Systematic control of the rate of singlet fission within 6,13-diphenylpentacene aggregates with PbS quantum dot templates

Wang, Chen; Kodaimati, Mohamad S.; Lian, Shichen; Weiss, Emily A.

doi:10.1039/c8fd00157j

Systematic control of the rate of singlet fission within 6,13-diphenylpentacene aggregates with PbS quantum dot templates

Journal Article · 01 January 2019 · Faraday Discussions

DOI:https://doi.org/10.1039/c8fd00157j· OSTI ID:1610452

^[1]; Kodaimati, Mohamad S. ^[2]; Lian, Shichen ^[2]; ^[2]

Department of Chemistry and Biochemistry; City University of New York; Queens College; Flushing; USA; DOE/OSTI
Department of Chemistry; Northwestern University; Evanston; USA

Perturbation of molecular packing and dielectric environment at a quantum dot surface can promote singlet fission in diphenylpentacene aggregates.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Bio-Inspired Energy Science (CBES); Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0000989

OSTI ID:: 1610452

Journal Information:: Faraday Discussions, Journal Name: Faraday Discussions Vol. 216; ISSN 1359-6640; ISSN FDISE6

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (44)

Exceeding the Shockley–Queisser limit in solar energy conversion Nelson, Cory A.; Monahan, Nicholas R.; Zhu, X. -Y. Energy & Environmental Science, Vol. 6, Issue 12 https://doi.org/10.1039/c3ee42098a	journal	January 2013
Observing the Multiexciton State in Singlet Fission and Ensuing Ultrafast Multielectron Transfer Chan, W. -L.; Ligges, M.; Jailaubekov, A. Science, Vol. 334, Issue 6062 https://doi.org/10.1126/science.1213986	journal	December 2011
Thermodynamic Limit of Exciton Fission Solar Cell Efficiency Tayebjee, Murad J. Y.; Gray-Weale, Angus A.; Schmidt, Timothy W. The Journal of Physical Chemistry Letters, Vol. 3, Issue 19 https://doi.org/10.1021/jz301069u	journal	September 2012
Steric-Hindrance-Driven Shape Transition in PbS Quantum Dots: Understanding Size-Dependent Stability Choi, Hyekyoung; Ko, Jae-Hyeon; Kim, Yong-Hyun Journal of the American Chemical Society, Vol. 135, Issue 14 https://doi.org/10.1021/ja400948t	journal	March 2013
Sub-Nanosecond Resonance Energy Transfer in the Near-Infrared within Self-Assembled Conjugates of PbS Quantum Dots and Cyanine Dye J-Aggregates Wang, Chen; Weiss, Emily A. Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b04087	journal	July 2016
Solar conversion efficiency of photovoltaic and photoelectrolysis cells with carrier multiplication absorbers Hanna, M. C.; Nozik, A. J. Journal of Applied Physics, Vol. 100, Issue 7 https://doi.org/10.1063/1.2356795	journal	October 2006
Aqueous Colloidal Acene Nanoparticles: A New Platform for Studying Singlet Fission Mastron, Joseph N.; Roberts, Sean T.; McAnally, R. Eric The Journal of Physical Chemistry B, Vol. 117, Issue 49 https://doi.org/10.1021/jp4057972	journal	July 2013
Charge Carrier Resolved Relaxation of the First Excitonic State in CdSe Quantum Dots Probed with Near-Infrared Transient Absorption Spectroscopy ^† McArthur, Eric A.; Morris-Cohen, Adam J.; Knowles, Kathryn E. The Journal of Physical Chemistry B, Vol. 114, Issue 45 https://doi.org/10.1021/jp102101f	journal	November 2010
Real-time observation of multiexcitonic states in ultrafast singlet fission using coherent 2D electronic spectroscopy Bakulin, Artem A.; Morgan, Sarah E.; Kehoe, Tom B. Nature Chemistry, Vol. 8, Issue 1 https://doi.org/10.1038/nchem.2371	journal	October 2015
Striking the right balance of intermolecular coupling for high-efficiency singlet fission Pensack, Ryan D.; Tilley, Andrew J.; Grieco, Christopher Chemical Science, Vol. 9, Issue 29 https://doi.org/10.1039/C8SC00293B	journal	January 2018
The Dynamics of Singlet Fission in Crystalline Tetracene and Covalent Analogs Burdett, Jonathan J.; Bardeen, Christopher J. Accounts of Chemical Research, Vol. 46, Issue 6 https://doi.org/10.1021/ar300191w	journal	January 2013
Unified model for singlet fission within a non-conjugated covalent pentacene dimer Basel, Bettina S.; Zirzlmeier, Johannes; Hetzer, Constantin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15171	journal	May 2017
Singlet fission in pentacene through multi-exciton quantum states Zimmerman, Paul M.; Zhang, Zhiyong; Musgrave, Charles B. Nature Chemistry, Vol. 2, Issue 8 https://doi.org/10.1038/nchem.694	journal	June 2010
Ultrafast Dynamics of Exciton Fission in Polycrystalline Pentacene Wilson, Mark W. B.; Rao, Akshay; Clark, Jenny Journal of the American Chemical Society, Vol. 133, Issue 31 https://doi.org/10.1021/ja201688h	journal	August 2011
A transferable model for singlet-fission kinetics Yost, Shane R.; Lee, Jiye; Wilson, Mark W. B. Nature Chemistry, Vol. 6, Issue 6 https://doi.org/10.1038/nchem.1945	journal	May 2014
Maximizing Singlet Fission in Organic Dimers: Theoretical Investigation of Triplet Yield in the Regime of Localized Excitation and Fast Coherent Electron Transfer ^† Greyson, Eric C.; Vura-Weis, Josh; Michl, Josef The Journal of Physical Chemistry B, Vol. 114, Issue 45 https://doi.org/10.1021/jp907392q	journal	November 2010
Observation of Two Triplet-Pair Intermediates in Singlet Exciton Fission Pensack, Ryan D.; Ostroumov, Evgeny E.; Tilley, Andrew J. The Journal of Physical Chemistry Letters, Vol. 7, Issue 13 https://doi.org/10.1021/acs.jpclett.6b00947	journal	June 2016
Singlet Fission Smith, Millicent B.; Michl, Josef Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr1002613	journal	November 2010
Resonant energy transfer of triplet excitons from pentacene to PbSe nanocrystals Tabachnyk, Maxim; Ehrler, Bruno; Gélinas, Simon Nature Materials, Vol. 13, Issue 11 https://doi.org/10.1038/nmat4093	journal	October 2014
Delayed Molecular Triplet Generation from Energized Lead Sulfide Quantum Dots Garakyaraghi, Sofia; Mongin, Cédric; Granger, Devin B. The Journal of Physical Chemistry Letters, Vol. 8, Issue 7 https://doi.org/10.1021/acs.jpclett.7b00546	journal	March 2017
Triplet Exciton Dissociation in Singlet Exciton Fission Photovoltaics Jadhav, Priya J.; Brown, Patrick R.; Thompson, Nicholas Advanced Materials, Vol. 24, Issue 46 https://doi.org/10.1002/adma.201202397	journal	September 2012
Efficient Singlet Fission Discovered in a Disordered Acene Film Roberts, Sean T.; McAnally, R. Eric; Mastron, Joseph N. Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja300504t	journal	March 2012
Narrow-Band Absorption-Enhanced Quantum Dot/J-Aggregate Conjugates Walker, Brian J.; Nair, Gautham P.; Marshall, Lisa F. Journal of the American Chemical Society, Vol. 131, Issue 28 https://doi.org/10.1021/ja902813q	journal	July 2009
Singlet Exciton Fission for Solar Cell Applications: Energy Aspects of Interchromophore Coupling ^† Greyson, Eric C.; Stepp, Brian R.; Chen, Xudong The Journal of Physical Chemistry B, Vol. 114, Issue 45 https://doi.org/10.1021/jp909002d	journal	November 2010
Femtosecond stimulated Raman evidence for charge-transfer character in pentacene singlet fission Hart, Stephanie M.; Silva, W. Ruchira; Frontiera, Renee R. Chemical Science, Vol. 9, Issue 5 https://doi.org/10.1039/C7SC03496B	journal	January 2018
Energy harvesting of non-emissive triplet excitons in tetracene by emissive PbS nanocrystals Thompson, Nicholas J.; Wilson, Mark W. B.; Congreve, Daniel N. Nature Materials, Vol. 13, Issue 11 https://doi.org/10.1038/nmat4097	journal	October 2014
Mechanism for Singlet Fission in Pentacene and Tetracene: From Single Exciton to Two Triplets Zimmerman, Paul M.; Bell, Franziska; Casanova, David Journal of the American Chemical Society, Vol. 133, Issue 49 https://doi.org/10.1021/ja208431r	journal	December 2011
Surface States Mediate Triplet Energy Transfer in Nanocrystal–Acene Composite Systems Bender, Jon A.; Raulerson, Emily K.; Li, Xin Journal of the American Chemical Society, Vol. 140, Issue 24 https://doi.org/10.1021/jacs.8b01966	journal	May 2018
Evidence for Charge-Transfer Mediation in the Primary Events of Singlet Fission in a Weakly Coupled Pentacene Dimer Basel, Bettina S.; Zirzlmeier, Johannes; Hetzer, Constantin Chem, Vol. 4, Issue 5 https://doi.org/10.1016/j.chempr.2018.04.006	journal	May 2018
Solution-processable, crystalline material for quantitative singlet fission Pensack, Ryan D.; Grieco, Christopher; Purdum, Geoffrey E. Materials Horizons, Vol. 4, Issue 5 https://doi.org/10.1039/C7MH00303J	journal	January 2017
Singlet Fission within Diketopyrrolopyrrole Nanoparticles in Water Mauck, Catherine M.; Hartnett, Patrick E.; Wu, Yi-Lin Chemistry of Materials, Vol. 29, Issue 16 https://doi.org/10.1021/acs.chemmater.7b01845	journal	August 2017
Singlet fission in rubrene single crystal: direct observation by femtosecond pump–probe spectroscopy Ma, Lin; Zhang, Keke; Kloc, Christian Physical Chemistry Chemical Physics, Vol. 14, Issue 23 https://doi.org/10.1039/c2cp40449d	journal	January 2012
High-Yield Excited Triplet States in Pentacene Self-Assembled Monolayers on Gold Nanoparticles through Singlet Exciton Fission Kato, Daiki; Sakai, Hayato; Tkachenko, Nikolai V. Angewandte Chemie, Vol. 128, Issue 17 https://doi.org/10.1002/ange.201601421	journal	March 2016
Evidence for conical intersection dynamics mediating ultrafast singlet exciton fission Musser, Andrew J.; Liebel, Matz; Schnedermann, Christoph Nature Physics, Vol. 11, Issue 4 https://doi.org/10.1038/nphys3241	journal	March 2015
Colloidal PbS Nanocrystals with Size-Tunable Near-Infrared Emission: Observation of Post-Synthesis Self-Narrowing of the Particle Size Distribution Hines, M. A.; Scholes, G. D. Advanced Materials, Vol. 15, Issue 21, p. 1844-1849 https://doi.org/10.1002/adma.200305395	journal	November 2003
Singlet Exciton Fission-Sensitized Infrared Quantum Dot Solar Cells Ehrler, Bruno; Wilson, Mark W. B.; Rao, Akshay Nano Letters, Vol. 12, Issue 2 https://doi.org/10.1021/nl204297u	journal	January 2012
Singlet Fission for Dye-Sensitized Solar Cells: Can a Suitable Sensitizer Be Found? Paci, Irina; Johnson, Justin C.; Chen, Xudong Journal of the American Chemical Society, Vol. 128, Issue 51 https://doi.org/10.1021/ja063980h	journal	December 2006
Hybrid organic/inorganic semiconductor nanostructures with highly efficient energy transfer Savateeva, Diana; Melnikau, Dzmitry; Lesnyak, Vladimir Journal of Materials Chemistry, Vol. 22, Issue 21 https://doi.org/10.1039/c2jm30917c	journal	January 2012
Long-Lived Correlated Triplet Pairs in a π-Stacked Crystalline Pentacene Derivative Folie, Brendan D.; Haber, Jonah B.; Refaely-Abramson, Sivan Journal of the American Chemical Society, Vol. 140, Issue 6 https://doi.org/10.1021/jacs.7b12662	journal	February 2018
Quantum Beats in Crystalline Tetracene Delayed Fluorescence Due to Triplet Pair Coherences Produced by Direct Singlet Fission Burdett, Jonathan J.; Bardeen, Christopher J. Journal of the American Chemical Society, Vol. 134, Issue 20 https://doi.org/10.1021/ja301683w	journal	May 2012
The Spectral Signatures of Frenkel Polarons in H- and J-Aggregates Spano, Frank C. Accounts of Chemical Research, Vol. 43, Issue 3 https://doi.org/10.1021/ar900233v	journal	March 2010
Dynamics of the triplet-pair state reveals the likely coexistence of coherent and incoherent singlet fission in crystalline hexacene Monahan, Nicholas R.; Sun, Dezheng; Tamura, Hiroyuki Nature Chemistry, Vol. 9, Issue 4 https://doi.org/10.1038/nchem.2665	journal	December 2016
Competition between Singlet Fission and Charge Separation in Solution-Processed Blend Films of 6,13-Bis(triisopropylsilylethynyl)pentacene with Sterically-Encumbered Perylene-3,4:9,10-bis(dicarboximide)s Ramanan, Charusheela; Smeigh, Amanda L.; Anthony, John E. Journal of the American Chemical Society, Vol. 134, Issue 1 https://doi.org/10.1021/ja2080482	journal	December 2011
Exciton Delocalization Drives Rapid Singlet Fission in Nanoparticles of Acene Derivatives Pensack, Ryan D.; Tilley, Andrew J.; Parkin, Sean R. Journal of the American Chemical Society, Vol. 137, Issue 21 https://doi.org/10.1021/ja512668r	journal	May 2015

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