TERFENOL-D∕Pb(Mg1∕3Nb2∕3)O3–PbTiO3 laminate composite journal November 2004
A phenomenological thermodynamic potential for BaTiO3 single crystals journal September 2005
Influence of compositional ratio K/Na on physical properties in (KxNa1−x)NbO3 ceramics journal April 2008
Internal friction study on CuFe2O4∕PbZr0.53Ti0.47O3 composites journal November 2004
Ferroelectric and Piezoelectric Properties of Fine-Grained Na0.5K0.5NbO3 Lead-Free Piezoelectric Ceramics Prepared by Spark Plasma Sintering journal February 2006
Dielectric, ferroelectric, magnetic, and magnetoelectric properties of multiferroic laminated composites journal December 2003
Dielectric Relaxor Properties in the System of (Na 1- x K x ) 1/2 Bi 1/2 TiO 3 Ceramics journal June 2006
Giant magneto-electric effect in laminate composites journal October 2003
Self-biased magnetoelectric response in three-phase laminates journal November 2010
Longitudinal and transverse magnetoelectric voltage coefficients of magnetostrictive/piezoelectric laminate composite: theory journal October 2003
Enhancing Electrical Properties in NBT-KBT Lead-Free Piezoelectric Ceramics by Optimizing Sintering Temperature journal August 2008
Frequency dependence of magnetoelectric interactions in layered structures of ferromagnetic alloys and piezoelectric oxides journal January 2004
Fe–Ga∕Pb(Mg1∕3Nb2∕3)O3–PbTiO3 magnetoelectric laminate composites journal November 2005
A three-phase magnetoelectric composite of piezoelectric ceramics, rare-earth iron alloys, and polymer journal November 2002
A new route to magnetic ferroelectrics: Magnetoelectrics journal December 2004
Frequency and field dependence of magnetoelectric interactions in layered ferromagnetic transition metal-piezoelectric lead zirconate titanate journal November 2005
Phase transition temperature and electrical properties of (Bi1∕2Na1∕2)TiO3–(Bi1∕2A1∕2)TiO3 (A=Li and K) lead-free ferroelectric ceramics journal April 2008
Investigations of the phase transitions in Na 0.5 Bi 0.5 TiO 3 journal October 1995
Resonance magnetoelectric effects in layered magnetostrictive-piezoelectric composites journal October 2003
Phase transitional behavior and piezoelectric properties of (Na0.5K0.5)NbO3–LiNbO3 ceramics journal November 2004
Investigation of the structure and phase transitions in the novel A-site substituted distorted perovskite compound Na 0.5 Bi 0.5 TiO 3 journal March 2002
Effects of Sb content on electrical properties of lead-free piezoelectric [(Na0.535K0.480)0.942Li0.058](Nb1−xSbx)O3 ceramics journal February 2010
Electrical properties of Na1/2Bi1/2TiO3–BaTiO3 ceramics journal December 2002
Magnetoelectric effects in bilayers and multilayers of magnetostrictive and piezoelectric perovskite oxides journal March 2002
High Magnetoelectric Properties in 0.68Pb(Mg1/3Nb2/3)O3-0.32PbTiO3Single Crystal and Terfenol-D Laminate Composites journal January 2002
ME response of cofired trilayer magnetoelectric composites with partial texturing journal August 2009
Piezoelectric and ferroelectric properties of lead-free [Bi1−y(Na1−x−yLix)]0.5BayTiO3 ceramics journal January 2006
Theory of low-frequency magnetoelectric coupling in magnetostrictive-piezoelectric bilayers journal August 2003
Effect of martensitic transformation on magnetoelectric properties of Ni2MnGa∕PbZr0.52Ti0.48O3 composite journal October 2005
Revival of the magnetoelectric effect journal April 2005
Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures journal March 2003
On the Phase Transition in Barium-Lead Titanate (1) journal July 1951
Microstructure and piezoelectric properties of lead-free (1−x)(Na0.5K0.5)NbO3-xCaTiO3 ceramics journal December 2007
Longitudinal and transverse magnetoelectric voltage coefficients of magnetostrictive/ piezoelectric laminate composite: experiments journal July 2004
Lead-free piezoceramics journal October 2004
Reactive-templated grain growth processing for lead free piezoelectric ceramics journal February 2006
Hot Pressing of Potassium-Sodium Niobates journal May 1962
Phase coexistence and Mn-doping effect in lead-free ferroelectric (Na1/2Bi1/2)TiO3 crystals journal February 2010
A generalized rule for large piezoelectric response in perovskite oxide ceramics and its application for design of lead-free compositions journal June 2009
Piezoelectric and Pyroelectric Properties of (K 0.5 Na 0.5 ) 1 - x (Nb 1 - y Ta y )O 3 Ceramics journal July 2006
Study of magnetic and magnetoelectric measurements in bismuth iron titanate ceramic—Bi8Fe4Ti3O24 journal January 2004
Magnetoelectric Properties in Piezoelectric and Magnetostrictive Laminate Composites journal August 2001
(Bi 1/2 Na 1/2 )TiO 3 -BaTiO 3 System for Lead-Free Piezoelectric Ceramics journal September 1991
Magnetoelectric effects in ferrite-lead zirconate titanate layered composites: The influence of zinc substitution in ferrites journal January 2003
Polarization and lattice strains in epitaxial BaTiO3 films grown by high-pressure sputtering journal June 2007
Small dc magnetic field response of magnetoelectric laminate composites journal February 2006
A strong magnetoelectric voltage gain effect in magnetostrictive-piezoelectric composite journal October 2004
Electrostrictive strain and pyroeffect in the region of phase coexistence in Na 0.5 Bi 0.5 TiO 3 journal January 1988
Enhanced magnetoelectric effects in laminate composites of Terfenol-D/Pb(Zr,Ti)O3 under resonant drive journal December 2003
Magnetoelectric Laminate Composites: An Overview journal February 2008
Magnetic-field-induced phase transition in BiFeO 3 observed by high-field electron spin resonance: Cycloidal to homogeneous spin order journal February 2004
Effects of Na nonstoichiometry in (Bi0.5Na0.5+x)TiO3 ceramics journal January 2010
Directional solidification and interface structure of BaTiO3-CoFe2O4 eutectic journal January 2000
Structural variation and piezoelectric properties of 0.95(Na0.5K0.5)NbO3–0.05BaTiO3 ceramics journal May 2007
Electromechanical and ferroelectric properties of (Bi1∕2Na1∕2)TiO3–(Bi1∕2K1∕2)TiO3–BaTiO3 lead-free piezoelectric ceramics journal July 2004
Piezoelectric properties of Li- and Ta-modified (K0.5Na0.5)NbO3 ceramics journal October 2005
Lead-free piezoelectric ceramics of (Bi 1/2 Na 1/2 )TiO 3 -BaTiO 3 -BiFeO 3 system journal May 1999
Properties of Hot-Pressed Ferroelectric Alkali Niobate Ceramics journal June 1967
Lead-Free Piezoelectric Ceramics of ( B i 1/2 N a 1/2 ) T i O 3 –1/2( B i 2 O 3 · S c 2 O 3 ) System journal September 1997
High magnetic field sensitivity in Pb(Zr,Ti)O3–Pb(Mg1/3Nb2/3)O3 single crystal/Terfenol-D/Metglas magnetoelectric laminate composites journal May 2010
Dielectric and Piezoelectric Properties of NaNbO3 - BaTiO3 - SrTiO3 Ceramics conference May 2007
Enhanced magnetoelectric effect in core-shell particulate composites journal April 2006
Frequency response of magnetoelectric 1–3-type composites journal May 2010
Structure and electrical properties of (1−x)Bi0.5Na0.5TiO3–xBi0.5K0.5TiO3 ceramics near morphotropic phase boundary journal January 2008
Magnetostrictive and magnetoelectric behavior of Fe–20at.% Ga∕Pb(Zr,Ti)O3 laminates journal May 2005
Thermal and X‐Ray Diffraction Studies of the NaNbO 3 –KNbO 3 System journal September 1968
Shear-Mode Piezoelectric Properties of Modified-(K,Na)NbO3 Ceramics for “Hard” Lead-Free Materials: Rapid Communications of the American Ceramic Society journal June 2010
(Reactive) Templated Grain Growth of Textured Sodium Bismuth Titanate (Na 1/2 Bi 1/2 TiO 3 -BaTiO 3 ) Ceramics—I Processing journal December 2003
Magnetoelectric interaction phenomena in materials journal December 1994
Quasistatic and dynamic properties of 1–3 composites made by soft molding journal January 2003
Generalized Lattice Model of Multi-Component Systems with Internal Degrees of Freedom. II. Quasiequilibrium States preprint January 2009
Order-disorder type critical behaviour at the magnetoelectric phase transition in multiferroic DyMnO$_3$ text January 2015

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