Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production

Ding, Hanping; Wu, Wei; Jiang, Chao; Ding, Yong; Bian, Wenjuan; Hu, Boxun; Singh, Prabhakar; Orme, Christopher J.; Wang, Lucun; Zhang, Yunya; Ding, Dong

doi:10.1038/s41467-020-15677-z

Title: Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production

Journal Article · Mon Apr 20 00:00:00 EDT 2020 · Nature Communications

DOI:https://doi.org/10.1038/s41467-020-15677-z· OSTI ID:1618272

^[1];

^[2]; Bian, Wenjuan ^[3]; Hu, Boxun ^[4]; Singh, Prabhakar ^[4];

^[1];

^[1]; Zhang, Yunya ^[1];

^[1]

Idaho National Lab. (INL), Idaho Falls, ID (United States)
Georgia Inst. of Technology, Atlanta, GA (United States)
Idaho National Lab. (INL), Idaho Falls, ID (United States); New Mexico State Univ., Las Cruces, NM (United States)
Univ. of Connecticut, Storrs, CT (United States)

The protonic ceramic electrochemical cell (PCEC) is an emerging and attractive technology that converts energy between power and hydrogen using solid oxide proton conductors at intermediate temperatures. To achieve efficient electrochemical hydrogen and power production with stable operation, highly robust and durable electrodes are urgently desired to facilitate water oxidation and oxygen reduction reactions, which are the critical steps for both electrolysis and fuel cell operation, especially at reduced temperatures. In this study, a triple conducting oxide of PrNi_0.5Co_0.5O_3-δ perovskite is developed as an oxygen electrode, presenting superior electrochemical performance at 400-600°C. More importantly, the self-sustainable and reversible operation is successfully demonstrated by converting the generated hydrogen in electrolysis mode to electricity without any hydrogen addition. The excellent electrocatalytic activity is attributed to the considerable proton conduction, as confirmed by hydrogen permeation experiment, remarkable hydration behavior and computations.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Idaho National Lab. (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1618272

Report Number(s):: INL/JOU-18-52078-Rev001; TRN: US2106803

Journal Information:: Nature Communications, Vol. 11, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 131 works

Citation information provided by
Web of Science

References (61)

Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Improved stability of reversible solid oxide cells with a nickelate-based oxygen electrode Laguna-Bercero, M. A.; Monzón, H.; Larrea, A. Journal of Materials Chemistry A, Vol. 4, Issue 4 https://doi.org/10.1039/C5TA08531D	journal	January 2016
Ce0.6Mn0.3Fe0.1O2-δ as an Alternative Cathode Material for High Temperature Steam Electrolysis Using LaGaO3-based Oxide Electrolyte Hosoi, Kohei; Sakai, Takaaki; Ida, Shintaro Electrochimica Acta, Vol. 194 https://doi.org/10.1016/j.electacta.2016.02.121	journal	March 2016
Intermediate-temperature solid oxide electrolysis cells with thin proton-conducting electrolyte and a robust air electrode Lei, Libin; Tao, Zetian; Wang, Xiaoming Journal of Materials Chemistry A, Vol. 5, Issue 44 https://doi.org/10.1039/C7TA05841A	journal	January 2017
Technological development of hydrogen production by solid oxide electrolyzer cell (SOEC) Ni, M.; Leung, M.; Leung, D. International Journal of Hydrogen Energy, Vol. 33, Issue 9 https://doi.org/10.1016/j.ijhydene.2008.02.048	journal	May 2008
Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production Duan, Chuancheng; Kee, Robert; Zhu, Huayang Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0333-2	journal	March 2019
Development of High Performance Intermediate Temperature Proton-Conducting Solid Oxide Electrolysis Cells Wu, Wei; Ding, Dong; He, Ting ECS Transactions, Vol. 80, Issue 9 https://doi.org/10.1149/08009.0167ecst	journal	August 2017
Proton-Conducting Oxides Kreuer, K. D. Annual Review of Materials Research, Vol. 33, Issue 1, p. 333-359 https://doi.org/10.1146/annurev.matsci.33.022802.091825	journal	August 2003
Progress in high-temperature electrolysis for hydrogen production using planar SOFC technology Herring, J. Stephen; O’Brien, James E.; Stoots, Carl M. International Journal of Hydrogen Energy, Vol. 32, Issue 4 https://doi.org/10.1016/j.ijhydene.2006.06.061	journal	March 2007
Mechanistic Insights into Hydration of Solid Oxides Jing, Yuhang; Matsumoto, Hiroshige; Aluru, Narayana R. Chemistry of Materials, Vol. 30, Issue 1 https://doi.org/10.1021/acs.chemmater.7b03476	journal	December 2017
Readily processed protonic ceramic fuel cells with high performance at low temperatures Duan, C.; Tong, J.; Shang, M. Science, Vol. 349, Issue 6254 https://doi.org/10.1126/science.aab3987	journal	July 2015
High Temperature Electrolysis in Alkaline Cells, Solid Proton Conducting Cells, and Solid Oxide Cells Ebbesen, Sune Dalgaard; Jensen, Søren Højgaard; Hauch, Anne Chemical Reviews, Vol. 114, Issue 21 https://doi.org/10.1021/cr5000865	journal	October 2014
Cogeneration of ethylene and energy in protonic fuel cell with an efficient and stable anode anchored with in-situ exsolved functional metal nanoparticles Liu, Subiao; Liu, Qingxia; Fu, Xian-Zhu Applied Catalysis B: Environmental, Vol. 220 https://doi.org/10.1016/j.apcatb.2017.08.051	journal	January 2018
Development and Demonstration of a Novel Reversible SOFC System for Utility and Micro Grid Energy Storage Mermelstein, Joshua; Posdziech, Oliver Fuel Cells, Vol. 17, Issue 4 https://doi.org/10.1002/fuce.201600185	journal	January 2017
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
High performing triple-conductive Pr ₂ NiO _4+δ anode for proton-conducting steam solid oxide electrolysis cell Li, Wenyuan; Guan, Bo; Ma, Liang Journal of Materials Chemistry A, Vol. 6, Issue 37 https://doi.org/10.1039/C8TA04018D	journal	January 2018
A novel single phase cathode material for a proton-conducting SOFC Tao, Zetian; Bi, Lei; Yan, Litao Electrochemistry Communications, Vol. 11, Issue 3 https://doi.org/10.1016/j.elecom.2009.01.012	journal	March 2009
Cobalt-doped BaZrO3: A single phase air electrode material for reversible solid oxide cells Rao, Yuanyuan; Zhong, Shenghong; He, Fei International Journal of Hydrogen Energy, Vol. 37, Issue 17 https://doi.org/10.1016/j.ijhydene.2012.05.022	journal	September 2012
Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements Chen, Yubo; Zhou, Wei; Ding, Dong Advanced Energy Materials, Vol. 5, Issue 18 https://doi.org/10.1002/aenm.201500537	journal	June 2015
Mixed proton and electron conducting double perovskite anodes for stable and efficient tubular proton ceramic electrolysers Vøllestad, Einar; Strandbakke, Ragnar; Tarach, Mateusz Nature Materials, Vol. 18, Issue 7 https://doi.org/10.1038/s41563-019-0388-2	journal	June 2019
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y. Physical Review B, Vol. 57, Issue 3, p. 1505-1509 https://doi.org/10.1103/PhysRevB.57.1505	journal	January 1998
Experimental and theoretical studies of hydrogen permeation for doped strontium cerates Matsuka, Maki; Braddock, Roger D.; Matsumoto, Hiroshige Solid State Ionics, Vol. 181, Issue 29-30 https://doi.org/10.1016/j.ssi.2010.07.002	journal	September 2010
Symmetric and reversible solid oxide fuel cells Ruiz-Morales, Juan Carlos; Marrero-López, David; Canales-Vázquez, Jesús RSC Advances, Vol. 1, Issue 8 https://doi.org/10.1039/c1ra00284h	journal	January 2011
Achieving High Efficiency and Eliminating Degradation in Solid Oxide Electrochemical Cells Using High Oxygen-Capacity Perovskite Jun, Areum; Kim, Junyoung; Shin, Jeeyoung Angewandte Chemie International Edition, Vol. 55, Issue 40 https://doi.org/10.1002/anie.201606972	journal	September 2016
Bond-length fluctuations and the spin-state transition in $L {CoO}_{3}$ $(L = La,$ Pr, and Nd) Yan, J. -Q.; Zhou, J. -S.; Goodenough, J. B. Physical Review B, Vol. 69, Issue 13 https://doi.org/10.1103/PhysRevB.69.134409	journal	April 2004
Strain Effects on Oxygen Reduction Activity of Pr ₂ NiO ₄ Caused by Gold Bulk Dispersion for Low Temperature Solid Oxide Fuel Cells Kim, Sun Jae; Akbay, Taner; Matsuda, Junko ACS Applied Energy Materials, Vol. 2, Issue 2 https://doi.org/10.1021/acsaem.8b01776	journal	January 2019
A climbing image nudged elastic band method for finding saddle points and minimum energy paths Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904 https://doi.org/10.1063/1.1329672	journal	December 2000
Y-doped BaZrO ₃ as a chemically stable electrolyte for proton-conducting solid oxide electrolysis cells (SOECs) Bi, Lei; Shafi, Shahid P.; Traversa, Enrico Journal of Materials Chemistry A, Vol. 3, Issue 11 https://doi.org/10.1039/C4TA07202B	journal	January 2015
A Highly Efficient Multi-phase Catalyst Dramatically Enhances the Rate of Oxygen Reduction Chen, Yu; Choi, YongMan; Yoo, Seonyoung Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.02.008	journal	May 2018
High-performance Ni–BaZr0.1Ce0.7Y0.1Yb0.1O3−δ (BZCYYb) membranes for hydrogen separation Liu, Mingfei; Sun, Wenping; Li, Xiaxi International Journal of Hydrogen Energy, Vol. 38, Issue 34 https://doi.org/10.1016/j.ijhydene.2013.09.057	journal	November 2013
New, Efficient, and Reliable Air Electrode Material for Proton-Conducting Reversible Solid Oxide Cells Huan, Daoming; Shi, Nai; Zhang, Lu ACS Applied Materials & Interfaces, Vol. 10, Issue 2 https://doi.org/10.1021/acsami.7b16703	journal	January 2018
Review—Materials Degradation of Solid Oxide Electrolysis Cells Chen, Kongfa; Jiang, San Ping Journal of The Electrochemical Society, Vol. 163, Issue 11 https://doi.org/10.1149/2.0101611jes	journal	January 2016
Hybrid-solid oxide electrolysis cell: A new strategy for efficient hydrogen production Kim, Junyoung; Jun, Areum; Gwon, Ohhun Nano Energy, Vol. 44 https://doi.org/10.1016/j.nanoen.2017.11.074	journal	February 2018
Proton conductivity in mixed-conducting BSFZ perovskite from thermogravimetric relaxation Poetzsch, Daniel; Merkle, Rotraut; Maier, Joachim Physical Chemistry Chemical Physics, Vol. 16, Issue 31 https://doi.org/10.1039/C4CP00459K	journal	January 2014
3D Self-Architectured Steam Electrode Enabled Efficient and Durable Hydrogen Production in a Proton-Conducting Solid Oxide Electrolysis Cell at Temperatures Lower Than 600 °C Wu, Wei; Ding, Hanping; Zhang, Yunya Advanced Science, Vol. 5, Issue 11 https://doi.org/10.1002/advs.201800360	journal	August 2018
A review of high temperature co-electrolysis of H ₂ O and CO ₂ to produce sustainable fuels using solid oxide electrolysis cells (SOECs): advanced materials and technology Zheng, Yun; Wang, Jianchen; Yu, Bo Chemical Society Reviews, Vol. 46, Issue 5 https://doi.org/10.1039/C6CS00403B	journal	January 2017
Characterization of PrNiO3-δ as oxygen electrode for SOFCs Vibhu, Vaibhav; Flura, Aurélien; Nicollet, Clément Solid State Sciences, Vol. 81 https://doi.org/10.1016/j.solidstatesciences.2018.04.016	journal	July 2018
Rapid oxygen ion diffusion and surface exchange kinetics in PrBaCo2O5+x with a perovskite related structure and ordered A cations Kim, G.; Wang, S.; Jacobson, A. J. Journal of Materials Chemistry, Vol. 17, Issue 24 https://doi.org/10.1039/b618345j	journal	January 2007
Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers Irvine, John T. S.; Neagu, Dragos; Verbraeken, Maarten C. Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.14	journal	January 2016
Triple-Conducting Layered Perovskites as Cathode Materials for Proton-Conducting Solid Oxide Fuel Cells Kim, Junyoung; Sengodan, Sivaprakash; Kwon, Goeun ChemSusChem, Vol. 7, Issue 10 https://doi.org/10.1002/cssc.201402351	journal	August 2014
Chemically Stable Yttrium and Tin Co-Doped Barium Zirconate Electrolyte for Next Generation High Performance Proton-Conducting Solid Oxide Fuel Cells Sun, Wenping; Liu, Mingfei; Liu, Wei Advanced Energy Materials, Vol. 3, Issue 8 https://doi.org/10.1002/aenm.201201062	journal	April 2013
High-performance composite cathodes with tailored mixed conductivity for intermediate temperature solid oxide fuel cells using proton conducting electrolytes Fabbri, Emiliana; Bi, Lei; Pergolesi, Daniele Energy & Environmental Science, Vol. 4, Issue 12 https://doi.org/10.1039/c1ee02361f	journal	January 2011
Steam electrolysis in a solid oxide electrolysis cell fabricated by the phase-inversion tape casting method Liu, Tong; Wang, Yao; Zhang, Yanxiang Electrochemistry Communications, Vol. 61 https://doi.org/10.1016/j.elecom.2015.10.015	journal	December 2015
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Hydration Properties and Rate Determining Steps of the Oxygen Reduction Reaction of Perovskite-Related Oxides as H ⁺ -SOFC Cathodes Grimaud, A.; Mauvy, F.; Bassat, J. M. Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.101205jes	journal	January 2012
A scandium-doped manganate anode for a proton-conducting solid oxide steam electrolyzer Gan, Lizhen; Ye, Lingting; Liu, Mingzhou RSC Advances, Vol. 6, Issue 1 https://doi.org/10.1039/C5RA19844E	journal	January 2016
High performance of intermediate temperature solid oxide electrolysis cells using Nd2NiO4+δ impregnated scandia stabilized zirconia oxygen electrode Chen, Ting; Liu, Minquan; Yuan, Chun Journal of Power Sources, Vol. 276 https://doi.org/10.1016/j.jpowsour.2014.11.042	journal	February 2015
Proton conducting solid oxide fuel cells with layered PrBa0.5Sr0.5Co2O5+δ perovskite cathode Ding, Hanping; Xue, Xingjian International Journal of Hydrogen Energy, Vol. 35, Issue 6 https://doi.org/10.1016/j.ijhydene.2010.01.046	journal	March 2010
Steam electrolysis by solid oxide electrolysis cells (SOECs) with proton-conducting oxides Bi, Lei; Boulfrad, Samir; Traversa, Enrico Chem. Soc. Rev., Vol. 43, Issue 24 https://doi.org/10.1039/C4CS00194J	journal	January 2014
First-Principles Design of New Electrodes for Proton-Conducting Solid-Oxide Electrochemical Cells: A-Site Doped Sr ₂ Fe _1.5 Mo _0.5 O _6−δ Perovskite Muñoz-García, Ana B.; Pavone, Michele Chemistry of Materials, Vol. 28, Issue 2 https://doi.org/10.1021/acs.chemmater.5b03262	journal	January 2016
Defect Chemistry and Transport within Dense BaCe _0.7 Zr _0.1 Y _0.1 Yb _0.1 O _{3 − δ} (BCZYYb) Proton-Conducting Membranes Zhu, Huayang; Ricote, Sandrine; Duan, Chuancheng Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.1091810jes	journal	January 2018
Preparation and structural study from neutron diffraction data of RCoO ₃ (R = Pr, Tb, Dy, Ho, Er, Tm, Yb, Lu) perovskites Alonso, J. A.; Martínez-Lope, M. J.; de la Calle, C. J. Mater. Chem., Vol. 16, Issue 16 https://doi.org/10.1039/B515607F	journal	January 2006
Oxidation energies of transition metal oxides within the $GGA + U$ framework Wang, Lei; Maxisch, Thomas; Ceder, Gerbrand Physical Review B, Vol. 73, Issue 19 https://doi.org/10.1103/PhysRevB.73.195107	journal	May 2006
Controlling cation segregation in perovskite-based electrodes for high electro-catalytic activity and durability Li, Yifeng; Zhang, Wenqiang; Zheng, Yun Chemical Society Reviews, Vol. 46, Issue 20 https://doi.org/10.1039/C7CS00120G	journal	January 2017
Protonic ceramic electrochemical cells for hydrogen production and electricity generation: exceptional reversibility, stability, and demonstrated faradaic efficiency Choi, Sihyuk; Davenport, Timothy C.; Haile, Sossina M. Energy & Environmental Science, Vol. 12, Issue 1 https://doi.org/10.1039/C8EE02865F	journal	January 2019
Electrode performance and analysis of reversible solid oxide fuel cells with proton conducting electrolyte of BaCe0.5Zr0.3Y0.2O3−δ He, Fei; Song, Duo; Peng, Ranran Journal of Power Sources, Vol. 195, Issue 11 https://doi.org/10.1016/j.jpowsour.2009.12.079	journal	June 2010
A highly active hybrid catalyst modified (La0.60Sr0.40)0.95Co0.20Fe0.80O3-δ cathode for proton conducting solid oxide fuel cells Lei, Libin; Tao, Zetian; Hong, Tao Journal of Power Sources, Vol. 389 https://doi.org/10.1016/j.jpowsour.2018.03.058	journal	June 2018
Co-electrolysis of H ₂ O and CO ₂ in a solid oxide electrolysis cell with hierarchically structured porous electrodes Yang, Chenghao; Li, Jiao; Newkirk, James Journal of Materials Chemistry A, Vol. 3, Issue 31 https://doi.org/10.1039/C5TA03264D	journal	January 2015
Enhanced Sulfur and Coking Tolerance of a Mixed Ion Conductor for SOFCs: BaZr_0.1Ce_0.7Y_0.2–xYb_xO_3–δ Yang, L.; Wang, S.; Blinn, K. Science, Vol. 326, Issue 5949, p. 126-129 https://doi.org/10.1126/science.1174811	journal	October 2009
Layered microstructures based on BaZr0.85Y0.15O3−δ by pulsed laser deposition for metal-supported proton ceramic electrolyser cells Stefan, Elena; Stange, Marit; Denonville, Christelle Journal of Materials Science, Vol. 52, Issue 11 https://doi.org/10.1007/s10853-017-0884-1	journal	February 2017
Lightly doping Ca2+ in perovskite PrCoO3 for tailored spin states and electrical properties Wang, Heng; Li, Guangshe; Guan, Xiangfeng Physical Chemistry Chemical Physics, Vol. 13, Issue 39 https://doi.org/10.1039/c1cp21562k	journal	January 2011

Similar Records

An Unbalanced Battle in Excellence: Revealing Effect of Ni/Co Occupancy on Water Splitting and Oxygen Reduction Reactions in Triple–Conducting Oxides for Protonic Ceramic Electrochemical Cells

Journal Article · Wed Jun 29 00:00:00 EDT 2022 · Small · OSTI ID:1618272

Tang, Wei; Ding, Hanping; Bian, Wenjuan; +11 more

Surface restructuring of a perovskite-type air electrode for reversible protonic ceramic electrochemical cells

Journal Article · Fri Apr 22 00:00:00 EDT 2022 · Nature Communications · OSTI ID:1618272

Pei, Kai; Zhou, Yucun; Xu, Kang; +8 more

An Active and Robust Air Electrode for Reversible Protonic Ceramic Electrochemical Cells

Journal Article · Fri Mar 26 00:00:00 EDT 2021 · ACS Energy Letters · OSTI ID:1618272

Zhou, Yucun; Liu, Enzuo; Chen, Yu; +12 more

Related Subjects

08 - HYDROGEN
hydrogen production
electrochemical cell
proton conduction

Title: Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production

Citation Formats

References (61)

Similar Records

Related Subjects