Photoelectron spectroscopic and computational study of [EDTA•M(III)]- complexes (M = H3, Al, Sc, V-Co)

Yuan, Qinqin; Kong, Xiang-Tao; Hou, Gaolei; Jiang, Ling; Wang, Xue-Bin

doi:10.1039/c8cp01548a

Title: Photoelectron spectroscopic and computational study of [EDTA•M(III)]- complexes (M = H3, Al, Sc, V-Co)

Journal Article · Tue Aug 07 00:00:00 EDT 2018 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/c8cp01548a· OSTI ID:1601787

Yuan, Qinqin ^[1]; Kong, Xiang-Tao ^[2];

^[3]; Jiang, Ling ^[2];

^[3]

UNIVERSITY PROGRAMS
Chinese Academy of Sciences
BATTELLE (PACIFIC NW LAB)

Metal-EDTA complexes are commonly existed as biological redox reagents. We havegenerated a series of such complexes, [EDTA•M(III)]- (M = Al, Sc, V-Co), via electrospray ionization and characterized them by cryogenic mass-selected negative ion photoelectron spectroscopy (NIPES) and theoretical calculations. Experiments clearly revealed one more spectral band at low electron binding energy for transition metal complexes with d electrons (M = V-Co) than those without d electrons (M = Al and Sc). Quantum chemical calculations suggested that all of the metal-complexes possess hexacoordinated metal-ligand binding motifs, from which the calculated adiabatic/vertical detachment energy (ADE/VDE) and band gaps are in good agreement with experimental values. Direct spectrum and electronic structure analyses indicted that [EDTA•V(III)]- can be easily oxidized to [EDTA•V(IV)] with the smallest ADE/VDE of 3.95/4.40 eV among these metal-complexes, but further oxidation is hindered by the existence of a 2.30 eV band gap, a fact that accords with the special redox behavior of vanadium-containing species in biology cells. Spin density and molecular orbital analyses reveal that [EDTA•V(III)]- was overwhelmingly detached from vanadium atom, in a stark contrast to [EDTA•Sc(III)/Al(III)]- where the detachment occurred from the EDTA ligand. For all other metal complex anions, from M = Cr to Co, the detachment process is derived from contributions from both the metal and ligand. The intrinsic electronic and geometric structures of these complexes, obtained in this work, provide a molecular foundation to better understand their redox chemistries and specific metal bindings in condensed phases and biology cells.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1601787

Report Number(s):: PNNL-SA-132912

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 20, Issue 29

Country of Publication:: United States

Language:: English

References (65)

Infrared Spectra of Aqueous Solutions. III. Ethylenediaminetetraacetic Acid, N-Hydroxyethylethylenediaminetriacetic Acid and Diethylenetriaminepentaacetic Acid Nakamoto, Kazuo.; Morimoto, Yukiyoshi.; Martell, Arthur E. Journal of the American Chemical Society, Vol. 85, Issue 3 https://doi.org/10.1021/ja00886a014	journal	February 1963
Structure and bonding in the metal complexes of ethylenediaminetetra-acetic acid Nuttall, R. Talanta, Vol. 24, Issue 6 https://doi.org/10.1016/0039-9140(77)80020-9	journal	June 1977
Coordination chemistry of hexadentate EDTA-type ligands with M(III) ions Douglas, Bodie E.; Radanović, Dušan J. Coordination Chemistry Reviews, Vol. 128, Issue 1-2 https://doi.org/10.1016/0010-8545(93)80027-3	journal	October 1993
The Analytical Uses of Ethylenediaminetetraacetic Acid Yoe, John H. Journal of the American Chemical Society, Vol. 80, Issue 10 https://doi.org/10.1021/ja01543a080	journal	May 1958
Cupric-selective electrode with copper(II)-EDTA for end point detection in chelometric titrations of metal ions Baumann, Elizabeth W.; Wallace, Richard M. Analytical Chemistry, Vol. 41, Issue 14 https://doi.org/10.1021/ac50159a050	journal	December 1969
Potentiometric and spectrophotometric determination of the stabilities of In(III), Ga(III) and Fe(III) complexes of N,N′,N″-tris(3,5-dimethyl-2-hydroxybenzyl)-1,4,7-triazacyclononane Clarke, Eric T.; Martell, Arthur E. Inorganica Chimica Acta, Vol. 186, Issue 1 https://doi.org/10.1016/S0020-1693(00)87938-4	journal	August 1991
Spectrophotometric determination of metal ions in electroplating solutions in the presence of EDTA with the aid of multivariate calibration and artificial neural networks Ni, Yongnian; Chen, Shouhui; Kokot, Serge Analytica Chimica Acta, Vol. 463, Issue 2 https://doi.org/10.1016/S0003-2670(02)00437-3	journal	July 2002
Speciation of EDTA in Natural Waters: Exchange Kinetics of Fe-EDTA in River Water Xue, Hanbin.; Sigg, Laura.; Kari, Franz Guenter. Environmental Science & Technology, Vol. 29, Issue 1 https://doi.org/10.1021/es00001a007	journal	January 1995
Dissolution of Fe(III) (hydr) oxides by metal-EDTA complexes Ngwack, Bernd; Sigg, Laura Geochimica et Cosmochimica Acta, Vol. 61, Issue 5 https://doi.org/10.1016/S0016-7037(96)00391-2	journal	March 1997
Simulation of the Mobility of Metal−EDTA Complexes in Groundwater: The Influence of Contaminant Metals Friedly, J. C.; Kent, D. B.; Davis, J. A. Environmental Science & Technology, Vol. 36, Issue 3 https://doi.org/10.1021/es010926m	journal	February 2002
EDTA: the chelating agent under environmental scrutiny Oviedo, Claudia; Rodríguez, Jaime Química Nova, Vol. 26, Issue 6 https://doi.org/10.1590/S0100-40422003000600020	journal	January 2003
EDTA-induced heavy metal accumulation and phytotoxicity in cardoon plants Hernández-Allica, Javier; Garbisu, Carlos; Barrutia, Oihana Environmental and Experimental Botany, Vol. 60, Issue 1 https://doi.org/10.1016/j.envexpbot.2006.06.006	journal	May 2007
An environmental benign process for cobalt and lithium recovery from spent lithium-ion batteries by mechanochemical approach Wang, Meng-Meng; Zhang, Cong-Cong; Zhang, Fu-Shen Waste Management, Vol. 51 https://doi.org/10.1016/j.wasman.2016.03.006	journal	May 2016
Mechanism of the Peroxidatic Activity of Iron(III)-EDTA in the Catalyzed Reaction of Hydrogen Peroxide with p-Amino-N,N-diethylaniline Mader, Paul M. Journal of the American Chemical Society, Vol. 82, Issue 11 https://doi.org/10.1021/ja01496a068	journal	June 1960
The kinetics of decomposition of hydrogen peroxide in the presence of ethylenediaminetetraacetatoiron(III) complex Rizkalla, E. N.; El-Shafey, O. H.; Guindy, N. M. Inorganica Chimica Acta, Vol. 57 https://doi.org/10.1016/S0020-1693(00)86968-6	journal	January 1982
The kinetics of the reaction of superoxide radical with Fe(III) complexes of EDTA, DETAPAC and HEDTA Buettner, Garry R.; Doherty, Thomas P.; Patterson, Larry K. FEBS Letters, Vol. 158, Issue 1 https://doi.org/10.1016/0014-5793(83)80695-4	journal	July 1983
The mechanism of iron EDTA catalyzed superoxide dismutation Bull, Christopher; McClune, Gregory J.; Fee, James A. Journal of the American Chemical Society, Vol. 105, Issue 16 https://doi.org/10.1021/ja00354a019	journal	August 1983
Incorporation of an EDTA-metal complex at a rationally selected site within a protein: application to EDTA-iron DNA affinity cleaving with catabolite gene activator protein (CAP) and Cro Ebright, Yon W.; Chen, Yan; Pendergrast, P. Shannon Biochemistry, Vol. 31, Issue 44 https://doi.org/10.1021/bi00159a004	journal	November 1992
Further Mechanistic Information on the Reaction between Fe ^III (edta) and Hydrogen Peroxide: Observation of a Second Reaction Step and Importance of pH Brausam, Ariane; van Eldik, Rudi Inorganic Chemistry, Vol. 43, Issue 17 https://doi.org/10.1021/ic0497580	journal	August 2004
Evaluation of Microbial Reduction of Fe(III)EDTA in a Chemical Absorption-Biological Reduction Integrated NO _x Removal System Li, Wei; Wu, Cheng-Zhi; Zhang, Shi-Han Environmental Science & Technology, Vol. 41, Issue 2 https://doi.org/10.1021/es061757e	journal	January 2007
Enzyme Immunoassay to Determine Heavy Metals Using Antibodies to Specific Metal-EDTA Complexes: Optimization and Validation of an Immunoassay for Soluble Indium Chakrabarti, P.; Hatcher, F. M.; Blake, R. C. Analytical Biochemistry, Vol. 217, Issue 1 https://doi.org/10.1006/abio.1994.1084	journal	February 1994
Basic Edta as an Extractant for Soil Organic Phosphorus Bowman, R. A.; Moir, J. O. Soil Science Society of America Journal, Vol. 57, Issue 6 https://doi.org/10.2136/sssaj1993.03615995005700060020x	journal	January 1993
Sodium Iron EDTA [NaFe(III)EDTA] as a Food Fortificant Does Not Influence Absorption and Urinary Excretion of Manganese in Healthy Adults Davidsson, Lena; Almgren, Annette; Hurrell, Richard F. The Journal of Nutrition, Vol. 128, Issue 7 https://doi.org/10.1093/jn/128.7.1139	journal	July 1998
Reduction of vanadium(V) to vanadium(IV) by NADPH, and vanadium(IV) to vanadium(III) by cysteine methyl ester in the presence of biologically relevant ligands Islam, Mohammad K.; Tsuboya, Chieko; Kusaka, Hiroko Biochimica et Biophysica Acta (BBA) - General Subjects, Vol. 1770, Issue 8 https://doi.org/10.1016/j.bbagen.2007.05.003	journal	August 2007
Reduction of Vanadium(IV) to Vanadium(III) by Cysteine Methyl Ester in Water in the Presence of Amino Polycarboxylates Kanamori, Kan; Kinebuchi, Yoshiko; Michibata, Hitoshi Chemistry Letters, Vol. 26, Issue 5 https://doi.org/10.1246/cl.1997.423	journal	May 1997
Study of metal–ligand species by ESI-MS: The case of La, Nd and Th complexes with EDTA Espinosa, Mariela Soledad; Servant, Roberto; Babay, Paola Alejandra Microchemical Journal, Vol. 129 https://doi.org/10.1016/j.microc.2016.06.018	journal	November 2016
EDTA, thymidine, and Cu2+ ion complexes from mass spectrometry data Paston, S. V.; Nikolaev, A. I.; Ushkov, P. A. Journal of Structural Chemistry, Vol. 58, Issue 2 https://doi.org/10.1134/S0022476617020251	journal	March 2017
On the EPR spectrum of the trivalent nickel EDTA complex in aqueous solutions Lati, J.; Koresh, J.; Meyerstein, D. Chemical Physics Letters, Vol. 33, Issue 2 https://doi.org/10.1016/0009-2614(75)80157-6	journal	June 1975
Detailed Spectroscopic and Theoretical Studies on [Fe(EDTA)(O ₂ )] ³ ^- : Electronic Structure of the Side-on Ferric−Peroxide Bond and Its Relevance to Reactivity Neese, Frank; Solomon, Edward I. Journal of the American Chemical Society, Vol. 120, Issue 49 https://doi.org/10.1021/ja981561h	journal	December 1998
NMR study of intramolecular processes in EDTA metal complexes Gennaro, Maria Clara; Mirti, Piero; Casalino, Claudio Polyhedron, Vol. 2, Issue 1 https://doi.org/10.1016/S0277-5387(00)88025-0	journal	January 1983
Assignment of the deuteron NMR spectra of chromium(III) complexes with edta and related ligands Wheeler, William D.; Legg, J. Ivan Inorganic Chemistry, Vol. 24, Issue 9 https://doi.org/10.1021/ic00203a007	journal	April 1985
Studies on mixed ligand complexes of ruthenium(III) edta with purines Taqui Khan, Badar; Annapoorna, K. Inorganica Chimica Acta, Vol. 176, Issue 2 https://doi.org/10.1016/S0020-1693(00)84850-1	journal	October 1990
Dynamic NMR of Intramolecular Exchange Processes in EDTA Complexes of Sc3+, Y3+, and La3+ Ba, Yong; Han, Steven; Ni, Lily Journal of Chemical Education, Vol. 83, Issue 2 https://doi.org/10.1021/ed083p296	journal	February 2006
FT-IR study of the adsorption of some complexones and of EDTA alkaline salts into alumina Ryczkowski, J. Vibrational Spectroscopy, Vol. 22, Issue 1-2 https://doi.org/10.1016/S0924-2031(99)00055-7	journal	February 2000
FTIR Spectra of the M(EDTA) ^n- Complexes in the Process of Sol-Gel Technique Zhao, Y. E.; Cai, C. Y.; Luo, Y. Y. Journal of Superconductivity, Vol. 17, Issue 3 https://doi.org/10.1023/B:JOSC.0000034263.79799.02	journal	June 2004
The Raman Spectral Study on the Solution Structure of Iron(III)-edta Complexes Kanamori, Kan; Dohniwa, Hidekazu; Ukita, Naoya Bulletin of the Chemical Society of Japan, Vol. 63, Issue 5 https://doi.org/10.1246/bcsj.63.1447	journal	May 1990
Vibrational spectra of two Fe(III)/EDTA complexes useful for iron supplementation Wagner, Claudia C.; Baran, Enrique J. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 75, Issue 2 https://doi.org/10.1016/j.saa.2009.11.059	journal	February 2010
The molecular structure of sodium (aqua)(ethylenediaminetetraacetato)-titanate(III) dihydrate, Na[Ti(H(2O)-(edta)]·2H2O, as determined by X-ray crystal analysis Mizuta, Tsutomu; Wang, Jun; Miyoshi, Katsuhiko Inorganica Chimica Acta, Vol. 203, Issue 2 https://doi.org/10.1016/S0020-1693(00)81665-5	journal	January 1993
A Seven Coordinate Co-EDTA Complex. Crystal and Molecular Structure of Aquo(ethylenediaminetriacetatoacetic acid)cobalt(III) Dihydrate Zubkowski, Jeffrey D.; Perry, Dale L.; Valente, Edward J. Inorganic Chemistry, Vol. 34, Issue 25 https://doi.org/10.1021/ic00129a028	journal	December 1995
Stereochemistry of Ethylenediaminetetraacetato Complexes. II. The Structure of Crystalline Rb[Fe(OH ₂ )Y].H ₂ O. III. The Structure of Crystalline Li[Fe(OH ₂ )Y.2H ₂ O Lind, M. D.; Hamor, M. J.; Hamor, T. A. Inorganic Chemistry, Vol. 3, Issue 1 https://doi.org/10.1021/ic50011a007	journal	January 1964
The crystal structure of (hydrogen ethylenediaminetetraacetato) aquoferrate(III) and gallate(III) Kennard, C. H. L. Inorganica Chimica Acta, Vol. 1 https://doi.org/10.1016/S0020-1693(00)93200-6	journal	January 1967
The ligand field stabilization effect on the metal-ligand bond distances in octahedral metal complexes with edta-type ligands. Redetermination of the molecular structure of (ethylenediaminetriacetatoacetic acid)-(aqua)iron(III), [Fe(Hedta)(H2O)] Mizuta, Tsutomu; Yamamoto, Tamotsu; Miyoshi, Katsuhiko Inorganica Chimica Acta, Vol. 175, Issue 1 https://doi.org/10.1016/S0020-1693(00)83206-5	journal	September 1990
Influence of Chelate Effects on the Water-Exchange Mechanism of Polyaminecarboxylate Complexes of Iron(III) Schneppensieper, Thorsten; Seibig, Sabine; Zahl, Achim Inorganic Chemistry, Vol. 40, Issue 15 https://doi.org/10.1021/ic001304p	journal	July 2001
A Detailed Mechanistic Study of the Substitution Behavior of an Unusual Seven-Coordinate Iron(III) Complex in Aqueous Solution Ivanovic-Burmazovic, Ivana; Hamza, Mohamed S. A.; van Eldik, Rudi Inorganic Chemistry, Vol. 41, Issue 20 https://doi.org/10.1021/ic0200803	journal	October 2002
Solvent Tuning of the Substitution Behavior of a Seven-Coordinate Iron(III) Complex Ivanović-Burmazović, Ivana; Hamza, Mohamed S. A.; van Eldik, Rudi Inorganic Chemistry, Vol. 45, Issue 4 https://doi.org/10.1021/ic0514694	journal	February 2006
Complex Formation Equilibria of Unusual Seven-Coordinate Fe(EDTA) Complexes with DNA Constituents and Related Bio-relevant Ligands El-Sherif, Ahmed A.; Shoukry, Mohamed M.; Hosny, Wafaa M. Journal of Solution Chemistry, Vol. 41, Issue 5 https://doi.org/10.1007/s10953-012-9833-4	journal	May 2012
Cluster Model Studies of Anion and Molecular Specificities via Electrospray Ionization Photoelectron Spectroscopy Wang, Xue-Bin The Journal of Physical Chemistry A, Vol. 121, Issue 7 https://doi.org/10.1021/acs.jpca.6b09784	journal	January 2017
Determination of the electron affinity of iodine Hanstorp, D.; Gustafsson, M. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 25, Issue 8 https://doi.org/10.1088/0953-4075/25/8/012	journal	April 1992
Evidence of Significant Covalent Bonding in Au(CN) ₂ ⁻ Wang, Xue-Bin; Wang, Yi-Lei; Yang, Jie Journal of the American Chemical Society, Vol. 131, Issue 45 https://doi.org/10.1021/ja908106e	journal	November 2009
Evaluation of the Performance of the B3LYP, PBE0, and M06 DFT Functionals, and DBLOC-Corrected Versions, in the Calculation of Redox Potentials and Spin Splittings for Transition Metal Containing Systems Coskun, Dilek; Jerome, Steven V.; Friesner, Richard A. Journal of Chemical Theory and Computation, Vol. 12, Issue 3 https://doi.org/10.1021/acs.jctc.5b00782	journal	February 2016
Performance of M06, M06-2X, and M06-HF Density Functionals for Conformationally Flexible Anionic Clusters: M06 Functionals Perform Better than B3LYP for a Model System with Dispersion and Ionic Hydrogen-Bonding Interactions Walker, Martin; Harvey, Andrew J. A.; Sen, Ananya The Journal of Physical Chemistry A, Vol. 117, Issue 47 https://doi.org/10.1021/jp408166m	journal	November 2013
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals Zhao, Yan; Truhlar, Donald G. Theoretical Chemistry Accounts, Vol. 120, Issue 1-3 https://doi.org/10.1007/s00214-007-0310-x	journal	July 2007
Anion A ^– • HX Clusters with Reduced Electron Binding Energies: Proton vs Hydrogen Atom Relocation upon Electron Detachment Wang, Xue-Bin; Kass, Steven R. Journal of the American Chemical Society, Vol. 136, Issue 49 https://doi.org/10.1021/ja510914d	journal	November 2014
DFT calculations on kinetic data for some [4+2] reactions in solution Li, Yue; Fang, De-Cai Physical Chemistry Chemical Physics, Vol. 16, Issue 29 https://doi.org/10.1039/c4cp02068e	journal	January 2014
Performance of Ab Initio and Density Functional Methods for Conformational Equilibria of C _n H _{2 n +2} Alkane Isomers ( n = 4−8) ^† Gruzman, David; Karton, Amir; Martin, Jan M. L. The Journal of Physical Chemistry A, Vol. 113, Issue 43 https://doi.org/10.1021/jp903640h	journal	October 2009
Ligand-Controlled Reactivity, Selectivity, and Mechanism of Cationic Ruthenium-Catalyzed Hydrosilylations of Alkynes, Ketones, and Nitriles: A Theoretical Study Yang, Yun-Fang; Chung, Lung Wa; Zhang, Xinhao The Journal of Organic Chemistry, Vol. 79, Issue 18 https://doi.org/10.1021/jo501730n	journal	August 2014
Multiwfn: A multifunctional wavefunction analyzer Lu, Tian; Chen, Feiwu Journal of Computational Chemistry, Vol. 33, Issue 5 https://doi.org/10.1002/jcc.22885	journal	December 2011
Microsolvation of the acetate anion [ ${CH}_{3} {CO}_{2}^{-} (H_{2} O)_{n}$ , n= 1–3]: A photoelectron spectroscopy and ab initio computational study Wang, Xue-Bin; Jagoda-Cwiklik, Barbara; Chi, Chaoxian Chemical Physics Letters, Vol. 477, Issue 1-3 https://doi.org/10.1016/j.cplett.2009.06.074	journal	July 2009
Crystal- and Solution-Structure Characteristics of Ethylenediaminetetraacetatoaluminate(III) and Gallate(III) Jung, Woo-Sik; Chung, Young Keun; Shin, Dong Mok Bulletin of the Chemical Society of Japan, Vol. 75, Issue 6 https://doi.org/10.1246/bcsj.75.1263	journal	June 2002
Study of Ion Specific Interactions of Alkali Cations with Dicarboxylate Dianions Murdachaew, Garold; Valiev, Marat; Kathmann, Shawn M. The Journal of Physical Chemistry A, Vol. 116, Issue 9 https://doi.org/10.1021/jp3012848	journal	February 2012
Probing the electronic structure of redox species and direct determination of intrinsic reorganization energies of electron transfer reactions Wang, Xue-Bin; Wang, Lai-Sheng The Journal of Chemical Physics, Vol. 112, Issue 16 https://doi.org/10.1063/1.481292	journal	April 2000
On the electronic structures of gaseous transition metal halide complexes, FeX4− and MX3− (M=Mn, Fe, Co, Ni, X=Cl, Br), using photoelectron spectroscopy and density functional calculations Yang, Xin; Wang, Xue-Bin; Wang, Lai-Sheng The Journal of Chemical Physics, Vol. 119, Issue 16 https://doi.org/10.1063/1.1610431	journal	October 2003
Photoelectron Spectroscopy of Anilinide and Acidity of Aniline Wren, Scott W.; Vogelhuber, Kristen M.; Ichino, Takatoshi The Journal of Physical Chemistry A, Vol. 116, Issue 12 https://doi.org/10.1021/jp211463r	journal	March 2012
Photoelectron Angular Distribution and Molecular Structure in Multiply Charged Anions Xing, Xiao-Peng; Wang, Xue-Bin; Wang, Lai-Sheng The Journal of Physical Chemistry A, Vol. 113, Issue 6 https://doi.org/10.1021/jp8073442	journal	February 2009
Direct reduction from vanadium(V) to vanadium(IV) by NADPH in the presence of EDTA. A consideration of the reduction and accumulation of vanadium in the ascidian blood cells Kanamori, Kan; Sakurai, Miki; Kinoshita, Tomoko Journal of Inorganic Biochemistry, Vol. 77, Issue 3-4 https://doi.org/10.1016/S0162-0134(99)00186-5	journal	November 1999

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