Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Aqueous one-pot synthesis of epoxy-functional diblock copolymer worms from a single monomer: new anisotropic scaffolds for potential charge storage applications

Journal Article · · Polymer Chemistry
DOI:https://doi.org/10.1039/c8py01427b· OSTI ID:1612145
 [1];  [2];  [3];  [2];  [3];  [1]
  1. Dainton Building; Department of Chemistry; University of Sheffield; Sheffield; UK
  2. School of Applied and Engineering Physics; Cornell University; Ithaca; USA
  3. Materials Science and Engineering; Cornell University; Ithaca; USA

The one-pot synthesis of highly anisotropic epoxy-functional diblock copolymer worms is achieved directly in water using asinglemonomer (glycidyl methacrylate).

Research Organization:
Cornell Univ., Ithaca, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0014336
OSTI ID:
1612145
Journal Information:
Polymer Chemistry, Vol. 10, Issue 2; ISSN 1759-9954
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (41)

Radical Polymers for Organic Electronic Devices: A Radical Departure from Conjugated Polymers? June 2009
Nitroxide radical polymers – a versatile material class for high-tech applications January 2018
A radical advance for conducting polymers March 2018
Charge Transport in Conjugated Polymers with Pendent Stable Radical Groups June 2018
Rechargeable batteries with organic radical cathodes June 2002
A nonconjugated radical polymer glass with high electrical conductivity March 2018
Modular design of profluorescent polymer sensors January 2015
Impact of the synthesis method on the solid-state charge transport of radical polymers January 2018
Effects of shape and flexibility of conductive fillers in nanocomposites on percolating network formation and electrical conductivity March 2016
Tailoring percolating conductive networks of natural rubber composites for flexible strain sensors via a cellulose nanocrystal templated assembly January 2016
A Critical Appraisal of RAFT-Mediated Polymerization-Induced Self-Assembly March 2016
Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization July 2014
Self-assembly of block copolymers January 2012
Micellization of block copolymers July 2003
Polymeric filomicelles and nanoworms: two decades of synthesis and application January 2016
Controlled/Living Radical Polymerization in Dispersed Systems: An Update August 2015
Block copolymer synthesis by controlled/living radical polymerisation in heterogeneous systems January 2016
Polymerization-induced self-assembly of block copolymer nanoparticles via RAFT non-aqueous dispersion polymerization January 2016
Amphiphilic block copolymer nano-fibers via RAFT-mediated polymerization in aqueous dispersed system January 2010
Influence of the stirring speed and CaCl2 concentration on the nano-object morphologies obtained via RAFT-mediated aqueous emulsion polymerization in the presence of a water-soluble macroRAFT agent May 2011
Well-Defined Amphiphilic Block Copolymers and Nano-objects Formed in Situ via RAFT-Mediated Aqueous Emulsion Polymerization June 2011
One-Pot Synthesis of Poly(methacrylic acid- co -poly(ethylene oxide) methyl ether methacrylate)- b -polystyrene Amphiphilic Block Copolymers and Their Self-Assemblies in Water via RAFT-Mediated Radical Emulsion Polymerization. A Kinetic Study October 2011
Toward a Better Understanding of the Parameters that Lead to the Formation of Nonspherical Polystyrene Particles via RAFT-Mediated One-Pot Aqueous Emulsion Polymerization May 2012
The Effect of Hydrophile Topology in RAFT-Mediated Polymerization-Induced Self-Assembly February 2016
Multifunctional Nanoworms and Nanorods through a One-Step Aqueous Dispersion Polymerization February 2014
Facile production of nanoaggregates with tuneable morphologies from thermoresponsive P(DEGMA-co-HPMA) January 2016
Facile access to thermoresponsive filomicelles with tuneable cores January 2016
Surfactant-free RAFT emulsion polymerization using a novel biocompatible thermoresponsive polymer January 2017
Effect of Monomer Solubility on the Evolution of Copolymer Morphology during Polymerization-Induced Self-Assembly in Aqueous Solution January 2017
Synthesis of well-defined epoxy-functional spherical nanoparticles by RAFT aqueous emulsion polymerization January 2017
Predictive Phase Diagrams for RAFT Aqueous Dispersion Polymerization: Effect of Block Copolymer Composition, Molecular Weight, and Copolymer Concentration June 2012
Can percolation theory explain the gelation behavior of diblock copolymer worms? January 2018
From a Water-Immiscible Monomer to Block Copolymer Nano-Objects via a One-Pot RAFT Aqueous Dispersion Polymerization Formulation January 2013
Form factors of block copolymer micelles with spherical, ellipsoidal and cylindrical cores June 2000
Amphiphilic Poly(ethylene oxide) Macromolecular RAFT Agent as a Stabilizer and Control Agent in ab Initio Batch Emulsion Polymerization June 2008
Poly(glycerol monomethacrylate)–Poly(benzyl methacrylate) Diblock Copolymer Nanoparticles via RAFT Emulsion Polymerization: Synthesis, Characterization, and Interfacial Activity August 2014
Determining the Effective Density and Stabilizer Layer Thickness of Sterically Stabilized Nanoparticles July 2016
Soft and rigid core latex nanoparticles prepared by RAFT-mediated surfactant-free emulsion polymerization for cellulose modification – a comparative study January 2017
Electron spin resonance studies of spin-labeled polymers. 11. Segmental and end-group mobility of some acrylic ester polymers July 1976
Close Packing of Nitroxide Radicals in Stable Organic Radical Polymeric Materials April 2015
Tuning Hydrophobicity To Program Block Copolymer Assemblies from the Inside Out January 2017