Self-Assembly of Two-Dimensional Perovskite Nanosheet Building Blocks into Ordered Ruddlesden–Popper Perovskite Phase

Liu, Yong; Siron, Martin; Lu, Dylan; Yang, Jingjing; dos Reis, Roberto; Cui, Fan; Gao, Mengyu; Lai, Minliang; Lin, Jia; Kong, Qiao; Lei, Teng; Kang, Joohoon; Jin, Jianbo; Ciston, Jim; Yang, Peidong

doi:10.1021/jacs.9b06889

Title: Self-Assembly of Two-Dimensional Perovskite Nanosheet Building Blocks into Ordered Ruddlesden–Popper Perovskite Phase

Journal Article · Tue Aug 06 00:00:00 EDT 2019 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.9b06889· OSTI ID:1599805

^[1]; Siron, Martin ^[1]; Lu, Dylan ^[1];

^[2];

^[3]; Cui, Fan ^[1]; Gao, Mengyu ^[1]; Lai, Minliang ^[1]; Lin, Jia ^[1]; Kong, Qiao ^[1];

^[1];

^[4]; Jin, Jianbo ^[1]; Ciston, Jim ^[3];

^[5]

Univ. of California, Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Inst. for Basic Science (IBS), Seoul (Korea); Yonsei Univ., Seoul (Korea); Kavli Energy NanoScience Inst., Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoScience Inst., Berkeley, CA (United States)

The self-assembly of nanoparticles, a process whereby nanocrystal building blocks organize into even more ordered superstructures, is of great interest to nanoscience. In this work, we report the layer-by-layer assembly of 2D perovskite nanosheet building blocks. Structural analysis reveals that the assembled superlattice nanocrystals match with the layered Ruddlesden-Popper perovskite phase. This assembly proves reversible, as these superlattice nanocrystals can be reversibly exfoliated back into their building blocks via sonication. This study demonstrates the opportunity to further understand and exploit thermodynamics to increase order in a system of nanoparticles and to study emergent optical properties of a superlattice from 2D, weakly attracted, perovskite building blocks.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1599805

Journal Information:: Journal of the American Chemical Society, Vol. 141, Issue 33; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 42 works

Citation information provided by
Web of Science

References (32)

Perovskite light-emitting diodes based on solution-processed self-organized multiple quantum wells Wang, Nana; Cheng, Lu; Ge, Rui Nature Photonics, Vol. 10, Issue 11 https://doi.org/10.1038/nphoton.2016.185	journal	September 2016
Quantum dot-induced phase stabilization of -CsPbI3 perovskite for high-efficiency photovoltaics Swarnkar, A.; Marshall, A. R.; Sanehira, E. M. Science, Vol. 354, Issue 6308 https://doi.org/10.1126/science.aag2700	journal	October 2016
Dimensional tailoring of hybrid perovskites for photovoltaics Grancini, Giulia; Nazeeruddin, Mohammad Khaja Nature Reviews Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41578-018-0065-0	journal	November 2018
Ultrathin Two-Dimensional Organic-Inorganic Hybrid Perovskite Nanosheets with Bright, Tunable Photoluminescence and High Stability Yang, Shuang; Niu, Wenxin; Wang, An-Liang Angewandte Chemie International Edition, Vol. 56, Issue 15 https://doi.org/10.1002/anie.201701134	journal	March 2017
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals Akkerman, Quinten A.; Rainò, Gabriele; Kovalenko, Maksym V. Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0018-4	journal	February 2018
Highly Luminescent Colloidal Nanoplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies Bekenstein, Yehonadav; Koscher, Brent A.; Eaton, Samuel W. Journal of the American Chemical Society, Vol. 137, Issue 51 https://doi.org/10.1021/jacs.5b11199	journal	December 2015
Superfluorescence from lead halide perovskite quantum dot superlattices Rainò, Gabriele; Becker, Michael A.; Bodnarchuk, Maryna I. Nature, Vol. 563, Issue 7733 https://doi.org/10.1038/s41586-018-0683-0	journal	November 2018
Benzoyl Halides as Alternative Precursors for the Colloidal Synthesis of Lead-Based Halide Perovskite Nanocrystals Imran, Muhammad; Caligiuri, Vincenzo; Wang, Mengjiao Journal of the American Chemical Society, Vol. 140, Issue 7 https://doi.org/10.1021/jacs.7b13477	journal	January 2018
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I. Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/nl5048779	journal	February 2015
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires Zhang, Dandan; Eaton, Samuel W.; Yu, Yi Journal of the American Chemical Society, Vol. 137, Issue 29 https://doi.org/10.1021/jacs.5b05404	journal	July 2015
Ultrathin Colloidal Cesium Lead Halide Perovskite Nanowires Zhang, Dandan; Yu, Yi; Bekenstein, Yehonadav Journal of the American Chemical Society, Vol. 138, Issue 40 https://doi.org/10.1021/jacs.6b08373	journal	September 2016
Colloidal Synthesis of Quantum Confined Single Crystal CsPbBr ₃ Nanosheets with Lateral Size Control up to the Micrometer Range Shamsi, Javad; Dang, Zhiya; Bianchini, Paolo Journal of the American Chemical Society, Vol. 138, Issue 23 https://doi.org/10.1021/jacs.6b03166	journal	June 2016
Atomically thin two-dimensional organic-inorganic hybrid perovskites Dou, L.; Wong, A. B.; Yu, Y. Science, Vol. 349, Issue 6255 https://doi.org/10.1126/science.aac7660	journal	September 2015
Growth and Anion Exchange Conversion of CH ₃ NH ₃ PbX ₃ Nanorod Arrays for Light-Emitting Diodes Wong, Andrew Barnabas; Lai, Minliang; Eaton, Samuel Wilson Nano Letters, Vol. 15, Issue 8 https://doi.org/10.1021/acs.nanolett.5b02082	journal	July 2015
Spatially resolved multicolor CsPbX ₃ nanowire heterojunctions via anion exchange Dou, Letian; Lai, Minliang; Kley, Christopher S. Proceedings of the National Academy of Sciences, Vol. 114, Issue 28 https://doi.org/10.1073/pnas.1703860114	journal	June 2017
Phase-transition–induced p-n junction in single halide perovskite nanowire Kong, Qiao; Lee, Woochul; Lai, Minliang Proceedings of the National Academy of Sciences, Vol. 115, Issue 36 https://doi.org/10.1073/pnas.1806515115	journal	August 2018
Intrinsic anion diffusivity in lead halide perovskites is facilitated by a soft lattice Lai, Minliang; Obliger, Amael; Lu, Dylan Proceedings of the National Academy of Sciences, Vol. 115, Issue 47 https://doi.org/10.1073/pnas.1812718115	journal	November 2018
Properties and emerging applications of self-assembled structures made from inorganic nanoparticles Nie, Zhihong; Petukhova, Alla; Kumacheva, Eugenia Nature Nanotechnology, Vol. 5, Issue 1 https://doi.org/10.1038/nnano.2009.453	journal	December 2009
Superstructures generated from truncated tetrahedral quantum dots Nagaoka, Yasutaka; Tan, Rui; Li, Ruipeng Nature, Vol. 561, Issue 7723 https://doi.org/10.1038/s41586-018-0512-5	journal	September 2018
Binary nanocrystal superlattice membranes self-assembled at the liquid–air interface Dong, Angang; Chen, Jun; Vora, Patrick M. Nature, Vol. 466, Issue 7305 https://doi.org/10.1038/nature09188	journal	July 2010
Monolayer atomic crystal molecular superlattices Wang, Chen; He, Qiyuan; Halim, Udayabagya Nature, Vol. 555, Issue 7695 https://doi.org/10.1038/nature25774	journal	March 2018
Cross-sectional imaging of individual layers and buried interfaces of graphene-based heterostructures and superlattices Haigh, S. J.; Gholinia, A.; Jalil, R. Nature Materials, Vol. 11, Issue 9 https://doi.org/10.1038/nmat3386	journal	July 2012
Vertically stacked multi-heterostructures of layered materials for logic transistors and complementary inverters Yu, Woo Jong; Li, Zheng; Zhou, Hailong Nature Materials, Vol. 12, Issue 3 https://doi.org/10.1038/nmat3518	journal	December 2012
Two-Dimensional DNA-Programmable Assembly of Nanoparticles at Liquid Interfaces Srivastava, Sunita; Nykypanchuk, Dmytro; Fukuto, Masafumi Journal of the American Chemical Society, Vol. 136, Issue 23 https://doi.org/10.1021/ja501749b	journal	May 2014
Atomically thin p–n junctions with van der Waals heterointerfaces Lee, Chul-Ho; Lee, Gwan-Hyoung; van der Zande, Arend M. Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.150	journal	August 2014
In situ study of the formation mechanism of two-dimensional superlattices from PbSe nanocrystals Geuchies, Jaco J.; van Overbeek, Carlo; Evers, Wiel H. Nature Materials, Vol. 15, Issue 12 https://doi.org/10.1038/nmat4746	journal	September 2016
Kinetics of the self-assembly of nanocrystal superlattices measured by real-time in situ X-ray scattering Weidman, Mark C.; Smilgies, Detlef-M.; Tisdale, William A. Nature Materials, Vol. 15, Issue 7 https://doi.org/10.1038/nmat4600	journal	March 2016
Conducting tin halides with a layered organic-based perovskite structure Mitzi, D. B.; Feild, C. A.; Harrison, W. T. A. Nature, Vol. 369, Issue 6480, p. 467-469 https://doi.org/10.1038/369467a0	journal	June 1994
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe Nature, Vol. 536, Issue 7616 https://doi.org/10.1038/nature18306	journal	July 2016
Perovskite energy funnels for efficient light-emitting diodes Yuan, Mingjian; Quan, Li Na; Comin, Riccardo Nature Nanotechnology, Vol. 11, Issue 10 https://doi.org/10.1038/nnano.2016.110	journal	June 2016
Self-Assembly of Alkylammonium Chains on Montmorillonite: Effect of Chain Length, Head Group Structure, and Cation Exchange Capacity Heinz, Hendrik; Vaia, R. A.; Krishnamoorti, R. Chemistry of Materials, Vol. 19, Issue 1 https://doi.org/10.1021/cm062019s	journal	January 2007
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016