High-capacity lithium sulfur battery and beyond: a review of metal anode protection layers and perspective of solid-state electrolytes

Wang, Yang; Sahadeo, Emily; Rubloff, Gary; Lin, Chuan-Fu; Lee, Sang Bok

doi:10.1007/s10853-018-3093-7

High-capacity lithium sulfur battery and beyond: a review of metal anode protection layers and perspective of solid-state electrolytes

Journal Article · 05 November 2018 · Journal of Materials Science

DOI:https://doi.org/10.1007/s10853-018-3093-7· OSTI ID:1610538

; ; ; ;

Not provided.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES); Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0001160

OSTI ID:: 1610538

Journal Information:: Journal of Materials Science, Vol. 54, Issue 5; ISSN 0022-2461

Publisher:: Springer

Country of Publication:: United States

Language:: English

References (95)

Li–O₂ and Li–S batteries with high energy storage No authors listed Nature Materials https://doi.org/10.1038/nmat3191		January 2012
Recent Progress in the Design of Advanced Cathode Materials and Battery Models for High-Performance Lithium-X (X = O ₂ , S, Se, Te, I ₂ , Br ₂ ) Batteries No authors listed Advanced Materials https://doi.org/10.1002/adma.201606454		May 2017
Research Progress toward the Practical Applications of Lithium–Sulfur Batteries No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.7b06208		July 2017
Review on Li-Sulfur Battery Systems: an Integral Perspective No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201500212		May 2015
Reviving the lithium metal anode for high-energy batteries No authors listed Nature Nanotechnology https://doi.org/10.1038/nnano.2017.16		March 2017
Lithium metal anodes for rechargeable batteries No authors listed Energy Environ. Sci. https://doi.org/10.1039/C3EE40795K		January 2014
Anodes for Rechargeable Lithium-Sulfur Batteries No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201402273		April 2015
A Review of Solid Electrolyte Interphases on Lithium Metal Anode No authors listed Advanced Science https://doi.org/10.1002/advs.201500213		November 2015
Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode No authors listed Nature Communications https://doi.org/10.1038/ncomms10992		March 2016
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries No authors listed Journal of Power Sources https://doi.org/10.1016/S0378-7753(00)00431-6		August 2000
Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid No authors listed Advanced Materials https://doi.org/10.1002/adma.201701169		July 2017
Anode Improvement in Rechargeable Lithium-Sulfur Batteries No authors listed Advanced Materials https://doi.org/10.1002/adma.201700542		June 2017
Nanoscale Protection Layers To Mitigate Degradation in High-Energy Electrochemical Energy Storage Systems No authors listed Accounts of Chemical Research https://doi.org/10.1021/acs.accounts.7b00524		January 2018
Insight into lithium–metal anodes in lithium–sulfur batteries with a fluorinated ether electrolyte No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C5TA03195H		January 2015
High rate and stable cycling of lithium metal anode No authors listed Nature Communications https://doi.org/10.1038/ncomms7362		February 2015
Li 2 S 5 -based ternary-salt electrolyte for robust lithium metal anode No authors listed Energy Storage Materials https://doi.org/10.1016/j.ensm.2016.01.007		April 2016
Long term stability of Li-S batteries using high concentration lithium nitrate electrolytes No authors listed Nano Energy https://doi.org/10.1016/j.nanoen.2017.09.015		October 2017
Lithium battery chemistries enabled by solid-state electrolytes No authors listed Nature Reviews Materials https://doi.org/10.1038/natrevmats.2016.103		February 2017
Moving to a Solid-State Configuration: A Valid Approach to Making Lithium-Sulfur Batteries Viable for Practical Applications No authors listed Advanced Materials https://doi.org/10.1002/adma.201002584		September 2010
A review on anode for lithium-sulfur batteries: Progress and prospects No authors listed Chemical Engineering Journal https://doi.org/10.1016/j.cej.2018.04.112		September 2018
Lithium metal protected by atomic layer deposition metal oxide for high performance anodes No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C7TA03116E		January 2017
Long lifespan lithium metal anodes enabled by Al2O3 sputter coating No authors listed Energy Storage Materials https://doi.org/10.1016/j.ensm.2017.08.001		January 2018
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition No authors listed ACS Nano https://doi.org/10.1021/acsnano.5b02166		May 2015
Protected lithium anode with porous Al ₂ O ₃ layer for lithium–sulfur battery No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C5TA01490E		January 2015
Dendrite-free Li deposition using trace-amounts of water as an electrolyte additive No authors listed Nano Energy https://doi.org/10.1016/j.nanoen.2015.04.009		July 2015
Electrochemical Deposition of Very Smooth Lithium Using Nonaqueous Electrolytes Containing HF No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/1.1836979		January 1996
In Situ and Quantitative Characterization of Solid Electrolyte Interphases No authors listed Nano Letters https://doi.org/10.1021/nl404471v		February 2014
Stabilizing Li/electrolyte interface with a transplantable protective layer based on nanoscale LiF domains No authors listed Nano Energy https://doi.org/10.1016/j.nanoen.2017.07.052		September 2017
Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon No authors listed Nano Letters https://doi.org/10.1021/acs.nanolett.7b01020		May 2017
An In Vivo Formed Solid Electrolyte Surface Layer Enables Stable Plating of Li Metal No authors listed Joule https://doi.org/10.1016/j.joule.2017.11.009		December 2017
Pre-modified Li3PS4 based interphase for lithium anode towards high-performance Li-S battery No authors listed Energy Storage Materials https://doi.org/10.1016/j.ensm.2017.09.007		March 2018
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes No authors listed Advanced Materials https://doi.org/10.1002/adma.201504526		December 2015
Li metal coated with amorphous Li3PO4 via magnetron sputtering for stable and long-cycle life lithium metal batteries No authors listed Journal of Power Sources https://doi.org/10.1016/j.jpowsour.2016.11.097		February 2017
A lithium anode protection guided highly-stable lithium–sulfur battery No authors listed Chem. Commun. https://doi.org/10.1039/C4CC05535G		January 2014
Protection of lithium metal surfaces using tetraethoxysilane No authors listed J. Mater. Chem. https://doi.org/10.1039/C0JM02305A		January 2011
2D MoS2 as an efficient protective layer for lithium metal anodes in high-performance Li–S batteries No authors listed Nature Nanotechnology https://doi.org/10.1038/s41565-018-0061-y		February 2018
Lanthanum Nitrate As Electrolyte Additive To Stabilize the Surface Morphology of Lithium Anode for Lithium–Sulfur Battery No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.5b12231		March 2016
Mixed Ionic and Electronic Conductor for Li-Metal Anode Protection No authors listed Advanced Materials https://doi.org/10.1002/adma.201705105		January 2018
Electrochemical Interphases for High-Energy Storage Using Reactive Metal Anodes No authors listed Accounts of Chemical Research https://doi.org/10.1021/acs.accounts.7b00484		December 2017
Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.6b13314		March 2017
Dendrite-Free Lithium Deposition for Lithium Metal Anodes with Interconnected Microsphere Protection No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.7b01304		July 2017
Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes No authors listed Advanced Materials https://doi.org/10.1002/adma.201603755		October 2016
Enhanced cycle performance of a Li–S battery based on a protected lithium anode No authors listed J. Mater. Chem. A https://doi.org/10.1039/C4TA04172K		January 2014
High Polarity Poly(vinylidene difluoride) Thin Coating for Dendrite-Free and High-Performance Lithium Metal Anodes No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201701482		September 2017
A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201710806		January 2018
High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating No authors listed ACS Energy Letters https://doi.org/10.1021/acsenergylett.6b00456		November 2016
Implantable Solid Electrolyte Interphase in Lithium-Metal Batteries No authors listed Chem https://doi.org/10.1016/j.chempr.2017.01.003		February 2017
Improved cycling performances with high sulfur loading enabled by pre-treating lithium anode No authors listed Ionics https://doi.org/10.1007/s11581-015-1543-7		September 2015
Designable ultra-smooth ultra-thin solid-electrolyte interphases of three alkali metal anodes No authors listed Nature Communications https://doi.org/10.1038/s41467-018-03466-8		April 2018
Stable Artificial Solid Electrolyte Interphases for Lithium Batteries No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.6b03687		May 2017
Electrochemically Controlled Solid Electrolyte Interphase Layers Enable Superior Li–S Batteries No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.8b07248		June 2018
Stabilization of Lithium Metal Anodes by Hybrid Artificial Solid Electrolyte Interphase No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.7b01496		July 2017
Artificial Soft-Rigid Protective Layer for Dendrite-Free Lithium Metal Anode No authors listed Advanced Functional Materials https://doi.org/10.1002/adfm.201705838		January 2018
A simple composite protective layer coating that enhances the cycling stability of lithium metal batteries No authors listed Journal of Power Sources https://doi.org/10.1016/j.jpowsour.2015.03.004		June 2015
Robust Metallic Lithium Anode Protection by the Molecular-Layer-Deposition Technique No authors listed Small Methods https://doi.org/10.1002/smtd.201700417		March 2018
An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes No authors listed Advanced Materials https://doi.org/10.1002/adma.201605531		December 2016
Core–Shell Nanoparticle Coating as an Interfacial Layer for Dendrite-Free Lithium Metal Anodes No authors listed ACS Central Science https://doi.org/10.1021/acscentsci.6b00389		January 2017
Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode No authors listed Nano Letters https://doi.org/10.1021/nl503125u		September 2014
Magnetron sputtering amorphous carbon coatings on metallic lithium: Towards promising anodes for lithium secondary batteries No authors listed Journal of Power Sources https://doi.org/10.1016/j.jpowsour.2014.04.147		November 2014
Interconnected hollow carbon nanospheres for stable lithium metal anodes No authors listed Nature Nanotechnology https://doi.org/10.1038/nnano.2014.152		July 2014
Controlled Lithium Dendrite Growth by a Synergistic Effect of Multilayered Graphene Coating and an Electrolyte Additive No authors listed Chemistry of Materials https://doi.org/10.1021/cm503447u		April 2015
Carbon enables the practical use of lithium metal in a battery No authors listed Carbon https://doi.org/10.1016/j.carbon.2017.08.027		October 2017
Designing solid-electrolyte interphases for lithium sulfur electrodes using ionic shields No authors listed Nano Energy https://doi.org/10.1016/j.nanoen.2017.10.018		November 2017
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja312241y		March 2013
Li ⁺ -Permeable Film on Lithium Anode for Lithium Sulfur Battery No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.7b10306		October 2017
Volumetric variation confinement: surface protective structure for high cyclic stability of lithium metal electrodes No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C5TA10050J		January 2016
Trimethylsilyl Chloride-Modified Li Anode for Enhanced Performance of Li–S Cells No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.6b02612		June 2016
Dendrite-Free Lithium Anode via a Homogenous Li-Ion Distribution Enabled by a Kimwipe Paper No authors listed Advanced Sustainable Systems https://doi.org/10.1002/adsu.201600034		January 2017
The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/1.1850854		January 2005
A shuttle effect free lithium sulfur battery based on a hybrid electrolyte No authors listed Phys. Chem. Chem. Phys. https://doi.org/10.1039/C4CP03694H		January 2014
Polysulfide-Shuttle Control in Lithium-Sulfur Batteries with a Chemically/Electrochemically Compatible NaSICON-Type Solid Electrolyte No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201601392		August 2016
Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface No authors listed Science Advances https://doi.org/10.1126/sciadv.1601659		April 2017
A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles No authors listed Nature Communications https://doi.org/10.1038/ncomms10101		December 2015
Performance Improvement of Magnesium Sulfur Batteries with Modified Non-Nucleophilic Electrolytes No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201401155		October 2014
Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.6b00614		February 2017
Mapping the Challenges of Magnesium Battery No authors listed The Journal of Physical Chemistry Letters https://doi.org/10.1021/acs.jpclett.6b00384		April 2016
On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions No authors listed Journal of Electroanalytical Chemistry https://doi.org/10.1016/S0022-0728(99)00146-1		May 1999
Interfacial Insight from Operando XAS/TEM for Magnesium Metal Deposition with Borohydride Electrolytes No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.7b01189		August 2017
Magnesium(II) Bis(trifluoromethane sulfonyl) Imide-Based Electrolytes with Wide Electrochemical Windows for Rechargeable Magnesium Batteries No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/am405619v		March 2014
Evaluation of (CF ₃ SO ₂ ) ₂ N ⁻ (TFSI) Based Electrolyte Solutions for Mg Batteries No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/2.0161513jes		January 2015
Degradation Mechanisms of Magnesium Metal Anodes in Electrolytes Based on (CF ₃ SO ₂ ) ₂ N ^– at High Current Densities No authors listed Langmuir https://doi.org/10.1021/acs.langmuir.7b01051		July 2017
Passivation Dynamics in the Anisotropic Deposition and Stripping of Bulk Magnesium Electrodes During Electrochemical Cycling No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.5b04487		August 2015
Dendrite Growth in Mg Metal Cells Containing Mg(TFSI) ₂ /Glyme Electrolytes No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/2.1471809jes		January 2018
Passivation Layer Formation of Magnesium Metal Negative Electrodes for Rechargeable Magnesium Batteries No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/2.1191713jes		January 2017
Study of Electrochemical Phenomena Observed at the Mg Metal/Electrolyte Interface No authors listed ACS Energy Letters https://doi.org/10.1021/acsenergylett.6b00549		December 2016
Characterisation of the surface chemistry of magnesium exposed to the ambient atmosphere No authors listed Surface and Interface Analysis https://doi.org/10.1002/sia.2463		January 2006
Tuning the Reversibility of Mg Anodes via Controlled Surface Passivation by H ₂ O/Cl ^– in Organic Electrolytes No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.6b03227		October 2016
Elucidating Solvation Structures for Rational Design of Multivalent Electrolytes—A Review No authors listed Topics in Current Chemistry https://doi.org/10.1007/s41061-018-0195-2		April 2018
Instability at the Electrode/Electrolyte Interface Induced by Hard Cation Chelation and Nucleophilic Attack No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.7b03404		October 2017
Reaction Pathways for Solvent Decomposition on Magnesium Anodes No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/acs.jpcc.8b01752		April 2018
Hexafluorophosphate-Based Solutions for Mg Batteries and the Importance of Chlorides No authors listed Langmuir https://doi.org/10.1021/acs.langmuir.7b01609		July 2017
Enhancing the Reversibility of Mg/S Battery Chemistry through Li ⁺ Mediation No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.5b07820		September 2015
Existence of Solid Electrolyte Interphase in Mg Batteries: Mg/S Chemistry as an Example No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.8b02425		March 2018
Reducing Mg Anode Overpotential via Ion Conductive Surface Layer Formation by Iodine Additive No authors listed Advanced Energy Materials https://doi.org/10.1002/aenm.201701728		October 2017
An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes No authors listed Nature Chemistry https://doi.org/10.1038/s41557-018-0019-6		April 2018

Similar Records

Realizing high-capacity all-solid-state lithium-sulfur batteries using a low-density inorganic solid-state electrolyte

Journal Article · 2023 · Nature Communications · OSTI ID:1968540

Wang, Daiwei; Jhang, Li-Ji; Kou, Rong; +7 more

Solid Electrolyte Lithium Phosphous Oxynitride as a Protective Nanocladding Layer for 3D High-Capacity Conversion Electrodes

Journal Article · 2016 · ACS Nano · OSTI ID:1387540

Lin, Chuan-Fu; Noked, Malachi; Kozen, Alexander C.; +6 more

Related Subjects

Materials Science

High-capacity lithium sulfur battery and beyond: a review of metal anode protection layers and perspective of solid-state electrolytes

Citation Formats

References (95)

Similar Records

Related Subjects