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Spectroscopic Evidence for an Attractive Cation–Cation Interaction in Hydroxy-Functionalized Ionic Liquids: A Hydrogen-Bonded Chain-like Trimer

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [1];  [2];  [3];  [3];  [3]
  1. Department of ChemistryUniversity of Rostock 18059 Rostock Germany; Department Life, Light &, MatterUniversity of Rostock 18051 Rostock Germany
  2. Department of ChemistryUniversity of Rostock 18059 Rostock Germany; Department Life, Light &, MatterUniversity of Rostock 18051 Rostock Germany; Leibniz-Institut für Katalyse e.V. Albert-Einstein-Str. 29a 18059 Rostock Germany
  3. Sterling Chemistry LaboratoryYale University New Haven CT 06520 USA
+ Show Author Affiliations

Not provided.

Research Organization:
Yale Univ., New Haven, CT (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-06ER15800
OSTI ID:
1609703
Journal Information:
Angewandte Chemie (International Edition), Vol. 57, Issue 47; ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English

References (36)

When Like Charged Ions Attract in Ionic Liquids: Controlling the Formation of Cationic Clusters by the Interaction Strength of the Counterions December 2016
Ionic-Liquid-Mediated Extraction and Separation Processes for Bioactive Compounds: Past, Present, and Future Trends February 2017
Starke, lokalisierte und gerichtete H-Brücken machen ionische Flüssigkeiten beweglicher October 2008
The influence of hydrogen bonding on the physical properties of ionic liquids January 2011
Infrared absorption of methanol clusters (CH 3 OH) n with n = 2−6 recorded with a time-of-flight mass spectrometer using infrared depletion and vacuum-ultraviolet ionization April 2011
Understanding Ionic Liquids at the Molecular Level: Facts, Problems, and Controversies January 2008
Ultra-fast computation of electronic spectra for large systems by tight-binding based simplified Tamm-Dancoff approximation (sTDA-xTB) August 2016
Hydrogen bonding in ionic liquids January 2015
MP2 energy evaluation by direct methods December 1988
Water clusters: Untangling the mysteries of the liquid, one molecule at a time September 2001
Structural Motifs in Cold Ternary Ion Complexes of Hydroxyl-Functionalized Ionic Liquids: Isolating the Role of Cation–Cation Interactions May 2018
Water: From Clusters to the Bulk May 2001
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis August 1999
Infrared spectra of methanol, ethanol, and n-propanol April 1952
Doubly ionic hydrogen bond interactions within the choline chloride–urea deep eutectic solvent January 2016
Cation-cation clusters in ionic liquids: Cooperative hydrogen bonding overcomes like-charge repulsion December 2015
Dispersion-Corrected Mean-Field Electronic Structure Methods April 2016
Controlling the kinetic and thermodynamic stability of cationic clusters by the addition of molecules or counterions January 2017
Air and water stable ionic liquids in physical chemistry January 2006
Analyzing the interaction energies between cation and anion in ionic liquids: The subtle balance between Coulomb forces and hydrogen bonding April 2014
Anziehung gleich geladener Ionen in ionischen Flüssigkeiten: Kontrolle der Bildung kationischer Cluster über die Wechselwirkungsstärke der Gegenionen December 2016
Strong, Localized, and Directional Hydrogen Bonds Fluidize Ionic Liquids October 2008
Probing molecular interaction in ionic liquids by low frequency spectroscopy: Coulomb energy, hydrogen bonding and dispersion forces January 2014
Protic ionic liquids as electrolytes for lithium-ion batteries June 2013
Wasser: von Clustern in die Flüssigkeit May 2001
Ionic liquids as electrolytes August 2006
Infrared photodissociation of small methanol clusters March 1988
Applications of ionic liquids in the chemical industry January 2008
Spectroscopic Evidence for Clusters of Like-Charged Ions in Ionic Liquids Stabilized by Cooperative Hydrogen Bonding January 2016
Cationic clustering influences the phase behaviour of ionic liquids October 2018
Zum Verständnis ionischer Flüssigkeiten auf molekularer Ebene: Fakten, Probleme und Kontroversen January 2008
Note on an Approximation Treatment for Many-Electron Systems October 1934
Theoretical investigation of the dication of molecular nitrogen October 1986
System-Dependent Dispersion Coefficients for the DFT-D3 Treatment of Adsorption Processes on Ionic Surfaces October 2011
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu April 2010
The influence of like-charge attraction on the structure and dynamics of ionic liquids: NMR chemical shifts, quadrupole coupling constants, rotational correlation times and failure of Stokes–Einstein–Debye January 2018

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