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Controlled Expansion of a Strong-Field Iron Nitride Cluster: Multi-Site Ligand Substitution as a Strategy for Activating Interstitial Nitride Nucleophilicity

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [1];  [2];  [1];  [1];  [1];  [1]
  1. Department of Chemistry and BiochemistryUniversity of California, San Diego 9500 Gilman Drive MC 0358 La Jolla CA 92093 USA
  2. UCSD-CNRS Joint Research Laboratory (UMI 3555)Department of Chemistry and BiochemistryUniversity of California, San Diego 9500 Gilman Drive, Mail Code 0358 La Jolla California 92093 USA
+ Show Author Affiliations

Not provided.

Research Organization:
Univ. of California, San Diego, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0018243
OSTI ID:
1612895
Journal Information:
Angewandte Chemie (International Edition), Vol. 57, Issue 40; ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English

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Zero-valent isocyanides of nickel, palladium and platinum as transition metal σ-type Lewis bases January 2016
The Preparation, Properties and Structure of the Iron Carbonyl Carbide Fe 5 (CO) 15 C December 1962
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Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters March 2013
Metal clusters with exposed and low-coordinate nitride nitrogen atoms October 1980
Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination May 2013
A Well-Defined Isocyano Analogue of HCo(CO) 4 . 2: Relative Brønsted Acidity as a Function of Isocyanide Ligation July 2016
Interaction of nitrogen with iron surfaces I. Fe(100) and Fe(111) July 1977
Predicting Catalysis:  Understanding Ammonia Synthesis from First-Principles Calculations September 2006
Reaktionen an Oberflächen: vom Atomaren zum Komplexen (Nobel-Vortrag) April 2008
Synthesis and Protonation of an Encumbered Iron Tetraisocyanide Dianion May 2015
Clusters and surfaces April 1979
Synthesis and reactivity of an anionic tetrairon nitrido cluster. Crystal and molecular structure of bis(triphenylphosphin)iminium [dodecarbonylnitridotetraferrate] October 1981
The structure of atomic nitrogen adsorbed on Fe(100) December 1982
Isocyano Analogues of [Co(CO) 4 ] n : A Tetraisocyanide of Cobalt Isolated in Three States of Charge April 2010
Molecular Metal Clusters May 1977
Fischer-Tropsch chemistry: structure of a seminal .eta.2-CH cluster derivative, HFe4(.eta.2-CH)(CO)12 June 1980
Catalytic C−H Bond Amination from High-Spin Iron Imido Complexes April 2011
Metal clusters. 25. A uniquely bonded C-H group and reactivity of a low-coordinate carbidic carbon atom June 1980
Testing the Polynuclear Hypothesis: Multielectron Reduction of Small Molecules by Triiron Reaction Sites August 2013
The synthesis of phosphine derivatives of [Fe4N(CO)12]−: Crystal structures of [Fe4N(CO)9(NO)(PPh3)2], [HFe4N (CO)11)PPh3)] and [(PPh3)2N][Fe4N(CO)11(PMe2Ph)] November 1992
Nucleophilic attack and structural rearrangements in some iron carbonyl cluster carbides. Syntheses, structures, and reactions of the tetrahedral four-iron clusters [Fe4(CO)12(.mu.3-COMe)]- and [Fe4(CO)12(CMe)]- October 1982
Catalysis by low oxidation state transition metal (carbonyl) clusters December 2004
The flexible surface. Correlation between reactivity and restructuring ability December 1991

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