Determining P, S, Br, and I content in uranium by triple quadrupole inductively coupled plasma mass spectrometry

Fletcher, Nathaniel; Manard, Benjamin; Metzger, Shalina; Ticknor, Brian; Bostick, Debra; Hexel, Cole

doi:10.1007/s10967-020-07057-0

Title: Determining P, S, Br, and I content in uranium by triple quadrupole inductively coupled plasma mass spectrometry

Journal Article · Thu Feb 20 00:00:00 EST 2020 · Journal of Radioanalytical and Nuclear Chemistry

DOI:https://doi.org/10.1007/s10967-020-07057-0· OSTI ID:1606841

Fletcher, Nathaniel ^[1];

^[2];

^[2]

Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

The trace impurities of a uranium ore concentrate (UOC) can be examined to determine mine source, methods of production, and quality. This study presents a method to determine the concentration of halides and main group elements, specifically P, S, Br and I, utilizing triple quadrupole inductively coupled plasma–mass spectrometry. These analytes were measured in a uranium matrix to simulate a UOC sample. The concentrations determined with this method showed agreement with known values. Solutions with and without uranium were compared. A UOC certified reference material, CUP-2, was analyzed to further demonstrate the effectiveness of the method.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1606841

Journal Information:: Journal of Radioanalytical and Nuclear Chemistry, Vol. 324, Issue 1; ISSN 0236-5731

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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References (30)

Attribution of uranium ore concentrates using elemental and anionic data Keegan, Elizabeth; Wallenius, Maria; Mayer, Klaus Applied Geochemistry, Vol. 27, Issue 8 https://doi.org/10.1016/j.apgeochem.2012.05.009	journal	August 2012
Characterization and classification of uranium ore concentrates (yellow cakes) using infrared spectrometry Varga, Zsolt; Öztürk, Betül; Meppen, Manuela Radiochimica Acta, Vol. 99, Issue 12 https://doi.org/10.1524/ract.2011.1886	journal	December 2011
An automated micro-separation system for the chromatographic removal of uranium matrix for trace element analysis by ICP-OES Wylie, E. Miller; Manard, Benjamin T.; Quarles, C. Derrick Talanta, Vol. 189 https://doi.org/10.1016/j.talanta.2018.06.063	journal	November 2018
Improved measurement of iodine in food samples using inductively coupled plasma isotope dilution mass spectrometry Haldimann, Max; Zimmerli, Bernhard; Eastgate, Alan The Analyst, Vol. 125, Issue 11 https://doi.org/10.1039/b005879n	journal	January 2000
Study on the identification of organic and common anions in the pyrohydrolysis distillate of mixed uranium-plutonium carbide for the interference free determination of chlorine and fluorine by ion chromatography Jeyakumar, Subbiah; Mishra, Vivekchandra Guruprasad; Das, Mrinal Kanti Radiochimica Acta, Vol. 102, Issue 4 https://doi.org/10.1515/ract-2013-2131	journal	January 2014
Determination of iodine in food samples by inductively coupled plasma mass spectrometry after alkaline extraction Fecher, Peter A.; Goldmann, Ingeborg; Nagengast, Anton Journal of Analytical Atomic Spectrometry, Vol. 13, Issue 9 https://doi.org/10.1039/a801671b	journal	January 1998
Inductively coupled plasma – Tandem mass spectrometry (ICP-MS/MS): A powerful and universal tool for the interference-free determination of (ultra)trace elements – A tutorial review Balcaen, Lieve; Bolea-Fernandez, Eduardo; Resano, Martín Analytica Chimica Acta, Vol. 894 https://doi.org/10.1016/j.aca.2015.08.053	journal	September 2015
Characterization of uranium ore concentrate chemical composition via Raman spectroscopy Johnson, Timothy J.; Su, Yin-Fong; Bryan, Samuel A. Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XIX https://doi.org/10.1117/12.2304304	conference	May 2018
Simultaneous Determination of Fluorine, Chlorine, Bromine and Iodine in Six Geochemical Reference Materials Using Pyrohydrolysis, Ion Chromatography and Inductively Coupled Plasma-Mass Spectrometry Balcone-Boissard, HÃ©lÃ¨ne; Michel, AgnÃ¨s; Villemant, BenoÃ®t Geostandards and Geoanalytical Research, Vol. 33, Issue 4 https://doi.org/10.1111/j.1751-908X.2009.00018.x	journal	December 2009
Trace impurity analysis in uranium oxide via hybrid quantification techniques—gravimetric standard addition and isotope dilution mass spectrometry Rogers, Kayron T.; Giaquinto, Joseph; Essex, Richard M. Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 1 https://doi.org/10.1007/s10967-018-6106-8	journal	August 2018
Determination of trace elements and lanthanide (REE) signatures in uranium mine products in South Africa by means of inductively coupled plasma mass spectrometry Khumalo, Ntokozo; Mathuthu, Manny Journal of Geochemical Exploration, Vol. 186 https://doi.org/10.1016/j.gexplo.2017.12.012	journal	March 2018
Nuclear Forensic Science: Analysis of Nuclear Material Out of Regulatory Control Kristo, Michael J.; Gaffney, Amy M.; Marks, Naomi Annual Review of Earth and Planetary Sciences, Vol. 44, Issue 1 https://doi.org/10.1146/annurev-earth-060115-012309	journal	June 2016
REVIEW: Iodine Determination by Inductively Coupled Plasma Spectrometry Oliveira, Adriana A.; Trevizan, Lilian C.; Nóbrega, Joaquim A. Applied Spectroscopy Reviews, Vol. 45, Issue 6 https://doi.org/10.1080/05704928.2010.502207	journal	November 2010
Determination of rare-earth elements in uranium-bearing materials by inductively coupled plasma mass spectrometry Varga, Zsolt; Katona, Róbert; Stefánka, Zsolt Talanta, Vol. 80, Issue 5 https://doi.org/10.1016/j.talanta.2009.10.018	journal	March 2010
Quantifying multiple trace elements in uranium ore concentrates: an interlaboratory comparison Bürger, S.; Boulyga, S. F.; Peńkin, M. V. Journal of Radioanalytical and Nuclear Chemistry, Vol. 301, Issue 3 https://doi.org/10.1007/s10967-014-3224-9	journal	June 2014
Tracing origins of uranium ore concentrates (UOCs) by multidimensional statistical analysis of rare-earth impurities Lin, Mu; Zhao, Yonggang; Zhao, Lifei Journal of Analytical Atomic Spectrometry, Vol. 30, Issue 2 https://doi.org/10.1039/C4JA00354C	journal	January 2015
Investigation of sulphur isotope variation due to different processes applied during uranium ore concentrate production Krajkó, Judit; Varga, Zsolt; Wallenius, Maria Journal of Radioanalytical and Nuclear Chemistry, Vol. 309, Issue 3 https://doi.org/10.1007/s10967-016-4733-5	journal	February 2016
Investigation of the sample characteristics needed for the determination of the origin of uranium-bearing materials Švedkauskaitė-LeGore, J.; Rasmussen, G.; Abousahl, S. Journal of Radioanalytical and Nuclear Chemistry, Vol. 278, Issue 1 https://doi.org/10.1007/s10967-007-7215-y	journal	June 2008
Development, validation and verification of an ICP-MS procedure for a multi-element analysis of uranium ore concentrates Boulyga, Sergei F.; Cunningham, J. Alan; Macsik, Zsuzsanna Journal of Analytical Atomic Spectrometry, Vol. 32, Issue 11 https://doi.org/10.1039/C7JA00180K	journal	January 2017
Anion analysis in uranium ore concentrates by ion chromatography Badaut, V.; Wallenius, M.; Mayer, K. Journal of Radioanalytical and Nuclear Chemistry, Vol. 280, Issue 1 https://doi.org/10.1007/s10967-008-7404-3	journal	March 2009
Iodine speciation studies in commercially available seaweed by coupling different chromatographic techniques with UV and ICP-MS detection Shah, Monika; Wuilloud, Rodolfo G.; Kannamkumarath, Sasi S. Journal of Analytical Atomic Spectrometry, Vol. 20, Issue 3 https://doi.org/10.1039/b415756g	journal	January 2005
Iodine (and Other Halogens) in Twenty Six Geological Reference Materials by ICP-MS and Ion Chromatography Schnetger, Bernhard; Muramatsu, Yasuyuki; Yoshida, Satoshi Geostandards and Geoanalytical Research, Vol. 22, Issue 2 https://doi.org/10.1111/j.1751-908X.1998.tb00690.x	journal	December 1998
Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
Simultaneous determinations of fluorine, chlorine, and sulfur in rock samples by ion chromatography combined with pyrohydrolysis Shimizu, Kenji; Suzuki, Katsuhiko; Saitoh, Masafumi GEOCHEMICAL JOURNAL, Vol. 49, Issue 1 https://doi.org/10.2343/geochemj.2.0338	journal	January 2015
Reaction cells and collision cells for ICP-MS: a tutorial review Tanner, Scott D.; Baranov, Vladimir I.; Bandura, Dmitry R. Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 57, Issue 9 https://doi.org/10.1016/S0584-8547(02)00069-1	journal	September 2002
Evaluation and Specifications for In-Line Uranium Separations Using Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) Detection for Trace Elemental Analysis Manard, Benjamin T.; Metzger, Shalina C.; Quarles, C. Derrick Applied Spectroscopy, Vol. 73, Issue 8 https://doi.org/10.1177/0003702819837650	journal	March 2019
Determination of Bromine and Iodine in Twenty-three Geochemical Reference Materials by ICP-MS Chai, Jian Y.; Muramatsu, Yasuyuki Geostandards and Geoanalytical Research, Vol. 31, Issue 2 https://doi.org/10.1111/j.1751-908X.2007.00856.x	journal	June 2007
Applicability of Raman spectroscopy as a tool in nuclear forensics for analysis of uranium ore concentrates Lin, D. Ho Mer; Manara, D.; Varga, Zs. Radiochimica Acta, Vol. 101, Issue 12 https://doi.org/10.1524/ract.2013.2110	journal	January 2013
Use of micro-Raman spectrometry coupled with scanning electron microscopy to determine the chemical form of uranium compounds in micrometer-size particles: Determining the chemical form of uranium compounds using micro-Raman spectrometry Pointurier, F.; Marie, O. Journal of Raman Spectroscopy, Vol. 44, Issue 12 https://doi.org/10.1002/jrs.4392	journal	October 2013
The provenance of Australian uranium ore concentrates by elemental and isotopic analysis Keegan, Elizabeth; Richter, Stephan; Kelly, Ian Applied Geochemistry, Vol. 23, Issue 4 https://doi.org/10.1016/j.apgeochem.2007.12.004	journal	April 2008

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