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Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c9cc03350e· OSTI ID:1613207
 [1];  [2];  [3];  [4];  [4];  [3];  [1];  [3];  [4];  [2];  [1]
  1. Department of Chemistry and Biochemistry; University of California; Los Angeles; USA; California NanoSystems Institute (CNSI)
  2. Department of Fire Protection Engineering; University of Maryland; College Park; USA
  3. Department of Chemistry and Biochemistry; University of California; Los Angeles; USA
  4. Department of Chemistry; Northwestern University; 2145 Sheridan Road; Evanston; USA

A perhydroxylated dodecaborate cluster acts as an inorganic polyol to produce cross-linked polyurethanes, which confers a porous structure and enhanced thermal stability compared to analogous polymers produced from carbon-based polyols.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Synthetic Control Across Length-scales for Advancing Rechargeables (SCALAR); Univ. of California, Los Angeles, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0019381
OSTI ID:
1613207
Journal Information:
ChemComm, Vol. 55, Issue 60; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (44)

Vulcanization and crosslinking in elastomers journal January 1997
Influence of molecular weight and degree of crosslinking on the specific volume and glass temperature of polymers journal February 1955
Crosslinked poly(vinyl alcohol) hydrogels for wound dressing applications: A review of remarkably blended polymers journal January 2015
A novel supramolecular polymer gel constructed by crosslinking pillar[5]arene-based supramolecular polymers through metal–ligand interactions journal January 2015
Hypercrosslinked porous polymer materials: design, synthesis, and applications journal January 2017
Cross-linking dots on metal oxides journal April 2019
Polyurethane types, synthesis and applications – a review journal January 2016
Polyurethanes: A class of modern versatile materials journal November 1992
Structural engineering of polyurethane coatings for high performance applications journal March 2007
Vegetable oil-based rigid polyurethanes and phosphorylated flame-retardants derived from epoxydized soybean oil journal October 2014
Ultra low density and highly crosslinked biocompatible shape memory polyurethane foams
  • Singhal, Pooja; Rodriguez, Jennifer N.; Small, Ward
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 50, Issue 10, p. 724-737 https://doi.org/10.1002/polb.23056
journal March 2012
Synthesis and Properties of Polyurethane Elastomers with Castor Oil as Crosslinker journal November 2009
Synthesis of rigid polyurethane foams with castor oil-based flame retardant polyols journal January 2014
Glycerol-, pentaerythritol- and trimethylolpropane-based polyurethanes and their cellulose carbonate composites prepared via the non-isocyanate route with catalytic carbon dioxide fixation journal January 2013
Dodecahydroxy- c loso -dodecaborate(2−) journal March 2001
A molecular cross-linking approach for hybrid metal oxides journal March 2018
Rapid synthesis of redox-active dodecaborane B 12 (OR) 12 clusters under ambient conditions journal January 2016
Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants journal May 2016
A polymer precursor route to metal borides journal November 1993
Icosahedral boron clusters: a perfect tool for the enhancement of polymer features journal January 2016
New ligand platforms featuring boron-rich clusters as organomimetic substituents journal April 2013
THE ISOLATION OF THE ICOSAHEDRAL B 12 H 12 -2 ION journal June 1960
Synthesis and Applications of Perfunctionalized Boron Clusters journal February 2018
IR-change and yellowing of polyurethane as a result of UV irradiation journal April 2009
Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials journal January 2009
Thermal degradation of urethanes based on 4,4′-diphenylmethane diisocyanate and 1,4-butanediol (MDI/BDO) journal August 1986
Thermal degradation and stability of HTPB-based polyurethane and polyurethaneureas journal June 2003
Thermal degradation of linear polyurethanes and model biscarbamates journal March 1973
Full substitution of petroleum-based polyols by phosphorus-containing soy-based polyols for fabricating highly flame-retardant polyisocyanurate foams journal August 2018
Synthesis, mechanical properties and fire behaviors of rigid polyurethane foam with a reactive flame retardant containing phosphazene and phosphate journal December 2015
Screening flame retardants using milligram-scale flame calorimetry journal May 2018
Reactivity of isocyanates with urethanes: Conditions for allophanate formation journal November 2005
Characterization of hyperporous polyurethane-based gels by non-intrusive mercury porosimetry journal August 2003
Polymer science with transition metals and main group elements: Towards functional, supramolecular inorganic polymeric materials journal December 2001
Linear Hybrid Polymer Building Blocks: Methacrylate-Functionalized Polyhedral Oligomeric Silsesquioxane Monomers and Polymers journal November 1995
Functional Polymeric Materials Based on Main-Group Elements journal February 2019
Polyhedral boron clusters in materials science journal January 2011
Nonclassical Applications of closo -Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage journal February 2019
Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane journal January 2008
Polytellurophenes journal April 2011
A Microporous Metal-Organic Framework Supramolecularly Assembled from a Cu II Dodecaborate Cluster Complex for Selective Gas Separation journal May 2019
Model compounds and monomers for phenylene ether carboranylene ketone (PECK) polymer synthesis: preparation and characterization of boron-arylated ortho-carboranes bearing carboxyphenyl, phenoxyphenyl or benzoylphenyl substituents journal March 2002
Luminescent m -Carborane-Based π-Conjugated Polymer journal April 2009
Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl) journal January 2016