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Title: High-efficiency thermoelectric Ba[subscript 8]Cu[subscript 14]Ge[subscript 6]P[subscript 26]: bridging the gap between tetrel-based and tetrel-free clathrates

Authors:
; ; ; ; ; ;  [1]
  1. UCD
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
DOE - BASIC ENERGY SCIENCES
OSTI Identifier:
1600773
Resource Type:
Journal Article
Journal Name:
Chem. Sci.
Additional Journal Information:
Journal Volume: 8; Journal Issue: (12) ; 2017
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Wang, Jian, Lebedev, Oleg I., Lee, Kathleen, Dolyniuk, Juli-Anna, Klavins, Peter, Bux, Sabah, Kovnir, Kirill, CNRS-UMR), JPL), and Iowa State). High-efficiency thermoelectric Ba[subscript 8]Cu[subscript 14]Ge[subscript 6]P[subscript 26]: bridging the gap between tetrel-based and tetrel-free clathrates. United States: N. p., 2020. Web. doi:10.1039/C7SC03482B.
Wang, Jian, Lebedev, Oleg I., Lee, Kathleen, Dolyniuk, Juli-Anna, Klavins, Peter, Bux, Sabah, Kovnir, Kirill, CNRS-UMR), JPL), & Iowa State). High-efficiency thermoelectric Ba[subscript 8]Cu[subscript 14]Ge[subscript 6]P[subscript 26]: bridging the gap between tetrel-based and tetrel-free clathrates. United States. doi:10.1039/C7SC03482B.
Wang, Jian, Lebedev, Oleg I., Lee, Kathleen, Dolyniuk, Juli-Anna, Klavins, Peter, Bux, Sabah, Kovnir, Kirill, CNRS-UMR), JPL), and Iowa State). Thu . "High-efficiency thermoelectric Ba[subscript 8]Cu[subscript 14]Ge[subscript 6]P[subscript 26]: bridging the gap between tetrel-based and tetrel-free clathrates". United States. doi:10.1039/C7SC03482B.
@article{osti_1600773,
title = {High-efficiency thermoelectric Ba[subscript 8]Cu[subscript 14]Ge[subscript 6]P[subscript 26]: bridging the gap between tetrel-based and tetrel-free clathrates},
author = {Wang, Jian and Lebedev, Oleg I. and Lee, Kathleen and Dolyniuk, Juli-Anna and Klavins, Peter and Bux, Sabah and Kovnir, Kirill and CNRS-UMR) and JPL) and Iowa State)},
abstractNote = {},
doi = {10.1039/C7SC03482B},
journal = {Chem. Sci.},
number = (12) ; 2017,
volume = 8,
place = {United States},
year = {2020},
month = {2}
}

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    Works referencing / citing this record:

    Traversing the Metal-Insulator Transition in a Zintl Phase: Rational Enhancement of Thermoelectric Efficiency in Yb 14 Mn 1− x Al x Sb 11
    journal, September 2008

    • Toberer, Eric S.; Cox, Catherine A.; Brown, Shawna R.
    • Advanced Functional Materials, Vol. 18, Issue 18
    • DOI: 10.1002/adfm.200800298

    On the Design of High-Efficiency Thermoelectric Clathrates through a Systematic Cross-Substitution of Framework Elements
    journal, March 2010

    • Shi, Xun; Yang, Jiong; Bai, Shengqiang
    • Advanced Functional Materials, Vol. 20, Issue 5
    • DOI: 10.1002/adfm.200901817

    Band Engineering of Thermoelectric Materials
    journal, October 2012


    The Antimony-Based Type I Clathrate Compounds Cs8Cd18Sb28 and Cs8Zn18Sb28
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    • Liu, Yi; Wu, Li-Ming; Li, Long-Hua
    • Angewandte Chemie International Edition, Vol. 48, Issue 29
    • DOI: 10.1002/anie.200806158

    New and Old Concepts in Thermoelectric Materials
    journal, November 2009

    • Sootsman, Joseph R.; Chung, Duck Young; Kanatzidis, Mercouri G.
    • Angewandte Chemie International Edition, Vol. 48, Issue 46, p. 8616-8639
    • DOI: 10.1002/anie.200900598

    Breaking the Tetra-Coordinated Framework Rule: New Clathrate Ba 8 M 24 P 28+ δ ( M =Cu/Zn)
    journal, January 2017

    • Dolyniuk, Juli-Anna; Zaikina, Julia V.; Kaseman, Derrick C.
    • Angewandte Chemie International Edition, Vol. 56, Issue 9
    • DOI: 10.1002/anie.201611510

    The First Silicon-Based Cationic Clathrate III with High Thermal Stability: Si172−xPxTey (x=2y, y>20)
    journal, June 2008

    • Zaikina, Julia V.; Kovnir, Kirill A.; Haarmann, Frank
    • Chemistry - A European Journal, Vol. 14, Issue 18
    • DOI: 10.1002/chem.200800453

    Ba8Cu16P30 - eine neue tern�re Variante des Clathrat I-Strukturtyps
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    • D�nner, J.; Mewis, A.
    • Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 621, Issue 2
    • DOI: 10.1002/zaac.19956210205

    Ba8Ge43 revisited: a 2a?�2a?�2a? Superstructure of the Clathrate-I Type with Full Vacancy Ordering
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    • Carrillo-Cabrera, Wilder; Budnyk, Serhij; Prots, Yurii
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    • DOI: 10.1002/zaac.200400268

    Why are Clathrates Good Candidates for Thermoelectric Materials?
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    • Iversen, Bo B.; Palmqvist, Anders E. C.; Cox, David E.
    • Journal of Solid State Chemistry, Vol. 149, Issue 2
    • DOI: 10.1006/jssc.1999.8534

    Clathrates of Group 14 with Alkali Metals: An Exploration
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    • Bobev, Svilen; Sevov, Slavi C.
    • Journal of Solid State Chemistry, Vol. 153, Issue 1
    • DOI: 10.1006/jssc.2000.8755

    Growth and thermoelectric properties of Ba8Ga16Ge30 clathrate crystals
    journal, August 2009


    Thermoelectric properties of p-type Ba8Ga16Ge30 type-I clathrate compounds prepared by the vertical Bridgman method
    journal, October 2017


    Clathrate thermoelectrics
    journal, October 2016

    • Dolyniuk, Juli-Anna; Owens-Baird, Bryan; Wang, Jian
    • Materials Science and Engineering: R: Reports, Vol. 108
    • DOI: 10.1016/j.mser.2016.08.001

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    Rationally Designing High-Performance Bulk Thermoelectric Materials
    journal, August 2016


    Yb 14 MnSb 11 :  New High Efficiency Thermoelectric Material for Power Generation
    journal, April 2006

    • Brown, Shawna R.; Kauzlarich, Susan M.; Gascoin, Franck
    • Chemistry of Materials, Vol. 18, Issue 7
    • DOI: 10.1021/cm060261t

    Crystal Structure, Band Structure, and Physical Properties of Ba 8 Cu 6 - x Ge 40+ x (0 ≤ x ≤ 0.7)
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    • DOI: 10.1021/cm803252r

    New bulk Materials for Thermoelectric Power Generation: Clathrates and Complex Antimonides
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    • Nolas, G. S.; Chakoumakos, B. C.; Mahieu, B.
    • Chemistry of Materials, Vol. 12, Issue 7
    • DOI: 10.1021/cm990686y

    Siting of Antimony Dopants and Gallium in Ba 8 Ga 16 Ge 30 Clathrates Grown from Gallium Flux
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    • Latturner, S. E.; Bryan, J. D.; Blake, N.
    • Inorganic Chemistry, Vol. 41, Issue 15
    • DOI: 10.1021/ic011286r

    Introducing a Magnetic Guest to a Tetrel-Free Clathrate: Synthesis, Structure, and Properties of Eu x Ba 8– x Cu 16 P 30 (0 ≤ x ≤ 1.5)
    journal, October 2011

    • Kovnir, Kirill; Stockert, Ulrike; Budnyk, Sergij
    • Inorganic Chemistry, Vol. 50, Issue 20
    • DOI: 10.1021/ic201474h

    Cationic Clathrate I Si 46- x P x Te y (6.6(1) ≤ y ≤ 7.5(1), x ≤ 2 y ): Crystal Structure, Homogeneity Range, and Physical Properties
    journal, April 2009

    • Zaikina, J. V.; Kovnir, K. A.; Burkhardt, U.
    • Inorganic Chemistry, Vol. 48, Issue 8
    • DOI: 10.1021/ic8023887

    Ordering of Vacancies in Type-I Tin Clathrate:  Superstructure of Rb 8 Sn 442
    journal, March 2005

    • Dubois, Franck; Fässler, Thomas F.
    • Journal of the American Chemical Society, Vol. 127, Issue 10
    • DOI: 10.1021/ja043500r

    Solid-Solutioned Homojunction Nanoplates with Disordered Lattice: A Promising Approach toward “Phonon Glass Electron Crystal” Thermoelectric Materials
    journal, April 2012

    • Xiao, Chong; Xu, Jie; Cao, Boxiao
    • Journal of the American Chemical Society, Vol. 134, Issue 18
    • DOI: 10.1021/ja3020204

    Ca 1– x RE x Ag 1– y Sb (RE = La, Ce, Pr, Nd, Sm; 0 ≤ x ≤1; 0 ≤ y ≤1): Interesting Structural Transformation and Enhanced High-Temperature Thermoelectric Performance
    journal, July 2013

    • Wang, Jian; Liu, Xiao-Cun; Xia, Sheng-Qing
    • Journal of the American Chemical Society, Vol. 135, Issue 32
    • DOI: 10.1021/ja403653m

    Clathrate Ba 8 Au 16 P 30 : The “Gold Standard” for Lattice Thermal Conductivity
    journal, August 2013

    • Fulmer, James; Lebedev, Oleg I.; Roddatis, Vladimir V.
    • Journal of the American Chemical Society, Vol. 135, Issue 33
    • DOI: 10.1021/ja4052679

    Elusive β-Zn 8 Sb 7 : A New Zinc Antimonide Thermoelectric
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    • Wang, Jian; Kovnir, Kirill
    • Journal of the American Chemical Society, Vol. 137, Issue 39
    • DOI: 10.1021/jacs.5b08214

    Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals
    journal, April 2014

    • Zhao, Li-Dong; Lo, Shih-Han; Zhang, Yongsheng
    • Nature, Vol. 508, Issue 7496, p. 373-377
    • DOI: 10.1038/nature13184

    Complex thermoelectric materials
    journal, February 2008

    • Snyder, G. Jeffrey; Toberer, Eric S.
    • Nature Materials, Vol. 7, Issue 2, p. 105-114
    • DOI: 10.1038/nmat2090

    Better thermoelectrics through glass-like crystals
    journal, November 2015

    • Beekman, Matt; Morelli, Donald T.; Nolas, George S.
    • Nature Materials, Vol. 14, Issue 12
    • DOI: 10.1038/nmat4461

    Effects of the order–disorder phase transition on the physical properties of A8Sn44□2 (A = Rb, Cs)
    journal, January 2008

    • Kaltzoglou, Andreas; Fässler, Thomas; Christensen, Mogens
    • Journal of Materials Chemistry, Vol. 18, Issue 46
    • DOI: 10.1039/b810783a

    Thermoelectric properties of Sr3GaSb3 – a chain-forming Zintl compound
    journal, January 2012

    • Zevalkink, Alex; Zeier, Wolfgang G.; Pomrehn, Gregory
    • Energy & Environmental Science, Vol. 5, Issue 10
    • DOI: 10.1039/c2ee22378c

    Thermoelectric properties of Zn-doped Ca3AlSb3
    journal, January 2012

    • Zeier, Wolfgang G.; Zevalkink, Alex; Schechtel, Eugen
    • Journal of Materials Chemistry, Vol. 22, Issue 19
    • DOI: 10.1039/c2jm31324c

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    • Wood, C.; Zoltan, D.; Stapfer, G.
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    • DOI: 10.1063/1.1138213

    Thermoelectric properties of a clathrate compound Ba8Cu16P30
    journal, April 2003

    • Huo, Dexuan; Sasakawa, Tetsuya; Muro, Yuji
    • Applied Physics Letters, Vol. 82, Issue 16
    • DOI: 10.1063/1.1568819

    High temperature thermoelectric transport properties of p-type Ba8Ga16AlxGe30−x type-I clathrates with high performance
    journal, April 2008

    • Deng, Shukang; Tang, Xinfeng; Li, Peng
    • Journal of Applied Physics, Vol. 103, Issue 7
    • DOI: 10.1063/1.2902504

    High thermoelectric efficiency in lanthanum doped Yb14MnSb11
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