Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries

Fu, Kun (Kelvin); Gong, Yunhui; Dai, Jiaqi; Gong, Amy; Han, Xiaogang; Yao, Yonggang; Wang, Chengwei; Wang, Yibo; Chen, Yanan; Yan, Chaoyi; Li, Yiju; Wachsman, Eric D.; Hu, Liangbing

doi:10.1073/pnas.1600422113

Title: Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries

Journal Article · Wed Jun 15 00:00:00 EDT 2016 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1600422113· OSTI ID:1608918

Fu, Kun (Kelvin) ^[1]; Gong, Yunhui ^[1]; Dai, Jiaqi ^[1]; Gong, Amy ^[1]; Han, Xiaogang ^[1]; Yao, Yonggang ^[1]; Wang, Chengwei ^[1]; Wang, Yibo ^[1]; Chen, Yanan ^[1]; Yan, Chaoyi ^[1]; Li, Yiju ^[1]; Wachsman, Eric D. ^[1]; Hu, Liangbing ^[1]

Univ. of Maryland, College Park, MD (United States)

Beyond state-of-the-art lithium-ion battery (LIB) technology with metallic lithium anodes to replace conventional ion intercalation anode materials is highly desirable because of lithium’s highest specific capacity (3,860 mA/g) and lowest negative electrochemical potential (~3.040 V vs. the standard hydrogen electrode). In this work, we report for the first time, to our knowledge, a 3D lithium-ion–conducting ceramic network based on garnet-type Li_6.4La₃Zr₂Al_0.2O₁₂(LLZO) lithium-ion conductor to provide continuous Li⁺transfer channels in a polyethylene oxide (PEO)-based composite. This composite structure further provides structural reinforcement to enhance the mechanical properties of the polymer matrix. The flexible solid-state electrolyte composite membrane exhibited an ionic conductivity of 2.5 × 10^-4 S/cm at room temperature. The membrane can effectively block dendrites in a symmetric Li | electrolyte | Li cell during repeated lithium stripping/plating at room temperature, with a current density of 0.2 mA/cm² for around 500 h and a current density of 0.5 mA/cm² for over 300 h. Finally, these results provide an all solid ion-conducting membrane that can be applied to flexible LIBs and other electrochemical energy storage systems, such as lithium–sulfur batteries.

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Research Organization:: Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007807

OSTI ID:: 1608918

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Vol. 113, Issue 26; ISSN 0027-8424

Publisher:: National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 702 works

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References (34)

Progress and prospective of solid-state lithium batteries Takada, Kazunori Acta Materialia, Vol. 61, Issue 3, p. 759-770 https://doi.org/10.1016/j.actamat.2012.10.034	journal	February 2013
Solid-state, rechargeable Li/LiFePO4 polymer battery for electric vehicle application Damen, L.; Hassoun, J.; Mastragostino, M. Journal of Power Sources, Vol. 195, Issue 19 https://doi.org/10.1016/j.jpowsour.2010.03.089	journal	October 2010
Interfacial Challenges in Solid-State Li Ion Batteries Luntz, Alan C.; Voss, Johannes; Reuter, Karsten The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b02352	journal	October 2015
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Rechargeable Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500062v	journal	July 2014
All solid state lithium batteries based on lamellar garnet-type ceramic electrolytes Du, Fuming; Zhao, Ning; Li, Yiqiu Journal of Power Sources, Vol. 300 https://doi.org/10.1016/j.jpowsour.2015.09.061	journal	December 2015
In Situ Synthesis of a Hierarchical All-Solid-State Electrolyte Based on Nitrile Materials for High-Performance Lithium-Ion Batteries Zhou, Dong; He, Yan-Bing; Liu, Ruliang Advanced Energy Materials, Vol. 5, Issue 15 https://doi.org/10.1002/aenm.201500353	journal	May 2015
Enhancement of ionic conductivity of composite membranes for all-solid-state lithium rechargeable batteries incorporating tetragonal Li7La3Zr2O12 into a polyethylene oxide matrix Choi, Jeong-Hee; Lee, Chul-Ho; Yu, Ji-Hyun Journal of Power Sources, Vol. 274 https://doi.org/10.1016/j.jpowsour.2014.10.078	journal	January 2015
Nanocomposites of Titanium Dioxide and Polystyrene-Poly(ethylene oxide) Block Copolymer as Solid-State Electrolytes for Lithium Metal Batteries Gurevitch, Inna; Buonsanti, Raffaella; Teran, Alexander A. Journal of The Electrochemical Society, Vol. 160, Issue 9 https://doi.org/10.1149/2.117309jes	journal	January 2013
Garnet-type solid-state fast Li ion conductors for Li batteries: critical review Thangadurai, Venkataraman; Narayanan, Sumaletha; Pinzaru, Dana Chemical Society Reviews, Vol. 43, Issue 13 https://doi.org/10.1039/c4cs00020j	journal	January 2014
High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO ₂ Nanospheres in Poly(ethylene oxide) Lin, Dingchang; Liu, Wei; Liu, Yayuan Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b04117	journal	December 2015
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
A Review of Solid Electrolyte Interphases on Lithium Metal Anode Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Advanced Science, Vol. 3, Issue 3 https://doi.org/10.1002/advs.201500213	journal	November 2015
Ionic Conductivity Enhancement of Polymer Electrolytes with Ceramic Nanowire Fillers Liu, Wei; Liu, Nian; Sun, Jie Nano Letters, Vol. 15, Issue 4, p. 2740-2745 https://doi.org/10.1021/acs.nanolett.5b00600	journal	March 2015
Ionic conductivity in crystalline polymer electrolytes Gadjourova, Zlatka; Andreev, Yuri G.; Tunstall, David P. Nature, Vol. 412, Issue 6846 https://doi.org/10.1038/35087538	journal	August 2001
Effect of nano-silica filler in polymer electrolyte on Li dendrite formation in Li/poly(ethylene oxide)–Li(CF3SO2)2N/Li Liu, S.; Imanishi, N.; Zhang, T. Journal of Power Sources, Vol. 195, Issue 19 https://doi.org/10.1016/j.jpowsour.2010.04.027	journal	October 2010
Recent developments in garnet based solid state electrolytes for thin film batteries Teng, Shiang; Tan, Jiajia; Tiwari, Ashutosh Current Opinion in Solid State and Materials Science, Vol. 18, Issue 1 https://doi.org/10.1016/j.cossms.2013.10.002	journal	February 2014
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Conductivity studies on ceramic Li1.3Al0.3Ti1.7(PO4)3-filled PEO-based solid composite polymer electrolytes Wang, Yan-Jie; Pan, Yi; Kim, Dukjoon Journal of Power Sources, Vol. 159, Issue 1 https://doi.org/10.1016/j.jpowsour.2005.10.104	journal	September 2006
Increasing the conductivity of crystalline polymer electrolytes Christie, Alasdair M.; Lilley, Scott J.; Staunton, Edward Nature, Vol. 433, Issue 7021 https://doi.org/10.1038/nature03186	journal	January 2005
Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects Yin, Ya-Xia; Xin, Sen; Guo, Yu-Guo Angewandte Chemie International Edition, Vol. 52, Issue 50 https://doi.org/10.1002/anie.201304762	journal	November 2013
Design principles for solid-state lithium superionic conductors Wang, Yan; Richards, William Davidson; Ong, Shyue Ping Nature Materials, Vol. 14, Issue 10 https://doi.org/10.1038/nmat4369	journal	August 2015
Safety-Reinforced Poly(Propylene Carbonate)-Based All-Solid-State Polymer Electrolyte for Ambient-Temperature Solid Polymer Lithium Batteries Zhang, Jianjun; Zhao, Jianghui; Yue, Liping Advanced Energy Materials, Vol. 5, Issue 24 https://doi.org/10.1002/aenm.201501082	journal	October 2015
Nanocomposite polymer electrolytes for lithium batteries Croce, F.; Appetecchi, G. B.; Persi, L. Nature, Vol. 394, Issue 6692 https://doi.org/10.1038/28818	journal	July 1998
An improved high-performance lithium–air battery Jung, Hun-Gi; Hassoun, Jusef; Park, Jin-Bum Nature Chemistry, Vol. 4, Issue 7 https://doi.org/10.1038/nchem.1376	journal	June 2012
Solid-State Li-Ion Batteries Using Fast, Stable, Glassy Nanocomposite Electrolytes for Good Safety and Long Cycle-Life Tan, Guoqiang; Wu, Feng; Zhan, Chun Nano Letters, Vol. 16, Issue 3 https://doi.org/10.1021/acs.nanolett.5b05234	journal	February 2016
Low-Cost Hollow Mesoporous Polymer Spheres and All-Solid-State Lithium, Sodium Batteries Zhou, Weidong; Gao, Hongcai; Goodenough, John B. Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501802	journal	October 2015
Polymer Nanofiber-Guided Uniform Lithium Deposition for Battery Electrodes Liang, Zheng; Zheng, Guangyuan; Liu, Chong Nano Letters, Vol. 15, Issue 5 https://doi.org/10.1021/nl5046318	journal	April 2015
Hybrid Electrolytes with Controlled Network Structures for Lithium Metal Batteries Pan, Qiwei; Smith, Derrick M.; Qi, Hao Advanced Materials, Vol. 27, Issue 39 https://doi.org/10.1002/adma.201502059	journal	August 2015
A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles Choudhury, Snehashis; Mangal, Rahul; Agrawal, Akanksha Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms10101	journal	December 2015
The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li₇La₃Zr₂O₁₂ Rangasamy, Ezhiyl; Wolfenstine, Jeff; Sakamoto, Jeffrey Solid State Ionics, Vol. 206, p. 28-32 https://doi.org/10.1016/j.ssi.2011.10.022	journal	January 2012
Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives Quartarone, Eliana; Mustarelli, Piercarlo Chemical Society Reviews, Vol. 40, Issue 5 https://doi.org/10.1039/c0cs00081g	journal	January 2011
Flexible Ion-Conducting Composite Membranes for Lithium Batteries Aetukuri, Nagaphani B.; Kitajima, Shintaro; Jung, Edward Advanced Energy Materials, Vol. 5, Issue 14 https://doi.org/10.1002/aenm.201500265	journal	May 2015

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Recent Progress in All-Solid-State Lithium−Sulfur Batteries Using High Li-Ion Conductive Solid Electrolytes Umeshbabu, Ediga; Zheng, Bizhu; Yang, Yong Electrochemical Energy Reviews, Vol. 2, Issue 2 https://doi.org/10.1007/s41918-019-00029-3	journal	February 2019
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Energy storage: The future enabled by nanomaterials Pomerantseva, Ekaterina; Bonaccorso, Francesco; Feng, Xinliang Science, Vol. 366, Issue 6468 https://doi.org/10.1126/science.aan8285	journal	November 2019
Enhanced Surface Interactions Enable Fast Li ⁺ Conduction in Oxide/Polymer Composite Electrolyte Wu, Nan; Chien, Po‐Hsiu; Qian, Yumin Angewandte Chemie International Edition, Vol. 59, Issue 10 https://doi.org/10.1002/anie.201914478	journal	January 2020
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Nanoflake Arrays of Lithiophilic Metal Oxides for the Ultra-Stable Anodes of Lithium-Metal Batteries Yu, Baozhi; Tao, Tao; Mateti, Srikanth Advanced Functional Materials, Vol. 28, Issue 36 https://doi.org/10.1002/adfm.201803023	journal	July 2018
Thick Electrode Batteries: Principles, Opportunities, and Challenges Kuang, Yudi; Chen, Chaoji; Kirsch, Dylan Advanced Energy Materials, Vol. 9, Issue 33 https://doi.org/10.1002/aenm.201901457	journal	July 2019
Progress and Perspective of Solid-State Lithium-Sulfur Batteries Lei, Danni; Shi, Kai; Ye, Heng Advanced Functional Materials, Vol. 28, Issue 38 https://doi.org/10.1002/adfm.201707570	journal	March 2018
Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries Fan, Lei; Wei, Shuya; Li, Siyuan Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702657	journal	January 2018
A polyoxometalate-based polymer electrolyte with an improved electrode interface and ion conductivity for high-safety all-solid-state batteries Yuan, Xiangfei; Sun, Cui; Duan, Jia-Ning Journal of Materials Chemistry A, Vol. 7, Issue 26 https://doi.org/10.1039/c9ta04714j	journal	January 2019
A Si-doped flexible self-supporting comb-like polyethylene glycol copolymer (Si-PEG) film as a polymer electrolyte for an all solid-state lithium-ion battery Ji, Xiaoxiao; Zeng, Huihui; Gong, Xianjing Journal of Materials Chemistry A, Vol. 5, Issue 46 https://doi.org/10.1039/c7ta07741f	journal	January 2017
Dense freeze-cast Li ₇ La ₃ Zr ₂ O ₁₂ solid electrolytes with oriented open porosity and contiguous ceramic scaffold Buannic, Lucienne; Naviroj, Maninpat; Miller, Sarah M. Journal of the American Ceramic Society, Vol. 102, Issue 3 https://doi.org/10.1111/jace.15938	journal	August 2018
Flexible and Stretchable Energy Storage: Recent Advances and Future Perspectives Liu, Wei; Song, Min-Sang; Kong, Biao Advanced Materials, Vol. 29, Issue 1 https://doi.org/10.1002/adma.201603436	journal	November 2016
Zirconium‐Based Materials for Electrochemical Energy Storage Wang, Jianda; Xiao, Xiao; Lu, Yao ChemElectroChem, Vol. 6, Issue 7 https://doi.org/10.1002/celc.201801586	journal	February 2019
Superlithiophilic graphene-silver enabling ultra-stable hosts for lithium metal anodes Zhuang, Huifeng; Zhao, Ping; Xu, Yue Inorganic Chemistry Frontiers, Vol. 7, Issue 4 https://doi.org/10.1039/c9qi01457h	journal	January 2020
The Role of Current Collector in Enabling the High Performance of Li/S Battery Benítez, Almudena; Caballero, Álvaro; Rodríguez-Castellón, Enrique ChemistrySelect, Vol. 3, Issue 37 https://doi.org/10.1002/slct.201802529	journal	October 2018
Mixed Ionic and Electronic Conductor for Li-Metal Anode Protection Yan, Jianhua; Yu, Jianyong; Ding, Bin Advanced Materials, Vol. 30, Issue 7 https://doi.org/10.1002/adma.201705105	journal	January 2018
A Single‐Ion Conducting Borate Network Polymer as a Viable Quasi‐Solid Electrolyte for Lithium Metal Batteries Shin, Dong‐Myeong; Bachman, Jonathan E.; Taylor, Mercedes K. Advanced Materials, Vol. 32, Issue 10 https://doi.org/10.1002/adma.201905771	journal	January 2020
A versatile and membrane-less electrochemical reactor for the electrolysis of water and brine Hashemi, S. Mohammad H.; Karnakov, Petr; Hadikhani, Pooria ETH Zurich https://doi.org/10.3929/ethz-b-000344975	text	January 2019
Progress and Perspective of Ceramic/Polymer Composite Solid Electrolytes for Lithium Batteries Li, Song; Zhang, Shi‐Qi; Shen, Lu Advanced Science, Vol. 7, Issue 5 https://doi.org/10.1002/advs.201903088	journal	January 2020
A Review of Inactive Materials and Components of Flexible Lithium-Ion Batteries Foreman, Evan; Zakri, Waleed; Hossein Sanatimoghaddam, Mohammad Advanced Sustainable Systems, Vol. 1, Issue 11 https://doi.org/10.1002/adsu.201700061	journal	September 2017
Enzyme-assisted mechanical grinding for cellulose nanofibers from bagasse: energy consumption and nanofiber characteristics Liu, Xiuyu; Jiang, Yan; Qin, Chengrong Cellulose, Vol. 25, Issue 12 https://doi.org/10.1007/s10570-018-2071-1	journal	October 2018
Innovation and challenges in materials design for flexible rechargeable batteries: from 1D to 3D He, Yanghua; Matthews, Bryan; Wang, Jingyun Journal of Materials Chemistry A, Vol. 6, Issue 3 https://doi.org/10.1039/c7ta09301b	journal	January 2018
Design Principles of the Anode–Electrolyte Interface for All Solid‐State Lithium Metal Batteries Shen, Zeyu; Zhang, Weidong; Zhu, Guannan Small Methods, Vol. 4, Issue 1 https://doi.org/10.1002/smtd.201900592	journal	October 2019
Anion‐Sorbent Composite Separators for High‐Rate Lithium‐Ion Batteries Zhang, Chen; Shen, Li; Shen, Jianqiang Advanced Materials, Vol. 31, Issue 21 https://doi.org/10.1002/adma.201808338	journal	April 2019
Impedance Spectroscopy Analysis of the Lithium Ion Transport through the Li ₇ La ₃ Zr ₂ O ₁₂ /P(EO) ₂₀ Li Interface Langer, Frederieke; Palagonia, Maria Sofia; Bardenhagen, Ingo Journal of The Electrochemical Society, Vol. 164, Issue 12 https://doi.org/10.1149/2.0381712jes	journal	January 2017
Flexible, Scalable, and Highly Conductive Garnet-Polymer Solid Electrolyte Templated by Bacterial Cellulose Xie, Hua; Yang, Chunpeng; Fu, Kun Kelvin Advanced Energy Materials, Vol. 8, Issue 18 https://doi.org/10.1002/aenm.201703474	journal	March 2018
Dendrite‐Free Lithium Deposition via a Superfilling Mechanism for High‐Performance Li‐Metal Batteries Wang, Qian; Yang, Chengkai; Yang, Jijin Advanced Materials, Vol. 31, Issue 41 https://doi.org/10.1002/adma.201903248	journal	August 2019
Building Better Batteries in the Solid State: A Review Mauger, Alain; Julien, Christian M.; Paolella, Andrea Materials, Vol. 12, Issue 23, p. 3892 https://doi.org/10.3390/ma12233892	journal	November 2019
Solvent‐Free Synthesis of Thin, Flexible, Nonflammable Garnet‐Based Composite Solid Electrolyte for All‐Solid‐State Lithium Batteries Jiang, Taoli; He, Pingge; Wang, Guoxu Advanced Energy Materials, Vol. 10, Issue 12 https://doi.org/10.1002/aenm.201903376	journal	March 2020
Low Resistance-Integrated All-Solid-State Battery Achieved by Li ₇ La ₃ Zr ₂ O ₁₂ Nanowire Upgrading Polyethylene Oxide (PEO) Composite Electrolyte and PEO Cathode Binder Wan, Zipei; Lei, Danni; Yang, Wei Advanced Functional Materials, Vol. 29, Issue 1 https://doi.org/10.1002/adfm.201805301	journal	October 2018
Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries Guo, Yanpeng; Li, Huiqiao; Zhai, Tianyou Advanced Materials, Vol. 29, Issue 29 https://doi.org/10.1002/adma.201700007	journal	June 2017
Realization of the Li ⁺ domain diffusion effect via constructing molecular brushes on the LLZTO surface and its application in all-solid-state lithium batteries Li, Wenwen; Sun, Changzhi; Jin, Jun Journal of Materials Chemistry A, Vol. 7, Issue 48 https://doi.org/10.1039/c9ta10400c	journal	January 2019
Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid Yang, Chunpeng; Fu, Kun; Zhang, Ying Advanced Materials, Vol. 29, Issue 36 https://doi.org/10.1002/adma.201701169	journal	July 2017
The Challenge of Lithium Metal Anodes for Practical Applications Chen, Yuqing; Luo, Yang; Zhang, Hongzhang Small Methods, Vol. 3, Issue 7 https://doi.org/10.1002/smtd.201800551	journal	April 2019
Recent advances in solid polymer electrolytes for lithium batteries Zhang, Qingqing; Liu, Kai; Ding, Fei Nano Research, Vol. 10, Issue 12 https://doi.org/10.1007/s12274-017-1763-4	journal	August 2017
Composite lithium electrode with mesoscale skeleton via simple mechanical deformation Liang, Zheng; Yan, Kai; Zhou, Guangmin Science Advances, Vol. 5, Issue 3 https://doi.org/10.1126/sciadv.aau5655	journal	March 2019
Mechanistic understanding and strategies to design interfaces of solid electrolytes: insights gained from transmission electron microscopy Hood, Zachary D.; Chi, Miaofang Journal of Materials Science, Vol. 54, Issue 15 https://doi.org/10.1007/s10853-019-03633-2	journal	May 2019
An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing Proceedings of the National Academy of Sciences, Vol. 114, Issue 42 https://doi.org/10.1073/pnas.1708489114	journal	October 2017
Tough Gel Electrolyte Using Double Polymer Network Design for the Safe, Stable Cycling of Lithium Metal Anode Wu, Haiping; Cao, Yue; Su, Haiping Angewandte Chemie International Edition, Vol. 57, Issue 5 https://doi.org/10.1002/anie.201709774	journal	January 2018
Interface Engineering for Garnet-Based Solid-State Lithium-Metal Batteries: Materials, Structures, and Characterization Dai, Jiaqi; Yang, Chunpeng; Wang, Chengwei Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201802068	journal	October 2018
Nanostructured Metal Oxides and Sulfides for Lithium-Sulfur Batteries Liu, Xue; Huang, Jia-Qi; Zhang, Qiang Advanced Materials, Vol. 29, Issue 20 https://doi.org/10.1002/adma.201601759	journal	February 2017
Simultaneously Enhancing the Thermal Stability, Mechanical Modulus, and Electrochemical Performance of Solid Polymer Electrolytes by Incorporating 2D Sheets Tang, Wenjing; Tang, Shan; Zhang, Cuijuan Advanced Energy Materials, Vol. 8, Issue 24 https://doi.org/10.1002/aenm.201800866	journal	June 2018
Enhanced Surface Interactions Enable Fast Li ⁺ Conduction in Oxide/Polymer Composite Electrolyte Wu, Nan; Chien, Po‐Hsiu; Qian, Yumin Angewandte Chemie, Vol. 132, Issue 10 https://doi.org/10.1002/ange.201914478	journal	January 2020
Research Progress of the Solid State Lithium-Sulfur Batteries Wang, HangChao; Cao, Xin; Liu, Wen Frontiers in Energy Research, Vol. 7 https://doi.org/10.3389/fenrg.2019.00112	journal	October 2019
Controlling Nucleation in Lithium Metal Anodes Guan, Xuze; Wang, Aoxuan; Liu, Shan Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201801423	journal	July 2018
Li ⁺ ‐Containing, Continuous Silica Nanofibers for High Li ⁺ Conductivity in Composite Polymer Electrolyte Yu, Jianming; Wang, Chao; Li, Shiheng Small, Vol. 15, Issue 44 https://doi.org/10.1002/smll.201902729	journal	September 2019
Transient Behavior of the Metal Interface in Lithium Metal-Garnet Batteries Fu, Kun Kelvin; Gong, Yunhui; Fu, Zhezhen Angewandte Chemie International Edition, Vol. 56, Issue 47 https://doi.org/10.1002/anie.201708637	journal	October 2017
Review : Solid Electrolytes for Safe and High Energy Density Lithium-Sulfur Batteries : Promises and Challenges Judez, Xabier; Zhang, Heng; Li, Chunmei RWTH Aachen University https://doi.org/10.18154/rwth-2021-07455	text	January 2018
An Aqueous Inorganic Polymer Binder for High Performance Lithium–Sulfur Batteries with Flame-Retardant Properties Zhou, Guangmin; Liu, Kai; Fan, Yanchen ACS Central Science, Vol. 4, Issue 2 https://doi.org/10.1021/acscentsci.7b00569	journal	February 2018
Employing of Trukhan Model to Estimate Ion Transport Parameters in PVA Based Solid Polymer Electrolyte Polymers, Vol. 11, Issue 10 https://doi.org/10.3390/polym11101694	journal	October 2019

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