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Title: Patterning of graphene oxide with optoelectronic tweezers

Abstract

Optoelectronic tweezers (OET) offer a means for parallel trapping and dynamic manipulation of micro-scale particles using low-intensity light. Such capabilities can facilitate the formation of bulk materials with a precisely tailored microstructure. Here, we report the use of OET to vertically align, trap, and reposition sheets of graphene oxide (GO) in liquids, paving the way for textured and patterned graphene macroassemblies that could offer superior performance for applications in energy storage, catalysis, and electronic devices. Trapping can be achieved with low-power light from inexpensive digital projectors and diode lasers, making it simple for users to create and apply patterns while avoiding undesirable photothermal heating effects. To give users a quantitative idea of trap stiffness, we also present a theoretical framework for predicting the maximum achievable speed of a GO platelet in an OET trap.

Authors:
 [1];  [1];  [2];  [1];  [3]
  1. University of Washington
  2. UNIVERSITY OF WASHINGTON
  3. UNIVERSITY OF WASHINGTON (MAIN CAMPUS)
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1598847
Report Number(s):
PNNL-SA-138997
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 113; Journal Issue: 3
Country of Publication:
United States
Language:
English

Citation Formats

Lim, Matthew B., Felsted, Robert G., Zhou, Xuezhe, Smith, Bennett E., and Pauzauskie, Peter. Patterning of graphene oxide with optoelectronic tweezers. United States: N. p., 2018. Web. doi:10.1063/1.5025225.
Lim, Matthew B., Felsted, Robert G., Zhou, Xuezhe, Smith, Bennett E., & Pauzauskie, Peter. Patterning of graphene oxide with optoelectronic tweezers. United States. https://doi.org/10.1063/1.5025225
Lim, Matthew B., Felsted, Robert G., Zhou, Xuezhe, Smith, Bennett E., and Pauzauskie, Peter. Mon . "Patterning of graphene oxide with optoelectronic tweezers". United States. https://doi.org/10.1063/1.5025225.
@article{osti_1598847,
title = {Patterning of graphene oxide with optoelectronic tweezers},
author = {Lim, Matthew B. and Felsted, Robert G. and Zhou, Xuezhe and Smith, Bennett E. and Pauzauskie, Peter},
abstractNote = {Optoelectronic tweezers (OET) offer a means for parallel trapping and dynamic manipulation of micro-scale particles using low-intensity light. Such capabilities can facilitate the formation of bulk materials with a precisely tailored microstructure. Here, we report the use of OET to vertically align, trap, and reposition sheets of graphene oxide (GO) in liquids, paving the way for textured and patterned graphene macroassemblies that could offer superior performance for applications in energy storage, catalysis, and electronic devices. Trapping can be achieved with low-power light from inexpensive digital projectors and diode lasers, making it simple for users to create and apply patterns while avoiding undesirable photothermal heating effects. To give users a quantitative idea of trap stiffness, we also present a theoretical framework for predicting the maximum achievable speed of a GO platelet in an OET trap.},
doi = {10.1063/1.5025225},
url = {https://www.osti.gov/biblio/1598847}, journal = {Applied Physics Letters},
number = 3,
volume = 113,
place = {United States},
year = {2018},
month = {7}
}

Works referenced in this record:

Preparation of Graphitic Oxide
journal, March 1958


Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
journal, July 2010


Mechanically robust 3D graphene macroassembly with high surface area
journal, January 2012


High Surface Area, sp2-Cross-Linked Three-Dimensional Graphene Monoliths
journal, April 2011


Ultrafast sol–gel synthesis of graphene aerogel materials
journal, December 2015


Tunable Lyotropic Photonic Liquid Crystal Based on Graphene Oxide
journal, December 2013


Liquid crystals of aqueous, giant graphene oxide flakes
journal, January 2011


Massively parallel manipulation of single cells and microparticles using optical images
journal, July 2005


Dynamic manipulation and separation of individual semiconducting and metallic nanowires
journal, January 2008


In Situ Raman Spectroscopy of COOH-Functionalized SWCNTs Trapped with Optoelectronic Tweezers
journal, January 2012


Parallel trapping of multiwalled carbon nanotubes with optoelectronic tweezers
journal, September 2009


Operational Regimes and Physics Present in Optoelectronic Tweezers
journal, April 2008


Electro-optical switching of graphene oxide liquid crystals with an extremely large Kerr coefficient
journal, March 2014


Dielectrophoretic motion of oblate spheroidal particles. Measurements of motion of red blood cells using the Stokes method
journal, July 1998


Direct measurements of constrained Brownian motion of an isolated sphere between two walls
journal, September 2000


The use of stokeslets to describe the arbitrary translation of a disk near a plane wall
journal, March 1996


NanoPen: Dynamic, Low-Power, and Light-Actuated Patterning of Nanoparticles
journal, August 2009


Determination of the Local Chemical Structure of Graphene Oxide and Reduced Graphene Oxide
journal, August 2010


Extremum Principles for slow Viscous flow and the Approximate Calculation of drag
journal, January 1956


The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene
journal, February 2013


Synthesis of Graphene Aerogel with High Electrical Conductivity
journal, October 2010

  • Worsley, Marcus A.; Pauzauskie, Peter J.; Olson, Tammy Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14067-14069
  • https://doi.org/10.1021/ja1072299

Phototransistor-based optoelectronic tweezers for dynamic cell manipulation in cell culture media
journal, January 2010


Pearl Chain Formation of Nanoparticles in Microelectrode Gaps by Dielectrophoresis
journal, December 2004


Simultaneous microscale optical manipulation, fabrication and immobilisation in aqueous media
journal, January 2012