A Metal–Organic Framework with Tetrahedral Aluminate Sites as a Single-Ion Li + Solid Electrolyte

Fischer, Sabrina; Roeser, Jérôme; Lin, Terri C.; DeBlock, Ryan H.; Lau, Jonathan; Dunn, Bruce S.; Hoffmann, Frank; Fröba, Michael; Thomas, Arne; Tolbert, Sarah H.

doi:10.1002/anie.201808885

A Metal–Organic Framework with Tetrahedral Aluminate Sites as a Single-Ion Li ⁺ Solid Electrolyte

Journal Article · 17 December 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201808885· OSTI ID:1612113

Fischer, Sabrina ^[1]; Roeser, Jérôme ^[2]; Lin, Terri C. ^[3]; DeBlock, Ryan H. ^[4]; Lau, Jonathan ^[4]; Dunn, Bruce S. ^[4]; Hoffmann, Frank ^[5]; Fröba, Michael ^[5]; Thomas, Arne ^[2]; ^[6]

Department of Chemistry and BiochemistryUniversity of California Los Angeles Los Angeles CA 90095-1569 USA; Department of ChemistryTechnische Universität Berlin, BA2 Hardenbergstraße 40 10623 Berlin Germany
Department of ChemistryTechnische Universität Berlin, BA2 Hardenbergstraße 40 10623 Berlin Germany
Department of Chemistry and BiochemistryUniversity of California Los Angeles Los Angeles CA 90095-1569 USA
Department of Materials Science and EngineeringUniversity of California Los Angeles Los Angeles CA 90095-1595 USA
Institute of Inorganic and Applied ChemistryUniversity of Hamburg Martin-Luther-King Platz 6 20146 Hamburg Germany
Department of Chemistry and BiochemistryUniversity of California Los Angeles Los Angeles CA 90095-1569 USA; Department of Materials Science and EngineeringUniversity of California Los Angeles Los Angeles CA 90095-1595 USA

Not provided.

Research Organization:: Univ. of California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0014213

OSTI ID:: 1612113

Journal Information:: Angewandte Chemie (International Edition), Vol. 57, Issue 51; ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (30)

Scandium/Alkaline Metal–Organic Frameworks: Adsorptive Properties and Ionic Conductivity Cepeda, Javier; Pérez-Yáñez, Sonia; Beobide, Garikoitz Chemistry of Materials, Vol. 28, Issue 8 https://doi.org/10.1021/acs.chemmater.5b03458	journal	April 2016
RASPA: molecular simulation software for adsorption and diffusion in flexible nanoporous materials Dubbeldam, David; Calero, Sofía; Ellis, Donald E. Molecular Simulation, Vol. 42, Issue 2 https://doi.org/10.1080/08927022.2015.1010082	journal	February 2015
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Ligand Substitution Reactions at Inorganic Centers ^† Richens, David T. Chemical Reviews, Vol. 105, Issue 6 https://doi.org/10.1021/cr030705u	journal	June 2005
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Ionic Conductivity in the Metal-Organic Framework UiO-66 by Dehydration and Insertion of Lithium tert -Butoxide Ameloot, Rob; Aubrey, Michael; Wiers, Brian M. Chemistry - A European Journal, Vol. 19, Issue 18 https://doi.org/10.1002/chem.201300326	journal	March 2013
3D Anionic Silicate Covalent Organic Framework with srs Topology Yahiaoui, Oussama; Fitch, Andrew N.; Hoffmann, Frank Journal of the American Chemical Society, Vol. 140, Issue 16 https://doi.org/10.1021/jacs.8b01774	journal	April 2018
Anionische, mikroporöse Polymernetzwerke durch Polymerisation eines schwach koordinierenden Anions Fischer, Sabrina; Schmidt, Johannes; Strauch, Peter Angewandte Chemie, Vol. 125, Issue 46 https://doi.org/10.1002/ange.201303045	journal	September 2013
UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations Rappe, A. K.; Casewit, C. J.; Colwell, K. S. Journal of the American Chemical Society, Vol. 114, Issue 25, p. 10024-10035 https://doi.org/10.1021/ja00051a040	journal	December 1992
The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets O’Keeffe, Michael; Peskov, Maxim A.; Ramsden, Stuart J. Accounts of Chemical Research, Vol. 41, Issue 12, p. 1782-1789 https://doi.org/10.1021/ar800124u	journal	December 2008
Ionic Covalent Organic Frameworks with Spiroborate Linkage Du, Ya; Yang, Haishen; Whiteley, Justin Michael Angewandte Chemie International Edition, Vol. 55, Issue 5 https://doi.org/10.1002/anie.201509014	journal	December 2015
Dihydroxybenzoquinone as Linker for the Synthesis of Permanently Porous Aluminum Metal–Organic Frameworks Halis, Selda; Inge, A. Ken; Dehning, Niklas Inorganic Chemistry, Vol. 55, Issue 15 https://doi.org/10.1021/acs.inorgchem.6b00661	journal	July 2016
Topological Analysis of Metal–Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity Principle Li, Mian; Li, Dan; O’Keeffe, Michael Chemical Reviews, Vol. 114, Issue 2 https://doi.org/10.1021/cr400392k	journal	November 2013
Three-Dimensional Anionic Cyclodextrin-Based Covalent Organic Frameworks Zhang, Yuanyuan; Duan, Jiyun; Ma, Dou Angewandte Chemie, Vol. 129, Issue 51 https://doi.org/10.1002/ange.201710633	journal	November 2017
Crystal chemistry of aluminium carboxylates: From molecular species towards porous infinite three-dimensional networks Loiseau, Thierry; Volkringer, Christophe; Haouas, Mohamed Comptes Rendus Chimie, Vol. 18, Issue 12 https://doi.org/10.1016/j.crci.2015.08.006	journal	December 2015
Single-Ion Li ⁺ , Na ⁺ , and Mg ²⁺ Solid Electrolytes Supported by a Mesoporous Anionic Cu–Azolate Metal–Organic Framework Park, Sarah S.; Tulchinsky, Yuri; Dincă, Mircea Journal of the American Chemical Society, Vol. 139, Issue 38 https://doi.org/10.1021/jacs.7b06197	journal	September 2017
Anionic porous organic frameworks as advanced functional adsorbents for CO ₂ and organic micropollutants in water Liu, Yiqun; Landskron, Kai Journal of Materials Chemistry A, Vol. 5, Issue 45 https://doi.org/10.1039/C7TA07249J	journal	January 2017
High-symmetry embeddings of interpenetrating periodic nets. Essential rings and patterns of catenation Bonneau, Charlotte; O'Keeffe, Michael Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1 https://doi.org/10.1107/S2053273314019950	journal	January 2015
A Solid Lithium Electrolyte via Addition of Lithium Isopropoxide to a Metal–Organic Framework with Open Metal Sites Wiers, Brian M.; Foo, Maw-Lin; Balsara, Nitash P. Journal of the American Chemical Society, Vol. 133, Issue 37 https://doi.org/10.1021/ja205827z	journal	September 2011
An Anionic Microporous Polymer Network Prepared by the Polymerization of Weakly Coordinating Anions Fischer, Sabrina; Schmidt, Johannes; Strauch, Peter Angewandte Chemie International Edition, Vol. 52, Issue 46 https://doi.org/10.1002/anie.201303045	journal	October 2013
Charged Porous Polymers using a Solid CO Cross-Coupling Reaction Zhang, Pengfei; Jiang, Xueguang; Wan, Shun Chemistry - A European Journal, Vol. 21, Issue 37 https://doi.org/10.1002/chem.201501814	journal	July 2015
Recent advances in application of 27 Al NMR spectroscopy to materials science Haouas, Mohamed; Taulelle, Francis; Martineau, Charlotte Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 94-95 https://doi.org/10.1016/j.pnmrs.2016.01.003	journal	May 2016
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Arora, Pankaj; White, Ralph E.; Doyle, Marc Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667 https://doi.org/10.1149/1.1838857	journal	January 1998
A new aluminium-based microporous metal–organic framework: Al(BTB) (BTB=1,3,5-benzenetrisbenzoate) Reinsch, Helge; Krüger, Martin; Wack, Julia Microporous and Mesoporous Materials, Vol. 157 https://doi.org/10.1016/j.micromeso.2011.05.029	journal	July 2012
Ionic Covalent Organic Frameworks with Spiroborate Linkage Du, Ya; Yang, Haishen; Whiteley, Justin Michael Angewandte Chemie, Vol. 128, Issue 5 https://doi.org/10.1002/ange.201509014	journal	December 2015
Imidazolium formation from the reaction of N-heterocyclic carbene stabilised group 13 trihydride complexes with organic acids Cole, Marcus L.; Hibbs, David E.; Jones, Cameron Inorganica Chimica Acta, Vol. 358, Issue 1 https://doi.org/10.1016/j.ica.2004.07.036	journal	January 2005
Anionic silicate organic frameworks constructed from hexacoordinate silicon centres Roeser, Jérôme; Prill, Dragica; Bojdys, Michael J. Nature Chemistry, Vol. 9, Issue 10 https://doi.org/10.1038/nchem.2771	journal	May 2017
Molecular Networks Based on CN Coordination Bonds Karsch, Markus; Lund, Henrik; Schulz, Axel European Journal of Inorganic Chemistry, Vol. 2012, Issue 33 https://doi.org/10.1002/ejic.201200427	journal	September 2012
Three-Dimensional Anionic Cyclodextrin-Based Covalent Organic Frameworks Zhang, Yuanyuan; Duan, Jiyun; Ma, Dou Angewandte Chemie International Edition, Vol. 56, Issue 51 https://doi.org/10.1002/anie.201710633	journal	November 2017
Tetraarylborate polymer networks as single-ion conducting solid electrolytes Van Humbeck, Jeffrey F.; Aubrey, Michael L.; Alsbaiee, Alaaeddin Chemical Science, Vol. 6, Issue 10 https://doi.org/10.1039/C5SC02052B	journal	January 2015

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