skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis

Abstract

Delamination of layered zeolite precursor B-SSZ-70 succeeds in an aqueous solution of Zn(NO 3) 2and Bu 4NF without need for sonication.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2];  [3];  [3]; ORCiD logo [1]
  1. Department of Chemical and Biomolecular Engineering; University of California at Berkeley; Berkeley; USA
  2. Division of Chemistry and Chemical Engineering; California Institute of Technology; Pasadena; USA
  3. Chevron Energy Technology Company; Richmond; USA
Publication Date:
Research Org.:
Univ. of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1609616
DOE Contract Number:  
FG02-05ER15696; AC02-05CH11231
Resource Type:
Journal Article
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 42; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, and Katz, Alexander. SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis. United States: N. p., 2018. Web. doi:10.1039/c8dt03044h.
Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, & Katz, Alexander. SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis. United States. doi:10.1039/c8dt03044h.
Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, and Katz, Alexander. Mon . "SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis". United States. doi:10.1039/c8dt03044h.
@article{osti_1609616,
title = {SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis},
author = {Okrut, Alexander and Aigner, Martina and Schöttle, Christian and Grosso-Giordano, Nicolás A. and Hwang, Son-Jong and Ouyang, Xiaoying and Zones, Stacey and Katz, Alexander},
abstractNote = {Delamination of layered zeolite precursor B-SSZ-70 succeeds in an aqueous solution of Zn(NO3)2and Bu4NF without need for sonication.},
doi = {10.1039/c8dt03044h},
journal = {Dalton Transactions},
issn = {1477-9226},
number = 42,
volume = 47,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

The Quest For Extra-Large Pore, Crystalline Molecular Sieves
journal, November 1997


Extra-Large-Pore Zeolites: Bridging the Gap between Micro and Mesoporous Structures
journal, April 2010

  • Jiang, Jiuxing; Yu, Jihong; Corma, Avelino
  • Angewandte Chemie International Edition, Vol. 49, Issue 18
  • DOI: 10.1002/anie.200904016

Delaminated zeolite precursors as selective acidic catalysts
journal, November 1998

  • Corma, A.; Fornes, V.; Pergher, S. B.
  • Nature, Vol. 396, Issue 6709, p. 353-356
  • DOI: 10.1038/24592

Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor
journal, January 2008

  • Maheshwari, Sudeep; Jordan, Edgar; Kumar, Sandeep
  • Journal of the American Chemical Society, Vol. 130, Issue 4, p. 1507-1516
  • DOI: 10.1021/ja077711i

Two-dimensional zeolites: dream or reality?
journal, January 2011

  • Roth, Wieslaw J.; Čejka, Jiří
  • Catalysis Science & Technology, Vol. 1, Issue 1
  • DOI: 10.1039/c0cy00027b

Structure and Colloidal Stability of Nanosized Zeolite Beta Precursors
journal, January 2010

  • Hould, Nathan D.; Kumar, Sandeep; Tsapatsis, Michael
  • Langmuir, Vol. 26, Issue 2
  • DOI: 10.1021/la902445c

Pioneering In Situ Recrystallization during Bead Milling: A Top-down Approach to Prepare Zeolite A Nanocrystals
journal, July 2016

  • Anand, Chokkalingam; Yamaguchi, Yudai; Liu, Zhendong
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep29210

One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent
journal, January 2015

  • Luo, Helen Y.; Michaelis, Vladimir K.; Hodges, Sydney
  • Chemical Science, Vol. 6, Issue 11
  • DOI: 10.1039/C5SC01912E

Layered zeolitic materials: an approach to designing versatile functional solids
journal, January 2014

  • Díaz, Urbano; Corma, Avelino
  • Dalton Transactions, Vol. 43, Issue 27
  • DOI: 10.1039/c3dt53181c

Delamination of Layered Zeolite Precursors under Mild Conditions: Synthesis of UCB-1 via Fluoride/Chloride Anion-Promoted Exfoliation
journal, March 2011

  • Ogino, Isao; Nigra, Michael M.; Hwang, Son-Jong
  • Journal of the American Chemical Society, Vol. 133, Issue 10, p. 3288-3291
  • DOI: 10.1021/ja111147z

Influence of layer structure preservation on the catalytic properties of the pillared zeolite MCM-36
journal, June 2010

  • Maheshwari, Sudeep; Martínez, Cristina; Teresa Portilla, M.
  • Journal of Catalysis, Vol. 272, Issue 2
  • DOI: 10.1016/j.jcat.2010.04.011

Novel surfactant-free route to delaminated all-silica and titanosilicate zeolites derived from a layered borosilicate MWW precursor
journal, January 2014

  • Ouyang, Xiaoying; Wanglee, Ying-Jen; Hwang, Son-Jong
  • Dalton Trans., Vol. 43, Issue 27
  • DOI: 10.1039/C4DT00383G

Single-Step Delamination of a MWW Borosilicate Layered Zeolite Precursor under Mild Conditions without Surfactant and Sonication
journal, January 2014

  • Ouyang, Xiaoying; Hwang, Son-Jong; Runnebaum, Ron C.
  • Journal of the American Chemical Society, Vol. 136, Issue 4
  • DOI: 10.1021/ja410141u

Well-Defined Silanols in the Structure of the Calcined High-Silica Zeolite SSZ-70: New Understanding of a Successful Catalytic Material
journal, November 2017

  • Smeets, Stef; Berkson, Zachariah J.; Xie, Dan
  • Journal of the American Chemical Society, Vol. 139, Issue 46
  • DOI: 10.1021/jacs.7b08810

Role of Delamination in Zeolite-Catalyzed Aromatic Alkylation: UCB-3 versus 3-D Al-SSZ-70
journal, May 2014

  • Runnebaum, Ron C.; Ouyang, Xiaoying; Edsinga, Jeffrey A.
  • ACS Catalysis, Vol. 4, Issue 7
  • DOI: 10.1021/cs500285w

Heteroatom-Substituted Delaminated Zeolites as Solid Lewis Acid Catalysts
journal, March 2015

  • Ouyang, Xiaoying; Hwang, Son-Jong; Xie, Dan
  • ACS Catalysis, Vol. 5, Issue 5
  • DOI: 10.1021/cs5020546

Outer-Sphere Control of Catalysis on Surfaces: A Comparative Study of Ti(IV) Single-Sites Grafted on Amorphous versus Crystalline Silicates for Alkene Epoxidation
journal, March 2018

  • Grosso-Giordano, Nicolás A.; Schroeder, Christian; Okrut, Alexander
  • Journal of the American Chemical Society, Vol. 140, Issue 15
  • DOI: 10.1021/jacs.7b11467

Epoxidation of 1-octene under harsh tail-end conditions in a flow reactor I: a comparative study of crystalline vs. amorphous catalysts
journal, January 2017

  • Aigner, Martina; Grosso-Giordano, Nicolás Andrés; Okrut, Alexander
  • Reaction Chemistry & Engineering, Vol. 2, Issue 6
  • DOI: 10.1039/C7RE00076F

Epoxidation of 1-octene under harsh tail-end conditions in a flow reactor II: impact of delaminated-zeolite catalyst surface area and structural integrity on catalytic performance
journal, January 2017

  • Aigner, Martina; Grosso-Giordano, Nicolás Andrés; Schöttle, Christian
  • Reaction Chemistry & Engineering, Vol. 2, Issue 6
  • DOI: 10.1039/C7RE00138J

Two-Dimensional Zeolites: Current Status and Perspectives
journal, February 2014

  • Roth, Wieslaw J.; Nachtigall, Petr; Morris, Russell E.
  • Chemical Reviews, Vol. 114, Issue 9
  • DOI: 10.1021/cr400600f

From 3D to 2D zeolite catalytic materials
journal, January 2018

  • Přech, J.; Pizarro, P.; Serrano, D. P.
  • Chemical Society Reviews, Vol. 47, Issue 22
  • DOI: 10.1039/C8CS00370J

Two-dimensional zeolites in catalysis: current status and perspectives
journal, January 2016

  • Opanasenko, Maksym V.; Roth, Wieslaw J.; Čejka, Jiří
  • Catalysis Science & Technology, Vol. 6, Issue 8
  • DOI: 10.1039/C5CY02079D

Highly Active Layered Titanosilicate Catalyst with High Surface Density of Isolated Titanium on the Accessible Interlayer Surface
journal, May 2018

  • Tsunoji, Nao; Opanasenko, Maksym V.; Kubů, Martin
  • ChemCatChem, Vol. 10, Issue 12
  • DOI: 10.1002/cctc.201800413

Cutting Materials in Half: A Graph Theory Approach for Generating Crystal Surfaces and Its Prediction of 2D Zeolites
journal, February 2018


Heteroatom-Tolerant Delamination of Layered Zeolite Precursor Materials
journal, April 2013

  • Ogino, Isao; Eilertsen, Einar A.; Hwang, Son-Jong
  • Chemistry of Materials, Vol. 25, Issue 9
  • DOI: 10.1021/cm3032785

Nonaqueous Fluoride/Chloride Anion-Promoted Delamination of Layered Zeolite Precursors: Synthesis and Characterization of UCB-2
journal, December 2011

  • Eilertsen, Einar A.; Ogino, Isao; Hwang, Son-Jong
  • Chemistry of Materials, Vol. 23, Issue 24
  • DOI: 10.1021/cm202364q

Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning
journal, December 1980

  • Maciel, Gary E.; Sindorf, Dean W.
  • Journal of the American Chemical Society, Vol. 102, Issue 25
  • DOI: 10.1021/ja00545a056

Effect of Defect Site Preorganization on Fe(III) Grafting and Stability: A Comparative Study of Delaminated Zeolite vs Amorphous Silica Supports
journal, July 2017