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Title: Pressure-induced modifications of the magnetic order in the spin-chain compound C a 3 C o 2 O 6

Abstract

The structural and magnetic properties of the Ca 3Co 2O 6 spin-chain compound have been studied by means of neutron and x-ray powder diffraction at pressures up to 6.8 and 32 GPa, respectively. A suppression of the initial spin-density wave state (T N = 25 K) and stabilization of the collinear commensurate antiferromagnetic (AFM) state at high pressures (T NC = 26 K at P = 2.1 GPa) were observed. The pressure behavior of the competing intra- and interchain magnetic interactions was analyzed on the basis of obtained structural data and their role in the formation of the magnetic phase diagram is discussed. Here, the pressure behavior of the Néel temperature of the commensurate AFM phase was evaluated within the mean field theory approach and a good agreement with the experimental value dT NC/dP = 0.65 K/GPa was obtained.

Authors:
 [1];  [2];  [1];  [1];  [1];  [3];  [3];  [4];  [5];  [6];  [1];  [3];  [3]
  1. Joint Inst. for Nuclear Research, Dubna (Russia)
  2. Duy Tan Univ., Da Nang (Vietnam)
  3. Univ. of South Florida, Tampa, FL (United States)
  4. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
  5. Azerbaijan National Academy of Sciences, Baku (Azerbaijan)
  6. Hankuk Univ. of Foreign Studies, Yongin (South Korea)
Publication Date:
Research Org.:
Univ. of South Florida, Tampa, FL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; Russian Foundation for Basic Research; Vietnam National Foundation for Science and Technology Development (NAFOSTED)
OSTI Identifier:
1609899
Alternate Identifier(s):
OSTI ID: 1478593
Grant/Contract Number:  
FG02-07ER46438; 18-02-00359-a; 103.02-2017.364
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 98; Journal Issue: 13; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; materials science; physics; magnetic interactions; magnetic order; pressure effects; structural properties; 1-dimensional spin chains; neutron diffraction; X-ray diffraction

Citation Formats

Kozlenko, D. P., Dang, N. T., Golosova, N. O., Kichanov, S. E., Lukin, E. V., Lampen Kelley, P. J., Clements, E. M., Glazyrin, K. V., Jabarov, S. H., Phan, T. L., Savenko, B. N., Srikanth, H., and Phan, M. H. Pressure-induced modifications of the magnetic order in the spin-chain compound Ca3Co2O6. United States: N. p., 2018. Web. doi:10.1103/physrevb.98.134435.
Kozlenko, D. P., Dang, N. T., Golosova, N. O., Kichanov, S. E., Lukin, E. V., Lampen Kelley, P. J., Clements, E. M., Glazyrin, K. V., Jabarov, S. H., Phan, T. L., Savenko, B. N., Srikanth, H., & Phan, M. H. Pressure-induced modifications of the magnetic order in the spin-chain compound Ca3Co2O6. United States. doi:10.1103/physrevb.98.134435.
Kozlenko, D. P., Dang, N. T., Golosova, N. O., Kichanov, S. E., Lukin, E. V., Lampen Kelley, P. J., Clements, E. M., Glazyrin, K. V., Jabarov, S. H., Phan, T. L., Savenko, B. N., Srikanth, H., and Phan, M. H. Fri . "Pressure-induced modifications of the magnetic order in the spin-chain compound Ca3Co2O6". United States. doi:10.1103/physrevb.98.134435. https://www.osti.gov/servlets/purl/1609899.
@article{osti_1609899,
title = {Pressure-induced modifications of the magnetic order in the spin-chain compound Ca3Co2O6},
author = {Kozlenko, D. P. and Dang, N. T. and Golosova, N. O. and Kichanov, S. E. and Lukin, E. V. and Lampen Kelley, P. J. and Clements, E. M. and Glazyrin, K. V. and Jabarov, S. H. and Phan, T. L. and Savenko, B. N. and Srikanth, H. and Phan, M. H.},
abstractNote = {The structural and magnetic properties of the Ca3Co2O6 spin-chain compound have been studied by means of neutron and x-ray powder diffraction at pressures up to 6.8 and 32 GPa, respectively. A suppression of the initial spin-density wave state (TN = 25 K) and stabilization of the collinear commensurate antiferromagnetic (AFM) state at high pressures (TNC = 26 K at P = 2.1 GPa) were observed. The pressure behavior of the competing intra- and interchain magnetic interactions was analyzed on the basis of obtained structural data and their role in the formation of the magnetic phase diagram is discussed. Here, the pressure behavior of the Néel temperature of the commensurate AFM phase was evaluated within the mean field theory approach and a good agreement with the experimental value dTNC/dP = 0.65 K/GPa was obtained.},
doi = {10.1103/physrevb.98.134435},
journal = {Physical Review B},
issn = {2469-9950},
number = 13,
volume = 98,
place = {United States},
year = {2018},
month = {10}
}

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    Works referencing / citing this record:

    Pressure-induced modifications of the magnetic order in the spin-chain compound $\mathrm{Ca_{3}Co_{2}O_{6}}$
    text, January 2018

    • Kozlenko, Denis; Tuan, Dang Nguen; Golosova, N. O.
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
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    Origin of Ising magnetism in Ca3Co2O6 unveiled by orbital imaging
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    Origin of Ising magnetism in Ca$_3$Co$_2$O$_6$ unveiled by orbital imaging
    text, January 2019

    • Leedahl, Brett; Sundermann, Martin; Amorese, Andrea
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
    • DOI: 10.3204/pubdb-2019-04624