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Title: SO 2 -Induced Selectivity Change in CO 2 Electroreduction

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.9b03215· OSTI ID:1614351
 [1];  [1];  [2];  [3]; ORCiD logo [3];  [4]; ORCiD logo [1]
  1. Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, Delaware 19716, United States
  2. Department of Physics, Florida A&,M University, Tallahassee, Florida 32307, United States
  3. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States
  4. Department of Chemical Engineering, Columbia University, New York, New York 10027, United States

Not provided.

Research Organization:
Univ. of Delaware, Newark, DE (United States); Columbia Univ., New York, NY (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
DOE Contract Number:
FE0029868; SC0009476; SC0012704
OSTI ID:
1614351
Journal Information:
Journal of the American Chemical Society, Vol. 141, Issue 25; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (46)

Terawatt-scale photovoltaics: Trajectories and challenges journal April 2017
Combining theory and experiment in electrocatalysis: Insights into materials design journal January 2017
A selective and efficient electrocatalyst for carbon dioxide reduction journal January 2014
Electrodeposited Zn Dendrites with Enhanced CO Selectivity for Electrocatalytic CO 2 Reduction journal July 2015
Carbon Monoxide Gas Diffusion Electrolysis that Produces Concentrated C2 Products with High Single-Pass Conversion journal January 2019
Design of an Electrochemical Cell Making Syngas  (CO + H2)  from CO2 and H2O Reduction at Room Temperature journal January 2008
Effects of composition of the micro porous layer and the substrate on performance in the electrochemical reduction of CO2 to CO journal April 2016
The effect of electrolyte composition on the electroreduction of CO 2 to CO on Ag based gas diffusion electrodes journal January 2016
Insights into the Low Overpotential Electroreduction of CO 2 to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer journal November 2017
One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer journal January 2016
Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media journal August 1994
“Deactivation of copper electrode” in electrochemical reduction of CO2 journal September 2005
Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis journal June 2015
Self-Cleaning Catalyst Electrodes for Stabilized CO 2 Reduction to Hydrocarbons journal September 2017
Effect of Gaseous Impurities on the Electrochemical Reduction of CO conference January 2009
Direct Capture of CO2 from Ambient Air journal August 2016
A Process for Capturing CO2 from the Atmosphere journal August 2018
The CO 2 economy: Review of CO 2 capture and reuse technologies journal February 2018
A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction journal October 2018
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface journal May 2018
High Rate, Selective, and Stable Electroreduction of CO 2 to CO in Basic and Neutral Media journal October 2018
CO 2 Electrolysis to CO and O 2 at High Selectivity, Stability and Efficiency Using Sustainion Membranes journal January 2018
CO 2 Conversion to Formic Acid in a Three Compartment Cell with Sustainion™ Membranes journal July 2017
Structural studies of adsorption on metal surfaces journal May 1997
Surface Chemistry of SO 2 on Sn and Sn/Pt(111) Alloys:  Effects of Metal−Metal Bonding on Reactivity toward Sulfur journal November 1998
Photosensitization of TiO2 nanofibers by Ag2S with the synergistic effect of excess surface Ti3+ states for enhanced photocatalytic activity under simulated sunlight journal March 2017
Characterization of nano-sized CdS–Ag2S core-shell nanoparticles using XPS technique journal February 2007
Sulfur-Modulated Tin Sites Enable Highly Selective Electrochemical Reduction of CO2 to Formate journal December 2017
In Situ Studies of the Initial Atmospheric Corrosion of Copper Influence of Humidity, Sulfur Dioxide, Ozone, and Nitrogen Dioxide journal January 2000
Configuration Energies of the d-Block Elements journal May 2000
Electronegativity is the average one-electron energy of the valence-shell electrons in ground-state free atoms journal December 1989
Copper Sulfide Nanocrystals with Tunable Composition by Reduction of Covellite Nanocrystals with Cu + Ions journal November 2013
Absence of Oxidized Phases in Cu under CO Reduction Conditions journal February 2019
The effects of currents and potentials on the selectivities of copper toward carbon dioxide electroreduction journal March 2018
Sulfur-Modified Copper Catalysts for the Electrochemical Reduction of Carbon Dioxide to Formate journal January 2018
On the Role of Sulfur for the Selective Electrochemical Reduction of CO 2 to Formate on CuS x Catalysts journal August 2018
Lateral Adsorbate Interactions Inhibit HCOO while Promoting CO Selectivity for CO 2 Electrocatalysis on Silver journal January 2019
The urgency of the development of CO2 capture from ambient air journal July 2012
Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction journal December 2016
Inhomogeneous Electron Gas journal November 1964
Self-Consistent Equations Including Exchange and Correlation Effects journal November 1965
Projector augmented-wave method journal December 1994
Accurate and simple analytic representation of the electron-gas correlation energy journal June 1992
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Ab initio molecular dynamics for open-shell transition metals journal November 1993
Special points for Brillouin-zone integrations journal June 1976

Cited By (2)

Carbon monoxide electroreduction as an emerging platform for carbon utilization journal December 2019
Engineering Electronic Structure of Stannous Sulfide by Amino‐Functionalized Carbon: Toward Efficient Electrocatalytic Reduction of CO 2 to Formate journal January 2020

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