Structure and chemical stability in perovskite–polymer hybrid photovoltaic materials

Fairfield, Daniel J.; Sai, Hiroaki; Narayanan, Ashwin; Passarelli, James V.; Chen, Michelle; Palasz, Joseph; Palmer, Liam C.; Wasielewski, Michael R.; Stupp, Samuel I.

doi:10.1039/c8ta07545j

Title: Structure and chemical stability in perovskite–polymer hybrid photovoltaic materials

Journal Article · Tue Jan 01 00:00:00 EST 2019 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c8ta07545j· OSTI ID:1609336

Fairfield, Daniel J. ^[1];

^[1]; Narayanan, Ashwin ^[1]; Passarelli, James V. ^[2]; Chen, Michelle ^[2]; Palasz, Joseph ^[2];

^[3];

^[2];

^[4]

Department of Materials Science and Engineering; Northwestern University; Evanston; USA
Department of Chemistry; Northwestern University; USA
Department of Chemistry; Northwestern University; USA; Simpson Querrey Institute; Northwestern University
Department of Materials Science and Engineering; Northwestern University; Evanston; USA; Department of Chemistry

Chemical and morphological origins of the improved stability in various polymer–perovskite hybrid thin films under ambient environmental conditions are investigated.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: FG02-00ER45810; FG02-99ER14999

OSTI ID:: 1609336

Journal Information:: Journal of Materials Chemistry. A, Vol. 7, Issue 4; ISSN 2050-7488

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (42)

Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys Li, Zhen; Yang, Mengjin; Park, Ji-Sang Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04107	journal	December 2015
Origin of the Thermal Instability in CH ₃ NH ₃ PbI ₃ Thin Films Deposited on ZnO Yang, Jinli; Siempelkamp, Braden D.; Mosconi, Edoardo Chemistry of Materials, Vol. 27, Issue 12 https://doi.org/10.1021/acs.chemmater.5b01598	journal	June 2015
Enhanced Out-of-Plane Conductivity and Photovoltaic Performance in n = 1 Layered Perovskites through Organic Cation Design Passarelli, James V.; Fairfield, Daniel J.; Sather, Nicholas A. Journal of the American Chemical Society, Vol. 140, Issue 23 https://doi.org/10.1021/jacs.8b03659	journal	May 2018
Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells Bryant, Daniel; Aristidou, Nicholas; Pont, Sebastian Energy & Environmental Science, Vol. 9, Issue 5 https://doi.org/10.1039/C6EE00409A	journal	January 2016
6.5% efficient perovskite quantum-dot-sensitized solar cell Im, Jeong-Hyeok; Lee, Chang-Ryul; Lee, Jin-Wook Nanoscale, Vol. 3, Issue 10, p. 4088-4093 https://doi.org/10.1039/c1nr10867k	journal	January 2011
Band filling with free charge carriers in organometal halide perovskites Manser, Joseph S.; Kamat, Prashant V. Nature Photonics, Vol. 8, Issue 9 https://doi.org/10.1038/nphoton.2014.171	journal	August 2014
Low-temperature processed meso-superstructured to thin-film perovskite solar cells Ball, James M.; Lee, Michael M.; Hey, Andrew Energy & Environmental Science, Vol. 6, Issue 6 https://doi.org/10.1039/c3ee40810h	journal	January 2013
Polyvinylpyrrolidone (PVP) in nanoparticle synthesis Koczkur, Kallum M.; Mourdikoudis, Stefanos; Polavarapu, Lakshminarayana Dalton Transactions, Vol. 44, Issue 41 https://doi.org/10.1039/C5DT02964C	journal	January 2015
Electronic Properties of Meso-Superstructured and Planar Organometal Halide Perovskite Films: Charge Trapping, Photodoping, and Carrier Mobility Leijtens, Tomas; Stranks, Samuel D.; Eperon, Giles E. ACS Nano, Vol. 8, Issue 7 https://doi.org/10.1021/nn502115k	journal	June 2014
Polymer-modified halide perovskite films for efficient and stable planar heterojunction solar cells Zuo, Lijian; Guo, Hexia; deQuilettes, Dane W. Science Advances, Vol. 3, Issue 8 https://doi.org/10.1126/sciadv.1700106	journal	August 2017
Easily accessible polymer additives for tuning the crystal-growth of perovskite thin-films for highly efficient solar cells Dong, Qingqing; Wang, Zhaowei; Zhang, Kaicheng Nanoscale, Vol. 8, Issue 10 https://doi.org/10.1039/C6NR00206D	journal	January 2016
Ligand-Stabilized Reduced-Dimensionality Perovskites Quan, Li Na; Yuan, Mingjian; Comin, Riccardo Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b11740	journal	February 2016
The emergence of perovskite solar cells Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J. Nature Photonics, Vol. 8, Issue 7, p. 506-514 https://doi.org/10.1038/nphoton.2014.134	journal	July 2014
Enhanced Photovoltaic Performance of Perovskite Solar Cells Using Polymer P(VDF-TrFE) as a Processed Additive Sun, Chongyang; Guo, Yiping; Fang, Bijun The Journal of Physical Chemistry C, Vol. 120, Issue 24 https://doi.org/10.1021/acs.jpcc.6b05255	journal	June 2016
Sequential deposition as a route to high-performance perovskite-sensitized solar cells Burschka, Julian; Pellet, Norman; Moon, Soo-Jin Nature, Vol. 499, Issue 7458, p. 316-319 https://doi.org/10.1038/nature12340	journal	July 2013
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells Yang, Woon Seok; Park, Byung-Wook; Jung, Eui Hyuk Science, Vol. 356, Issue 6345 https://doi.org/10.1126/science.aan2301	journal	June 2017
The roles of alkyl halide additives in enhancing perovskite solar cell performance Chueh, Chu-Chen; Liao, Chien-Yi; Zuo, Fan Journal of Materials Chemistry A, Vol. 3, Issue 17 https://doi.org/10.1039/C4TA05012F	journal	January 2015
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Polymer-templated nucleation and crystal growth of perovskite films for solar cells with efficiency greater than 21% Bi, Dongqin; Yi, Chenyi; Luo, Jingshan Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.142	journal	September 2016
Remote-controlled experiments with cloud chemistry Skilton, Ryan A.; Bourne, Richard A.; Amara, Zacharias Nature Chemistry, Vol. 7, Issue 1 https://doi.org/10.1038/nchem.2143	journal	December 2014
Mesoporous perovskite solar cells: material composition, charge-carrier dynamics, and device characteristics Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai Faraday Discuss., Vol. 176 https://doi.org/10.1039/C4FD00128A	journal	January 2014
Intrinsic and Extrinsic Charge Transport in CH3NH3PbI3 Perovskites Predicted from First-Principles Zhao, Tianqi; Shi, Wen; Xi, Jinyang Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep19968	journal	January 2016
Unreacted PbI ₂ as a Double-Edged Sword for Enhancing the Performance of Perovskite Solar Cells Jacobsson, T. Jesper; Correa-Baena, Juan-Pablo; Halvani Anaraki, Elham Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b06320	journal	August 2016
Synthesis, Crystal Structure, and Optical and Thermal Properties of (C₄H₉NH₃)₂MI₄ (M = Ge, Sn, Pb) Mitzi, David B. Chemistry of Materials, Vol. 8, Issue 3, p. 791-800 https://doi.org/10.1021/cm9505097	journal	January 1996
Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide Ahn, Namyoung; Son, Dae-Yong; Jang, In-Hyuk Journal of the American Chemical Society, Vol. 137, Issue 27 https://doi.org/10.1021/jacs.5b04930	journal	July 2015
Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn Energy & Environmental Science, Vol. 9, Issue 6 https://doi.org/10.1039/C5EE03874J	journal	January 2016
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Processing Additives for Improved Efficiency from Bulk Heterojunction Solar Cells Lee, Jae Kwan; Ma, Wan Li; Brabec, Christoph J. Journal of the American Chemical Society, Vol. 130, Issue 11 https://doi.org/10.1021/ja710079w	journal	March 2008
A controllable fabrication of grain boundary PbI2 nanoplates passivated lead halide perovskites for high performance solar cells Zhang, Taiyang; Guo, Nanjie; Li, Ge Nano Energy, Vol. 26 https://doi.org/10.1016/j.nanoen.2016.05.003	journal	August 2016
Enabling reliability assessments of pre-commercial perovskite photovoltaics with lessons learned from industrial standards Snaith, Henry J.; Hacke, Peter Nature Energy, Vol. 3, Issue 6 https://doi.org/10.1038/s41560-018-0174-4	journal	June 2018
Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells Frost, Jarvist M.; Butler, Keith T.; Brivio, Federico Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl500390f	journal	April 2014
A polymer scaffold for self-healing perovskite solar cells Zhao, Yicheng; Wei, Jing; Li, Heng Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10228	journal	January 2016
Electron-hole diffusion lengths > 175 μm in solution-grown CH ₃ NH ₃ PbI ₃ single crystals Dong, Qingfeng; Fang, Yanjun; Shao, Yuchuan Science, Vol. 347, Issue 6225 https://doi.org/10.1126/science.aaa5760	journal	January 2015
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038 https://doi.org/10.1021/ic401215x	journal	July 2013
Additive to regulate the perovskite crystal film growth in planar heterojunction solar cells Song, Xin; Wang, Weiwei; Sun, Po Applied Physics Letters, Vol. 106, Issue 3 https://doi.org/10.1063/1.4906073	journal	January 2015
Unreacted PbI2 as a Double-Edged Sword for Enhancing the Performance of Perovskite Solar Cells. Jacobsson, Jesper; Correa-Baena, Juan-Pablo; Halvani Anaraki, Elham Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.12472	text	January 2016
Overcoming ultraviolet light instability of sensitized TiO2 with meso-superstructured organometal tri-halide perovskite solar cells Leijtens, Tomas; Eperon, Giles E.; Pathak, Sandeep Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3885	journal	December 2013
Tuning Perovskite Morphology by Polymer Additive for High Efficiency Solar Cell Chang, Chun-Yu; Chu, Cheng-Ya; Huang, Yu-Ching ACS Applied Materials & Interfaces, Vol. 7, Issue 8 https://doi.org/10.1021/acsami.5b00052	journal	February 2015
Perovskite solar cells employing organic charge-transport layers Malinkiewicz, Olga; Yella, Aswani; Lee, Yong Hui Nature Photonics, Vol. 8, Issue 2 https://doi.org/10.1038/nphoton.2013.341	journal	December 2013
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications Cao, Duyen H.; Stoumpos, Constantinos C.; Farha, Omar K. Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b03796	journal	June 2015
Enhancing the Hole-Conductivity of Spiro-OMeTAD without Oxygen or Lithium Salts by Using Spiro(TFSI) ₂ in Perovskite and Dye-Sensitized Solar Cells Nguyen, William H.; Bailie, Colin D.; Unger, Eva L. Journal of the American Chemical Society, Vol. 136, Issue 31 https://doi.org/10.1021/ja504539w	journal	July 2014

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Efficient Bifacial Passivation with Crosslinked Thioctic Acid for High‐Performance Methylammonium Lead Iodide Perovskite Solar Cells Chen, Hui; Liu, Tao; Zhou, Peng Advanced Materials, Vol. 32, Issue 6 https://doi.org/10.1002/adma.201905661	journal	December 2019
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Application of Perovskite‐Structured Materials in Field‐Effect Transistors Wu, Tingjun; Pisula, Wojciech; Rashid, Mohd Yusoff Abd Advanced Electronic Materials, Vol. 5, Issue 12 https://doi.org/10.1002/aelm.201900444	journal	September 2019
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