Transformation of gels via catalyst-free selective RAFT photoactivation
Abstract
This work explores the concept of structurally tailored and engineered macromolecular (STEM) networks by proposing a novel metal-free approach to prepare the networks.
- Authors:
-
[1];
[1];
[1];
[2];
[1];
[1]
- Department of Chemistry; Carnegie Mellon University; Pittsburgh; USA
- Centre for Advanced Macromolecular Design (CAMD) and Australian Centre for NanoMedicine School of Chemical Engineering; UNSW Australia; Sydney; Australia
- Publication Date:
- Research Org.:
- UNIVERSITY OF PITTSBURGH; Univ. of Pittsburgh, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1609403
- DOE Contract Number:
- FG02-02ER45998
- Resource Type:
- Journal Article
- Journal Name:
- Polymer Chemistry
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 19; Journal ID: ISSN 1759-9954
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Polymer Science
Citation Formats
Shanmugam, Sivaprakash, Cuthbert, Julia, Flum, Jacob, Fantin, Marco, Boyer, Cyrille, Kowalewski, Tomasz, and Matyjaszewski, Krzysztof. Transformation of gels via catalyst-free selective RAFT photoactivation. United States: N. p., 2019.
Web. doi:10.1039/c9py00213h.
Shanmugam, Sivaprakash, Cuthbert, Julia, Flum, Jacob, Fantin, Marco, Boyer, Cyrille, Kowalewski, Tomasz, & Matyjaszewski, Krzysztof. Transformation of gels via catalyst-free selective RAFT photoactivation. United States. https://doi.org/10.1039/c9py00213h
Shanmugam, Sivaprakash, Cuthbert, Julia, Flum, Jacob, Fantin, Marco, Boyer, Cyrille, Kowalewski, Tomasz, and Matyjaszewski, Krzysztof. Tue .
"Transformation of gels via catalyst-free selective RAFT photoactivation". United States. https://doi.org/10.1039/c9py00213h.
@article{osti_1609403,
title = {Transformation of gels via catalyst-free selective RAFT photoactivation},
author = {Shanmugam, Sivaprakash and Cuthbert, Julia and Flum, Jacob and Fantin, Marco and Boyer, Cyrille and Kowalewski, Tomasz and Matyjaszewski, Krzysztof},
abstractNote = {This work explores the concept of structurally tailored and engineered macromolecular (STEM) networks by proposing a novel metal-free approach to prepare the networks.},
doi = {10.1039/c9py00213h},
url = {https://www.osti.gov/biblio/1609403},
journal = {Polymer Chemistry},
issn = {1759-9954},
number = 19,
volume = 10,
place = {United States},
year = {2019},
month = {1}
}
Other availability
Find in Google Scholar
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Transformable Materials: Structurally Tailored and Engineered Macromolecular (STEM) Gels by Controlled Radical Polymerization
journal, May 2018
- Cuthbert, Julia; Beziau, Antoine; Gottlieb, Eric
- Macromolecules, Vol. 51, Issue 10
Macromolecular metamorphosis via stimulus-induced transformations of polymer architecture
journal, February 2017
- Sun, Hao; Kabb, Christopher P.; Dai, Yuqiong
- Nature Chemistry, Vol. 9, Issue 8
Photoactivated Structurally Tailored and Engineered Macromolecular (STEM) gels as precursors for materials with spatially differentiated mechanical properties
journal, September 2017
- Beziau, Antoine; Fortney, Andria; Fu, Liye
- Polymer, Vol. 126
Multifunctional Hydrogels with Reversible 3D Ordered Macroporous Structures
journal, March 2015
- He, Hongkun; Averick, Saadyah; Mandal, Pratiti
- Advanced Science, Vol. 2, Issue 5
A single-component hydrogel bioink for bioprinting of bioengineered 3D constructs for dermal tissue engineering
journal, January 2018
- Pereira, Rúben F.; Sousa, Aureliana; Barrias, Cristina C.
- Materials Horizons, Vol. 5, Issue 6
Soft Elastomers via Introduction of Poly(butyl acrylate) “Diluent” to Poly(hydroxyethyl acrylate)-Based Gel Networks
journal, December 2012
- Mpoukouvalas, Anastasia; Li, Wenwen; Graf, Robert
- ACS Macro Letters, Vol. 2, Issue 1
A surface-grafted thermoresponsive hydrogel in which the surface structure dominates the bulk properties
journal, January 2016
- Matsukawa, Ko; Masuda, Tsukuru; Akimoto, Aya Mizutani
- Chemical Communications, Vol. 52, Issue 74
Bioapplications of RAFT Polymerization
journal, November 2009
- Boyer, Cyrille; Bulmus, Volga; Davis, Thomas P.
- Chemical Reviews, Vol. 109, Issue 11
Cu(0)-Mediated Living Radical Polymerization: A Versatile Tool for Materials Synthesis
journal, July 2015
- Anastasaki, Athina; Nikolaou, Vasiliki; Nurumbetov, Gabit
- Chemical Reviews, Vol. 116, Issue 3
Macromolecular Engineering by Atom Transfer Radical Polymerization
journal, April 2014
- Matyjaszewski, Krzysztof; Tsarevsky, Nicolay V.
- Journal of the American Chemical Society, Vol. 136, Issue 18
“Green” Atom Transfer Radical Polymerization: From Process Design to Preparation of Well-Defined Environmentally Friendly Polymeric Materials
journal, June 2007
- Tsarevsky, Nicolay V.; Matyjaszewski, Krzysztof
- Chemical Reviews, Vol. 107, Issue 6
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
journal, December 2001
- Hawker, Craig J.; Bosman, Anton W.; Harth, Eva
- Chemical Reviews, Vol. 101, Issue 12
Thermoresponsive Hydrogels Based on Telechelic Polyelectrolytes: From Dynamic to “Frozen” Networks
journal, March 2018
- Tsitsilianis, Constantinos; Serras, George; Ko, Chia-Hsin
- Macromolecules, Vol. 51, Issue 6
Tuning thermoresponsive network materials through macromolecular architecture and dynamic thiol-Michael chemistry
journal, January 2018
- Chakma, Progyateg; Digby, Zachary A.; Via, Jeremy
- Polymer Chemistry, Vol. 9, Issue 38
Photo-Dimerization Induced Dynamic Viscoelastic Changes in ABA Triblock Copolymer-Based Hydrogels for 3D Cell Culture
journal, August 2016
- Tamate, Ryota; Ueki, Takeshi; Kitazawa, Yuzo
- Chemistry of Materials, Vol. 28, Issue 17
Photocontrolled Living Polymerization Systems with Reversible Deactivations through Electron and Energy Transfer
journal, May 2017
- Shanmugam, Sivaprakash; Xu, Jiangtao; Boyer, Cyrille
- Macromolecular Rapid Communications, Vol. 38, Issue 13
Externally controlled atom transfer radical polymerization
journal, January 2018
- Pan, Xiangcheng; Fantin, Marco; Yuan, Fang
- Chemical Society Reviews, Vol. 47, Issue 14
Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization
journal, September 2018
- Discekici, Emre H.; Anastasaki, Athina; Read de Alaniz, Javier
- Macromolecules, Vol. 51, Issue 19
Photomediated controlled radical polymerization
journal, November 2016
- Pan, Xiangcheng; Tasdelen, Mehmet Atilla; Laun, Joachim
- Progress in Polymer Science, Vol. 62
Living Additive Manufacturing: Transformation of Parent Gels into Diversely Functionalized Daughter Gels Made Possible by Visible Light Photoredox Catalysis
journal, January 2017
- Chen, Mao; Gu, Yuwei; Singh, Awaneesh
- ACS Central Science, Vol. 3, Issue 2
Opportunities for dual RDRP agents in synthesizing novel polymeric materials
journal, January 2017
- Pearson, Samuel; St Thomas, Claude; Guerrero-Santos, Ramiro
- Polymer Chemistry, Vol. 8, Issue 34
Aqueous Self-Assembly of Giant Bottlebrush Block Copolymer Surfactants as Shape-Tunable Building Blocks
journal, May 2014
- Fenyves, Ryan; Schmutz, Marc; Horner, Ian J.
- Journal of the American Chemical Society, Vol. 136, Issue 21
Synthesis of Thermoresponsive Mixed Arm Star Polymers by Combination of RAFT and ATRP from a Multifunctional Core and Its Self-Assembly in Water
journal, June 2008
- Ranganathan, Krishnan; Deng, Rui; Kainthan, Rajesh K.
- Macromolecules, Vol. 41, Issue 12
N , N -Diaryl Dihydrophenazines as Photoredox Catalysts for PET-RAFT and Sequential PET-RAFT/O-ATRP
journal, May 2018
- Theriot, Jordan C.; Miyake, Garret M.; Boyer, Cyrille A.
- ACS Macro Letters, Vol. 7, Issue 6
Catalyst-Free Selective Photoactivation of RAFT Polymerization: A Facile Route for Preparation of Comblike and Bottlebrush Polymers
journal, September 2018
- Shanmugam, Sivaprakash; Cuthbert, Julia; Kowalewski, Tomasz
- Macromolecules, Vol. 51, Issue 19
A Robust and Versatile Photoinduced Living Polymerization of Conjugated and Unconjugated Monomers and Its Oxygen Tolerance
journal, February 2014
- Xu, Jiangtao; Jung, Kenward; Atme, Amir
- Journal of the American Chemical Society, Vol. 136, Issue 14
Visible-light-mediated, additive-free, and open-to-air controlled radical polymerization of acrylates and acrylamides
journal, January 2019
- Lamb, Jessica R.; Qin, K. Peter; Johnson, Jeremiah A.
- Polymer Chemistry, Vol. 10, Issue 13