Directed Self-Assembly of MOF-Derived Nanoparticles toward Hierarchical Structures for Enhanced Catalytic Activity in CO Oxidation

Zhang, Suoying; Li, Hang; Liu, Pengfei; Ma, Lu; Li, Licheng; Zhang, Weina; Meng, Fanchen; Li, Long; Yang, Zhuhong; Wu, Tianpin; Huo, Fengwei; Lu, Jun

doi:10.1002/aenm.201901754

Title: Directed Self-Assembly of MOF-Derived Nanoparticles toward Hierarchical Structures for Enhanced Catalytic Activity in CO Oxidation

Journal Article · Tue Nov 12 00:00:00 EST 2019 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201901754· OSTI ID:1605901

Zhang, Suoying ^[1]; Li, Hang ^[2]; Liu, Pengfei ^[2]; Ma, Lu ^[3]; Li, Licheng ^[4]; Zhang, Weina ^[2]; Meng, Fanchen ^[2]; Li, Long ^[4]; Yang, Zhuhong ^[2]; Wu, Tianpin ^[3]; Huo, Fengwei ^[2];

^[3]

Nanjing Tech Univ. (China); Argonne National Lab. (ANL), Argonne, IL (United States)
Nanjing Tech Univ. (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Nanjing Forest Univ. (China)

The controllable self-assembly of nanomaterials remains a great challenge in nanotechnological applications, especially for the hierarchical structure with high complexity. Herein, by taking the advantage of highly dispersed metal nodes and mild thermal stability of metal-organic frameworks (MOFs), the self-assembly of nanoparticles is directed from MOFs to construct CuO hierarchical structures, which have an inherited octahedral framework consisting of the microspheres, nanowires, and polyhedrons, respectively. Unlike the conventional self-assembly in a solution media (such as solvent and molten solid), the assembly in this work is the first demonstration through a solution-free approach. Finally, compared to the general MOF-derived CuO octahedron, the assembled hierarchical CuO structure exhibits much enhanced catalytic activity in CO oxidation thanks to the exposure of more active sites during the assembly.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); National Science Funds for Distinguished Young Scholars; Natural Science Foundation (NSF); China Scholarship Council; China National Postdoctoral Council

Grant/Contract Number:: AC02-06CH11357; 2017YFA0207201; 21574065; 21604038; 21908105; BK20160975; BK20160993; 2016M591837; 201608320067; 20170020; AC02‐06CH11357

OSTI ID:: 1605901

Alternate ID(s):: OSTI ID: 1574036

Journal Information:: Advanced Energy Materials, Vol. 9, Issue 48; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 25 works

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