Porous nitrogen-enriched carbonaceous material from marine waste: chitosan-derived carbon nitride catalyst for aerial oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid
Abstract
Chitosan-derived, porous nitrogen-enriched carbonaceous carbon nitride catalyst (PCNx) has been synthesized from marine waste and its use demonstrated in a metal-free heterogeneous selective oxidation of 5-hydroxymethyl-furfural (HMF) to 2,5-furandicarboxylic acid (FDCA) using aerial oxygen under mild reaction conditions.
- Authors:
-
- Oak Ridge Inst. for Science and Education (ORISE), Oak Ridge, TN (United States)
- US Environmental Protection Agency (EPA), Cincinnati, OH (United States). National Risk Management Research Lab. Water Resources Recovery Branch. Water Systems Division
- Publication Date:
- Research Org.:
- Oak Ridge Institute for Science and Education (ORISE), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1624352
- Grant/Contract Number:
- SC0014664
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES; Science & Technology - Other Topics
Citation Formats
Verma, Sanny, Nadagouda, Mallikarjuna N., and Varma, Rajender S. Porous nitrogen-enriched carbonaceous material from marine waste: chitosan-derived carbon nitride catalyst for aerial oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid. United States: N. p., 2017.
Web. doi:10.1038/s41598-017-14016-5.
Verma, Sanny, Nadagouda, Mallikarjuna N., & Varma, Rajender S. Porous nitrogen-enriched carbonaceous material from marine waste: chitosan-derived carbon nitride catalyst for aerial oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid. United States. https://doi.org/10.1038/s41598-017-14016-5
Verma, Sanny, Nadagouda, Mallikarjuna N., and Varma, Rajender S. 2017.
"Porous nitrogen-enriched carbonaceous material from marine waste: chitosan-derived carbon nitride catalyst for aerial oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid". United States. https://doi.org/10.1038/s41598-017-14016-5. https://www.osti.gov/servlets/purl/1624352.
@article{osti_1624352,
title = {Porous nitrogen-enriched carbonaceous material from marine waste: chitosan-derived carbon nitride catalyst for aerial oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid},
author = {Verma, Sanny and Nadagouda, Mallikarjuna N. and Varma, Rajender S.},
abstractNote = {Chitosan-derived, porous nitrogen-enriched carbonaceous carbon nitride catalyst (PCNx) has been synthesized from marine waste and its use demonstrated in a metal-free heterogeneous selective oxidation of 5-hydroxymethyl-furfural (HMF) to 2,5-furandicarboxylic acid (FDCA) using aerial oxygen under mild reaction conditions.},
doi = {10.1038/s41598-017-14016-5},
url = {https://www.osti.gov/biblio/1624352},
journal = {Scientific Reports},
issn = {2045-2322},
number = 1,
volume = 7,
place = {United States},
year = {Thu Oct 19 00:00:00 EDT 2017},
month = {Thu Oct 19 00:00:00 EDT 2017}
}
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Works referenced in this record:
One-Step Approach to 2,5-Diformylfuran from Fructose by Proton- and Vanadium-Containing Graphitic Carbon Nitride
journal, September 2014
- Chen, Jinzhu; Guo, Yuanyuan; Chen, Jiayi
- ChemCatChem, Vol. 6, Issue 11
Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals
journal, September 2007
- Chheda, Juben N.; Huber, George W.; Dumesic, James A.
- Angewandte Chemie International Edition, Vol. 46, Issue 38, p. 7164-7183
Selective Conversion of Cellobiose and Cellulose into Gluconic Acid in Water in the Presence of Oxygen, Catalyzed by Polyoxometalate-Supported Gold Nanoparticles
journal, February 2012
- An, Dongli; Ye, Aihua; Deng, Weiping
- Chemistry - A European Journal, Vol. 18, Issue 10
A sulfuric acid management strategy for the production of liquid hydrocarbon fuels via catalytic conversion of biomass-derived levulinic acid
journal, January 2012
- Sen, S. Murat; Alonso, David Martin; Wettstein, Stephanie G.
- Energy & Environmental Science, Vol. 5, Issue 12
Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
journal, February 2013
- van Putten, Robert-Jan; van der Waal, Jan C.; de Jong, Ed
- Chemical Reviews, Vol. 113, Issue 3
Insights into the Interplay of Lewis and Brønsted Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural and Levulinic Acid in Aqueous Media
journal, March 2013
- Choudhary, Vinit; Mushrif, Samir H.; Ho, Christopher
- Journal of the American Chemical Society, Vol. 135, Issue 10
Chemical Routes for the Transformation of Biomass into Chemicals
journal, June 2007
- Corma, Avelino; Iborra, Sara; Velty, Alexandra
- Chemical Reviews, Vol. 107, Issue 6, p. 2411-2502
Oxidation of 5-hydroxymethylfurfural over supported Pt, Pd and Au catalysts
journal, February 2011
- Davis, Sara E.; Houk, Levi R.; Tamargo, Erin C.
- Catalysis Today, Vol. 160, Issue 1, p. 55-60
Fuels and plastics from lignocellulosic biomass via the furan pathway; a technical analysis
journal, January 2014
- Eerhart, A. J. J. E.; Huijgen, W. J. J.; Grisel, R. J. H.
- RSC Adv., Vol. 4, Issue 7
Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance
journal, January 2012
- Eerhart, A. J. J. E.; Faaij, A. P. C.; Patel, M. K.
- Energy & Environmental Science, Vol. 5, Issue 4
Gold-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural in Water at Ambient Temperature
journal, July 2009
- Gorbanev, Yury Y.; Klitgaard, Søren K.; Woodley, John M.
- ChemSusChem, Vol. 2, Issue 7
Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited
journal, January 2010
- Bozell, Joseph J.; Petersen, Gene R.
- Green Chemistry, Vol. 12, Issue 4, p. 539-554
The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials
journal, January 2012
- Ma, Jiping; Pang, Yi; Wang, Min
- Journal of Materials Chemistry, Vol. 22, Issue 8
Biomass into Chemicals: Aerobic Oxidation of 5-Hydroxymethyl-2-furfural into 2,5-Furandicarboxylic Acid with Gold Nanoparticle Catalysts
journal, December 2009
- Casanova, Onofre; Iborra, Sara; Corma, Avelino
- ChemSusChem, Vol. 2, Issue 12
Catalytic Performance of Zeolite-Supported Vanadia in the Aerobic Oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran
journal, November 2012
- Sádaba, Irantzu; Gorbanev, Yury Y.; Kegnaes, Søren
- ChemCatChem, Vol. 5, Issue 1
Selective oxidation of 5-hydroxymethyl-2-furfural into 2,5-diformylfuran over VO2+ and Cu2+ ions immobilized on sulfonated carbon catalysts
journal, August 2013
- Le, Ngoc-Thuc; Lakshmanan, Pandian; Cho, Kyungho
- Applied Catalysis A: General, Vol. 464-465
Metal-exchanged magnetic β-zeolites: valorization of lignocellulosic biomass-derived compounds to platform chemicals
journal, January 2017
- Jorge, Erlen Y. C.; Lima, Thiago de M.; Lima, Carolina G. S.
- Green Chemistry, Vol. 19, Issue 16
Sustainable Strategy Utilizing Biomass: Visible-Light-Mediated Synthesis of γ-Valerolactone
journal, February 2016
- Verma, Sanny; Baig, R. B. Nasir; Nadagouda, Mallikarjuna N.
- ChemCatChem, Vol. 8, Issue 4
Greener and Sustainable Trends in Synthesis of Organics and Nanomaterials
journal, July 2016
- Varma, Rajender S.
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 11
Sustainable polymers from renewable resources
journal, December 2016
- Zhu, Yunqing; Romain, Charles; Williams, Charlotte K.
- Nature, Vol. 540, Issue 7633
Hydrotalcite-supported gold-nanoparticle-catalyzed highly efficient base-free aqueous oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under atmospheric oxygen pressure
journal, January 2011
- Gupta, Navneet Kumar; Nishimura, Shun; Takagaki, Atsushi
- Green Chemistry, Vol. 13, Issue 4
A metal-free, high nitrogen-doped nanoporous graphitic carbon catalyst for an effective aerobic HMF-to-FDCA conversion
journal, January 2016
- Nguyen, Chi Van; Liao, Yu-Te; Kang, Ting-Cih
- Green Chemistry, Vol. 18, Issue 22
One-pot synthesis of 2,5-diformylfuran from fructose using a magnetic bi-functional catalyst
journal, January 2016
- Mittal, Neha; Nisola, Grace M.; Malihan, Lenny B.
- RSC Advances, Vol. 6, Issue 31
Optimization of Co/Mn/Br-Catalyzed Oxidation of 5-Hydroxymethylfurfural to Enhance 2,5-Furandicarboxylic Acid Yield and Minimize Substrate Burning
journal, June 2016
- Zuo, Xiaobin; Venkitasubramanian, Padmesh; Busch, Daryle H.
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 7
Selective oxidation of 5-hydroxymethyl-2-furaldehyde to furan-2,5-dicarboxaldehyde by catalytic systems based on vanadyl phosphate
journal, August 2005
- Carlini, Carlo; Patrono, Pasquale; Galletti, Anna Maria Raspolli
- Applied Catalysis A: General, Vol. 289, Issue 2
Aerobic oxidation of 5-hydroxylmethylfurfural with homogeneous and nanoparticulate catalysts
journal, January 2012
- Saha, Basudeb; Dutta, Saikat; Abu-Omar, Mahdi M.
- Catal. Sci. Technol., Vol. 2, Issue 1
Sustainable pathway to furanics from biomass via heterogeneous organo-catalysis
journal, January 2017
- Verma, Sanny; Baig, R. B. Nasir; Nadagouda, Mallikarjuna N.
- Green Chemistry, Vol. 19, Issue 1
Synthesis of 2,5-Diformylfuran and Furan-2,5-Dicarboxylic Acid by Catalytic Air-Oxidation of 5-Hydroxymethylfurfural. Unexpectedly Selective Aerobic Oxidation of Benzyl Alcohol to Benzaldehyde with Metal/Bromide Catalysts
journal, January 2001
- Partenheimer, Walt; Grushin, Vladimir V.
- Advanced Synthesis & Catalysis, Vol. 343, Issue 1
Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing
journal, January 2011
- Serrano-Ruiz, Juan Carlos; Luque, Rafael; Sepúlveda-Escribano, Antonio
- Chemical Society Reviews, Vol. 40, Issue 11, p. 5266-5281
Aerobic Oxidation of Biomass-Derived 5-(Hydroxymethyl)furfural into 2,5-Diformylfuran Catalyzed by the Trimetallic Mixed Oxide (Co–Ce–Ru)
journal, January 2014
- Wang, Yimei; Liu, Bing; Huang, Kecheng
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 4
A choline chloride/DMSO solvent for the direct synthesis of diformylfuran from carbohydrates in the presence of heteropolyacids
journal, January 2015
- Ghezali, W.; De Oliveira Vigier, K.; Kessas, R.
- Green Chemistry, Vol. 17, Issue 8
Purification of Biomass-Derived 5-Hydroxymethylfurfural and Its Catalytic Conversion to 2,5-Furandicarboxylic Acid
journal, May 2014
- Yi, Guangshun; Teong, Siew Ping; Li, Xiukai
- ChemSusChem, Vol. 7, Issue 8
Magnetic ZSM-5 zeolite: a selective catalyst for the valorization of furfuryl alcohol to γ-valerolactone, alkyl levulinates or levulinic acid
journal, January 2016
- Lima, Thiago M.; Lima, Carolina G. S.; Rathi, Anuj K.
- Green Chemistry, Vol. 18, Issue 20
Efficient Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran, and Synthesis of a Fluorescent Material
journal, November 2010
- Ma, Jiping; Du, Zhongtian; Xu, Jie
- ChemSusChem, Vol. 4, Issue 1
Visible light mediated upgrading of biomass to biofuel
journal, January 2016
- Verma, Sanny; Nasir Baig, R. B.; Nadagouda, Mallikarjuna N.
- Green Chemistry, Vol. 18, Issue 5
Nitrogen-Doped, Metal-Free Activated Carbon Catalysts for Aerobic Oxidation of Alcohols
journal, March 2015
- Watanabe, Hiroyuki; Asano, Sayaka; Fujita, Shin-ichiro
- ACS Catalysis, Vol. 5, Issue 5
Catalytic Conversion of Biomass-Derived Carbohydrates into γ-Valerolactone without Using an External H2 Supply
journal, August 2009
- Deng, Li; Li, Jiang; Lai, Da-Ming
- Angewandte Chemie International Edition, Vol. 48, Issue 35, p. 6529-6532
A Brief Summary of the Synthesis of Polyester Building-Block Chemicals and Biofuels from 5-Hydroxymethylfurfural
journal, February 2012
- Dutta, Saikat; De, Sudipta; Saha, Basudeb
- ChemPlusChem, Vol. 77, Issue 4, p. 259-272
Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals
journal, December 2007
- Chheda, Juben N.; Huber, George W.; Dumesic, James A.
- ChemInform, Vol. 38, Issue 50
Chemical Routes for the Transformation of Biomass into Chemicals
journal, September 2007
- Corma, Avelino; Iborra, Sara; Velty, Alexandra
- ChemInform, Vol. 38, Issue 36
Catalytic Conversion of Biomass-Derived Carbohydrates into γ-Valerolactone without Using an External H 2 Supply
journal, August 2009
- Deng, Li; Li, Jiang; Lai, Da-Ming
- Angewandte Chemie, Vol. 121, Issue 35
A sustainable approach to empower the bio-based future: upgrading of biomass via process intensification
dataset, January 2017
- Varma, Rajender
- U.S. EPA Office of Research and Development (ORD)
Sustainable pathway to furanics from biomass via heterogeneous organo-catalysis
dataset, January 2017
- Varma, Rajender
- U.S. EPA Office of Research and Development (ORD)
Catalytic Conversion of Biomass-Derived Carbohydrates into γ-Valerolactone without Using an External H 2 Supply
journal, August 2009
- Deng, Li; Li, Jiang; Lai, Da-Ming
- Angewandte Chemie, Vol. 121, Issue 35
One-Step Approach to 2,5-Diformylfuran from Fructose by Proton- and Vanadium-Containing Graphitic Carbon Nitride
journal, September 2014
- Chen, Jinzhu; Guo, Yuanyuan; Chen, Jiayi
- ChemCatChem, Vol. 6, Issue 11
Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals
journal, December 2007
- Chheda, Juben N.; Huber, George W.; Dumesic, James A.
- ChemInform, Vol. 38, Issue 50
A Brief Summary of the Synthesis of Polyester Building-Block Chemicals and Biofuels from 5-Hydroxymethylfurfural
journal, February 2012
- Dutta, Saikat; De, Sudipta; Saha, Basudeb
- ChemPlusChem, Vol. 77, Issue 4, p. 259-272
Gold-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural in Water at Ambient Temperature
journal, July 2009
- Gorbanev, Yury Y.; Klitgaard, Søren K.; Woodley, John M.
- ChemSusChem, Vol. 2, Issue 7
Biomass into Chemicals: Aerobic Oxidation of 5-Hydroxymethyl-2-furfural into 2,5-Furandicarboxylic Acid with Gold Nanoparticle Catalysts
journal, December 2009
- Casanova, Onofre; Iborra, Sara; Corma, Avelino
- ChemSusChem, Vol. 2, Issue 12
Purification of Biomass-Derived 5-Hydroxymethylfurfural and Its Catalytic Conversion to 2,5-Furandicarboxylic Acid
journal, May 2014
- Yi, Guangshun; Teong, Siew Ping; Li, Xiukai
- ChemSusChem, Vol. 7, Issue 8
Selective oxidation of 5-hydroxymethyl-2-furaldehyde to furan-2,5-dicarboxaldehyde by catalytic systems based on vanadyl phosphate
journal, August 2005
- Carlini, Carlo; Patrono, Pasquale; Galletti, Anna Maria Raspolli
- Applied Catalysis A: General, Vol. 289, Issue 2
Selective oxidation of 5-hydroxymethyl-2-furfural into 2,5-diformylfuran over VO2+ and Cu2+ ions immobilized on sulfonated carbon catalysts
journal, August 2013
- Le, Ngoc-Thuc; Lakshmanan, Pandian; Cho, Kyungho
- Applied Catalysis A: General, Vol. 464-465
Oxidation of 5-hydroxymethylfurfural over supported Pt, Pd and Au catalysts
journal, February 2011
- Davis, Sara E.; Houk, Levi R.; Tamargo, Erin C.
- Catalysis Today, Vol. 160, Issue 1, p. 55-60
Nitrogen-Doped, Metal-Free Activated Carbon Catalysts for Aerobic Oxidation of Alcohols
journal, March 2015
- Watanabe, Hiroyuki; Asano, Sayaka; Fujita, Shin-ichiro
- ACS Catalysis, Vol. 5, Issue 5
Optimization of Co/Mn/Br-Catalyzed Oxidation of 5-Hydroxymethylfurfural to Enhance 2,5-Furandicarboxylic Acid Yield and Minimize Substrate Burning
journal, June 2016
- Zuo, Xiaobin; Venkitasubramanian, Padmesh; Busch, Daryle H.
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 7
Greener and Sustainable Trends in Synthesis of Organics and Nanomaterials
journal, July 2016
- Varma, Rajender S.
- ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 11
Insights into the Interplay of Lewis and Brønsted Acid Catalysts in Glucose and Fructose Conversion to 5-(Hydroxymethyl)furfural and Levulinic Acid in Aqueous Media
journal, March 2013
- Choudhary, Vinit; Mushrif, Samir H.; Ho, Christopher
- Journal of the American Chemical Society, Vol. 135, Issue 10
Sustainable polymers from renewable resources
journal, December 2016
- Zhu, Yunqing; Romain, Charles; Williams, Charlotte K.
- Nature, Vol. 540, Issue 7633
Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited
journal, January 2010
- Bozell, Joseph J.; Petersen, Gene R.
- Green Chemistry, Vol. 12, Issue 4, p. 539-554
Hydrotalcite-supported gold-nanoparticle-catalyzed highly efficient base-free aqueous oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under atmospheric oxygen pressure
journal, January 2011
- Gupta, Navneet Kumar; Nishimura, Shun; Takagaki, Atsushi
- Green Chemistry, Vol. 13, Issue 4
Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing
journal, January 2011
- Serrano-Ruiz, Juan Carlos; Luque, Rafael; Sepúlveda-Escribano, Antonio
- Chemical Society Reviews, Vol. 40, Issue 11, p. 5266-5281
Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance
journal, January 2012
- Eerhart, A. J. J. E.; Faaij, A. P. C.; Patel, M. K.
- Energy & Environmental Science, Vol. 5, Issue 4
A sulfuric acid management strategy for the production of liquid hydrocarbon fuels via catalytic conversion of biomass-derived levulinic acid
journal, January 2012
- Sen, S. Murat; Alonso, David Martin; Wettstein, Stephanie G.
- Energy & Environmental Science, Vol. 5, Issue 12
The copolymerization reactivity of diols with 2,5-furandicarboxylic acid for furan-based copolyester materials
journal, January 2012
- Ma, Jiping; Pang, Yi; Wang, Min
- Journal of Materials Chemistry, Vol. 22, Issue 8
A sustainable approach to empower the bio-based future: upgrading of biomass via process intensification
journal, January 2017
- Tadele, Kidus; Verma, Sanny; Gonzalez, Michael A.
- Green Chemistry, Vol. 19, Issue 7
Continuous production of carbon nanotubes and diamond films by swirled floating catalyst chemical vapour deposition method
journal, January 2010
- Afolabi, A. S.; Abdulkareem, A. S.; Iyuke, S. E.
- South African Journal of Science, Vol. 105, Issue 7/8
Works referencing / citing this record:
Catalytic preparation of levulinic acid from cellobiose via Brønsted-Lewis acidic ionic liquids functional catalysts
journal, February 2019
- Liu, Shiwei; Wang, Kai; Yu, Hailong
- Scientific Reports, Vol. 9, Issue 1
Nitrogen-enriched porous carbon supported Pd-nanoparticles as an efficient catalyst for the transfer hydrogenation of alkenes
journal, January 2018
- Li, Jie; Zhou, Xin; Shang, Ning-Zhao
- New Journal of Chemistry, Vol. 42, Issue 20
Chemocatalytic Conversion of Cellulose into Key Platform Chemicals
journal, August 2018
- Li, Guangbi; Liu, Wei; Ye, Chenliang
- International Journal of Polymer Science, Vol. 2018
Lignocellulosic Biomass Transformations via Greener Oxidative Pretreatment Processes: Access to Energy and Value-Added Chemicals
journal, April 2018
- Den, Walter; Sharma, Virender K.; Lee, Mengshan
- Frontiers in Chemistry, Vol. 6
Comparison Study on the Adsorption Capacity of Rhodamine B, Congo Red, and Orange II on Fe-MOFs
journal, April 2018
- Wei, Fuhua; Chen, Ding; Liang, Zhao
- Nanomaterials, Vol. 8, Issue 4
Catalytic preparation of levulinic acid from cellobiose via Brønsted-Lewis acidic ionic liquids functional catalysts
journal, February 2019
- Liu, Shiwei; Wang, Kai; Yu, Hailong
- Scientific Reports, Vol. 9, Issue 1
Comparison Study on the Adsorption Capacity of Rhodamine B, Congo Red, and Orange II on Fe-MOFs
journal, April 2018
- Wei, Fuhua; Chen, Ding; Liang, Zhao
- Nanomaterials, Vol. 8, Issue 4