Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols

Liu, Cheng; Luo, Wei; Liu, Junhua; Sun, Lei; Yang, Yue; Liu, Gui; Wang, Fang; Zhong, Wei; Guild, Curtis; Suib, Steven L.

doi:10.1007/s10562-017-2280-5

Title: Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols

Journal Article · Thu Jan 04 00:00:00 EST 2018 · Catalysis Letters

DOI:https://doi.org/10.1007/s10562-017-2280-5· OSTI ID:1597845

Liu, Cheng ^[1]; Luo, Wei ^[1]; Liu, Junhua ^[1]; Sun, Lei ^[1]; Yang, Yue ^[1]; Liu, Gui ^[1]; Wang, Fang ^[2]; Zhong, Wei ^[3]; Guild, Curtis ^[3]; Suib, Steven L. ^[3]

Nanjing Normal Univ. (China). College of Chemistry and Materials Science
Nanjing Tech Univ. (China). College of Chemistry and Molecular Engineering
Univ. of Connecticut, Storrs, CT (United States)

Four micro (nano)-sized mesoporous ferric hydroxyphosphates (FHP) are synthesized by a reverse microemulsion-solvothermal method, and then are used as supports to prepare supported Pt catalysts. The mean particle diameter of Pt nanoparticles (NPs) was 4.5–4.6 nm. When the four different Pt/FHP catalysts were used into the hydrogenation of α,β-unsaturated aldehydes (ketones) to their corresponding unsaturated alcohols, Pt/FHP (c) catalyst showed better catalytic performance than the other three partners. Under the optimal experimental conditions, several tested α,β-unsaturated aldehydes could be effectively transformed into corresponding unsaturated alcohols over Pt/FHP (c) catalyst. The catalyst could be recycled and reused several times without activity loss. We propose the stronger interaction between the Pt NPs and ferric ions of the FHP (c) are responsible for its good catalytic performance, and this stronger interaction should be rooted in its enhanced Lewis acid strength.

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Research Organization:: Univ. of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: FG02-86ER-13622

OSTI ID:: 1597845

Journal Information:: Catalysis Letters, Vol. 148, Issue 2; ISSN 1011-372X

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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References (30)

Preparation of Mesoporous Nano-Hydroxyapatite Using a Surfactant Template Method for Protein Delivery Wu, Xiaodong; Song, Xiaofeng; Li, Dongsong Journal of Bionic Engineering, Vol. 9, Issue 2 https://doi.org/10.1016/S1672-6529(11)60105-4	journal	June 2012
Strong Metal–Support Interactions between Gold Nanoparticles and Nonoxides Tang, Hailian; Wei, Jiake; Liu, Fei Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b11306	journal	December 2015
Selective Hydrogenation of α,β-Unsaturated Aldehydes Catalyzed by Amine-Capped Platinum-Cobalt Nanocrystals Wu, Binghui; Huang, Huaqi; Yang, Jing Angewandte Chemie International Edition, Vol. 51, Issue 14 https://doi.org/10.1002/anie.201108593	journal	February 2012
Chemoselective Reduction of Complexα,β-Unsaturated Ketones to Allylic Alcohols over Ir-Metal Particles onβ Zeolites De bruyn, Mario; Coman, Simona; Bota, Roxana Angewandte Chemie International Edition, Vol. 42, Issue 43 https://doi.org/10.1002/anie.200352275	journal	November 2003
The Reduction of Mg–Fe–O and Mg–Fe–Al–O Complex Oxides Studied by Temperature-Programmed Reduction Combined with in Situ Mössbauer Spectroscopy Ge, Xin; Li, Mingshi; Shen, Jianyi Journal of Solid State Chemistry, Vol. 161, Issue 1 https://doi.org/10.1006/jssc.2001.9264	journal	October 2001
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Provisional) Sing, K. S. W. Pure and Applied Chemistry, Vol. 54, Issue 11 https://doi.org/10.1351/pac198254112201	journal	January 1982
Liquid-phase hydrogenation of acetophenone over silica-supported Ni, Co and Cu catalysts: Influence of metal and solvent Trasarti, A. F.; Bertero, N. M.; Apesteguía, C. R. Applied Catalysis A: General, Vol. 475 https://doi.org/10.1016/j.apcata.2014.01.038	journal	April 2014
Hydrogen production by partial oxidation of methanol over bimetallic Au–Ru/Fe2O3 catalysts Chang, Feg-Wen; Roselin, L. Selva; Ou, Ti-Cheng Applied Catalysis A: General, Vol. 334, Issue 1-2 https://doi.org/10.1016/j.apcata.2007.10.003	journal	January 2008
Direct Conversion of Bio-ethanol to Isobutene on Nanosized Zn _x Zr _y O _z Mixed Oxides with Balanced Acid–Base Sites Sun, Junming; Zhu, Kake; Gao, Feng Journal of the American Chemical Society, Vol. 133, Issue 29 https://doi.org/10.1021/ja204235v	journal	July 2011
States of Pt in Pt/C catalyst precursors after impregnation, drying and reduction steps de Miguel, S. R.; Scelza, O. A.; Román-Martı́nez, M. C. Applied Catalysis A: General, Vol. 170, Issue 1 https://doi.org/10.1016/S0926-860X(98)00029-5	journal	May 1998
Biphasic Hydrogenation of α,β-unsaturated Aldehydes with Hydrosoluble Rhodium and Ruthenium Complexes Melean, Luis G.; Rodriguez, Mariandry; González, Angel Catalysis Letters, Vol. 141, Issue 5 https://doi.org/10.1007/s10562-011-0560-z	journal	February 2011
Hydrogenation of α,β-unsaturated aldehydes over Ru/Al2O3 catalysts Mercadante, L.; Neri, G.; Milone, C. Journal of Molecular Catalysis A: Chemical, Vol. 105, Issue 3 https://doi.org/10.1016/1381-1169(96)80001-X	journal	February 1996
Polyaniline-derived Non-Precious Catalyst for the Polymer Electrolyte Fuel Cell Cathode Wu, Gang; Chen, Zhongwei; Artyushkova, Kateryna ECS Transactions, Vol. 16, Issue 2, p. 159-170 https://doi.org/10.1149/1.2981852	journal	January 2008
Nano-sized mesoporous sodium iron hydroxyphosphate supported gold: an effective catalyst for the oxidation of sulfides Liu, Junhua; Liu, Gui; Liu, Cheng Catalysis Science & Technology, Vol. 6, Issue 7 https://doi.org/10.1039/C5CY02004B	journal	January 2016
Comparative study on stability and coke deposition over supported Rh and FePO4 catalysts for oxy-bromination of methane Lin, Ronghe; Ding, Yunjie; Wang, Runqin Journal of Energy Chemistry, Vol. 23, Issue 1 https://doi.org/10.1016/S2095-4956(14)60114-5	journal	January 2014
Hydrodeoxygenation of anisole as bio-oil model compound over supported Ni and Co catalysts: Effect of metal and support properties Sankaranarayanan, Thangaraju M.; Berenguer, Antonio; Ochoa-Hernández, Cristina Catalysis Today, Vol. 243 https://doi.org/10.1016/j.cattod.2014.09.004	journal	April 2015
Reactions of diazomethane derivatives with platinum(II): a facile method for platinum ylide preparation Hanks, T. W.; Ekeland, R. A.; Emerson, K. Organometallics, Vol. 6, Issue 1 https://doi.org/10.1021/om00144a007	journal	January 1987
Effects of Ce addition on the Pt-Sn/γ-Al2O3 catalyst for propane dehydrogenation to propylene Yu, Changlin; Ge, Qingjie; Xu, Hengyong Applied Catalysis A: General, Vol. 315 https://doi.org/10.1016/j.apcata.2006.08.038	journal	November 2006
Intramolecular selective hydrogenation of cinnamaldehyde over CeO2–ZrO2-supported Pt catalysts Bhogeswararao, S.; Srinivas, D. Journal of Catalysis, Vol. 285, Issue 1 https://doi.org/10.1016/j.jcat.2011.09.006	journal	January 2012
Spectroscopic study of the reaction of aqueous Cr(VI) with Fe3O4 (111) surfaces Kendelewicz, T.; Liu, P.; Doyle, C. S. Surface Science, Vol. 469, Issue 2-3 https://doi.org/10.1016/S0039-6028(00)00808-6	journal	December 2000
Doping effects of B in ZrO2 on structural and catalytic properties of Ru/B-ZrO2 catalysts for benzene partial hydrogenation Zhou, Gongbing; Pei, Yan; Jiang, Zheng Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.12.022	journal	March 2014
Solvent effect in the liquid-phase hydrogenation of acetophenone over Ni/SiO2: A comprehensive study of the phenomenon Bertero, Nicolás M.; Trasarti, Andrés F.; Apesteguía, Carlos R. Applied Catalysis A: General, Vol. 394, Issue 1-2 https://doi.org/10.1016/j.apcata.2011.01.003	journal	February 2011
Ga and In promoters in bimetallic Pt based catalysts to improve the performance in the selective hydrogenation of citral Stassi, Julieta P.; Zgolicz, Patricia D.; Rodríguez, Virginia I. Applied Catalysis A: General, Vol. 497 https://doi.org/10.1016/j.apcata.2015.01.046	journal	May 2015
Comparative Study on the Formation and Reduction of Bulk and Al ₂ O ₃ -Supported Cobalt Oxides by H ₂ -TPR Technique Ji, Yuguo; Zhao, Zhen; Duan, Aijun The Journal of Physical Chemistry C, Vol. 113, Issue 17 https://doi.org/10.1021/jp8107057	journal	April 2009
Formation of different promoted metallic phases in PtFe and PtSn catalysts supported on carbonaceous materials used for selective hydrogenation Stassi, Julieta P.; Zgolicz, Patricia D.; de Miguel, Sergio R. Journal of Catalysis, Vol. 306 https://doi.org/10.1016/j.jcat.2013.05.029	journal	October 2013
Selective hydrogenation of cinnamaldehyde over Pt-supported multi-walled carbon nanotubes: Insights into the tube-size effects Liu, Zhao-Tie; Wang, Chun-Xia; Liu, Zhong-Wen Applied Catalysis A: General, Vol. 344, Issue 1-2 https://doi.org/10.1016/j.apcata.2008.04.005	journal	July 2008
Selective hydrogenation of cinnamaldehyde to cinnamyl alcohol over mesoporous carbon supported Fe and Zn promoted Pt catalyst Mahata, Nagendranath; Gonçalves, Filomena; Pereira, Manuel Fernando R. Applied Catalysis A: General, Vol. 339, Issue 2 https://doi.org/10.1016/j.apcata.2008.01.023	journal	May 2008
Selective hydrogenation of cinnamaldehyde on nickel nanoparticles supported on titania: role of catalyst preparation methods Prakash, Murthiyamma Gengatharan; Mahalakshmy, Rajaram; Krishnamurthy, Konda Ramaswamy Catalysis Science & Technology, Vol. 5, Issue 6 https://doi.org/10.1039/C4CY01379D	journal	January 2015
The reduction behavior of supported iron catalysts in hydrogen or carbon monoxide atmospheres Kock, A. Journal of Catalysis, Vol. 96, Issue 1 https://doi.org/10.1016/0021-9517(85)90379-3	journal	November 1985
Liquid phase hydrogenation of α,β-unsaturated aldehydes over gold supported on iron oxides Lenz, Jennifer; Campo, Betiana C.; Alvarez, Mariana Journal of Catalysis, Vol. 267, Issue 1 https://doi.org/10.1016/j.jcat.2009.07.012	journal	October 2009

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
α
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Ferric hydroxyphosphates
Lewis acid
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Title: Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols

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