Enabling fast charging of lithium-ion batteries through secondary-/dual- pore network: Part II - numerical model

Mai, Weijie; Usseglio-Viretta, Francois L.E.; Colclasure, Andrew M.; Smith, Kandler

doi:10.1016/j.electacta.2020.136013

Title: Enabling fast charging of lithium-ion batteries through secondary-/dual- pore network: Part II - numerical model

Journal Article · Fri Mar 06 00:00:00 EST 2020 · Electrochimica Acta

DOI:https://doi.org/10.1016/j.electacta.2020.136013· OSTI ID:1606302

^[1];

^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States). Center for Integrated Mobility Sciences

To increase the market share of electric vehicles, it is desirable to reduce the battery charge times, which are significantly limited by poor electrolyte transport. A high rate charging is achievable by using expensive and low energy density cells with thin electrodes. For higher energy density cells, new electrolytes with improved conductivity and diffusivity and/or electrodes with advanced architecture are required to boost the electrolyte transport, leading to a more uniform utilization of active materials. In our previous work, an analytical model was developed to investigate the effect of secondary pore network (SPN) on electrolyte transport and the configuration of SPN was optimized by enforcing equal characteristic diffusion times in through-plane and in-plane directions. Here, to evaluate the effect of SPN on the fast-charging capability of lithium-ion batteries, a 2D physics-based electrochemical model is developed with SPN in either one or both electrodes. Additionally, the effect of SPN on cell energy density and lithium plating is investigated for cells with different loadings and electrode porosities. Combining SPN with elevated charging temperatures, the model predicts that the volumetric discharge energy density of a 3 mA h/cm2 cell can reach 270 Wh/L after a 6C constant-current charging.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1606302

Alternate ID(s):: OSTI ID: 1691874

Report Number(s):: NREL/JA-5400-75454; MainId:16965; UUID:68b950f4-1307-ea11-9c2a-ac162d87dfe5; MainAdminID:5443

Journal Information:: Electrochimica Acta, Vol. 341; ISSN 0013-4686

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 29 works

Citation information provided by
Web of Science

References (22)

Enabling fast charging – A battery technology gap assessment Ahmed, Shabbir; Bloom, Ira; Jansen, Andrew N. Journal of Power Sources, Vol. 367 https://doi.org/10.1016/j.jpowsour.2017.06.055	journal	November 2017
Design of Battery Electrodes with Dual-Scale Porosity to Minimize Tortuosity and Maximize Performance Bae, Chang-Jun; Erdonmez, Can K.; Halloran, John W. Advanced Materials, Vol. 25, Issue 9 https://doi.org/10.1002/adma.201204055	journal	December 2012
Requirements for Enabling Extreme Fast Charging of High Energy Density Li-Ion Cells while Avoiding Lithium Plating Colclasure, Andrew M.; Dunlop, Alison R.; Trask, Stephen E. Journal of The Electrochemical Society, Vol. 166, Issue 8 https://doi.org/10.1149/2.0451908jes	journal	January 2019
Fast charging of lithium-ion batteries at all temperatures Yang, Xiao-Guang; Zhang, Guangsheng; Ge, Shanhai Proceedings of the National Academy of Sciences, Vol. 115, Issue 28 https://doi.org/10.1073/pnas.1807115115	journal	June 2018
All-Climate Battery Technology for Electric Vehicles: Inching Closer to the Mainstream Adoption of Automated Driving Yang, Xiao-Guang; Ge, Shanhai; Wu, Ningning IEEE Electrification Magazine, Vol. 7, Issue 1 https://doi.org/10.1109/MELE.2018.2889545	journal	March 2019
Performance enhancement of Li-ion battery by laser structuring of thick electrode with low porosity Park, Junsu; Hyeon, Seongsik; Jeong, Sungho Journal of Industrial and Engineering Chemistry, Vol. 70 https://doi.org/10.1016/j.jiec.2018.10.012	journal	February 2019
Electrode scale and electrolyte transport effects on extreme fast charging of lithium-ion cells Colclasure, Andrew M.; Tanim, Tanvir R.; Jansen, Andrew N. Electrochimica Acta, Vol. 337 https://doi.org/10.1016/j.electacta.2020.135854	journal	March 2020
Magnetically aligned graphite electrodes for high-rate performance Li-ion batteries Billaud, Juliette; Bouville, Florian; Magrini, Tommaso Nature Energy, Vol. 1, Issue 8 https://doi.org/10.1038/nenergy.2016.97	journal	July 2016
High-performance battery electrodes via magnetic templating Sander, J. S.; Erb, R. M.; Li, L. Nature Energy, Vol. 1, Issue 8 https://doi.org/10.1038/nenergy.2016.99	journal	July 2016
Modeling mass and density distribution effects on the performance of co-extruded electrodes for high energy density lithium-ion batteries Cobb, Corie L.; Blanco, Mario Journal of Power Sources, Vol. 249 https://doi.org/10.1016/j.jpowsour.2013.10.084	journal	March 2014
Communication—Analysis of Thick Co-Extruded Cathodes for Higher-Energy-and-Power Lithium-Ion Batteries Cobb, Corie L.; Solberg, Scott E. Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0101707jes	journal	January 2017
Capacitive Performance and Tortuosity of Activated Carbon Electrodes with Macroscopic Pores Reale, Erik R.; Smith, Kyle C. Journal of The Electrochemical Society, Vol. 165, Issue 9 https://doi.org/10.1149/2.0601809jes	journal	January 2018
Reducing impedance to ionic flux in capacitive deionization with Bi-tortuous activated carbon electrodes coated with asymmetrically charged polyelectrolytes Bhat, Akash P.; Reale, Erik R.; del Cerro, Martina Water Research X, Vol. 3 https://doi.org/10.1016/j.wroa.2019.100027	journal	April 2019
Coral-like directional porosity lithium ion battery cathodes by ice templating Huang, Chun; Grant, Patrick S. Journal of Materials Chemistry A, Vol. 6, Issue 30 https://doi.org/10.1039/C8TA05049J	journal	January 2018
Electrochemical Characterization of High Energy Density Graphite Electrodes Made by Freeze-Casting Amin, Ruhul; Delattre, Benjamin; Tomsia, Antoni P. ACS Applied Energy Materials, Vol. 1, Issue 9 https://doi.org/10.1021/acsaem.8b00962	journal	July 2018
Enabling fast charging of lithium-ion batteries through secondary- /dual- pore network: Part I - Analytical diffusion model Usseglio-Viretta, F. L. E.; Mai, W.; Colclasure, A. M. Electrochimica Acta, Vol. 342 https://doi.org/10.1016/j.electacta.2020.136034	journal	May 2020
Increasing the Discharge Rate Capability of Lithium-Ion Cells with Laser-Structured Graphite Anodes: Modeling and Simulation Habedank, Jan B.; Kraft, Ludwig; Rheinfeld, Alexander Journal of The Electrochemical Society, Vol. 165, Issue 7 https://doi.org/10.1149/2.1181807jes	journal	January 2018
Modeling and Simulation of Pore Morphology Modifications using Laser-Structured Graphite Anodes in Lithium-Ion Batteries Kraft, Ludwig; Habedank, Jan B.; Frank, Alexander Journal of The Electrochemical Society, Vol. 167, Issue 1 https://doi.org/10.1149/2.0062001JES	journal	September 2019
Resolving the Discrepancy in Tortuosity Factor Estimation for Li-Ion Battery Electrodes through Micro-Macro Modeling and Experiment Usseglio-Viretta, Francois L. E.; Colclasure, Andrew; Mistry, Aashutosh N. Journal of The Electrochemical Society, Vol. 165, Issue 14 https://doi.org/10.1149/2.0731814jes	journal	January 2018
Galvanostatic Intermittent Titration and Performance Based Analysis of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Verma, Ankit; Smith, Kandler; Santhanagopalan, Shriram Journal of The Electrochemical Society, Vol. 164, Issue 13 https://doi.org/10.1149/2.1701713jes	journal	January 2017
Tortuosity Anisotropy in Lithium-Ion Battery Electrodes Ebner, Martin; Chung, Ding-Wen; García, R. Edwin Advanced Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aenm.201301278	journal	October 2013
Design of Bi-Tortuous, Anisotropic Graphite Anodes for Fast Ion-Transport in Li-Ion Batteries Nemani, V. Pavan; Harris, Stephen J.; Smith, Kyle C. Journal of The Electrochemical Society, Vol. 162, Issue 8 https://doi.org/10.1149/2.0151508jes	journal	January 2015

Similar Records

Enabling fast charging of lithium-ion batteries through secondary- /dual- pore network: Part I - Analytical diffusion model

Journal Article · Thu Mar 12 00:00:00 EDT 2020 · Electrochimica Acta · OSTI ID:1606302

Usseglio Viretta, Francois; Mai, W.; Colclasure, Andrew; +3 more

Secondary Pore Network Design Optimization Analytical Diffusion Model for Lithium Ion Battery

Software · Wed Dec 18 00:00:00 EST 2019 · OSTI ID:1606302

Usseglio Viretta, Francois; Mai, Weijie

Requirements for Enabling Extreme Fast Charging of High Energy Density Li-Ion Cells while Avoiding Lithium Plating

Journal Article · Mon Apr 29 00:00:00 EDT 2019 · Journal of the Electrochemical Society · OSTI ID:1606302

Colclasure, Andrew M.; Dunlop, Alison R.; Trask, Stephen E.; +3 more

Related Subjects

25 ENERGY STORAGE
fast charging
secondary-pore network
dual-pore network
lithium plating
optimization study

Title: Enabling fast charging of lithium-ion batteries through secondary-/dual- pore network: Part II - numerical model

Citation Formats

References (22)

Similar Records

Related Subjects