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Title: The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Post-Modification

Abstract

The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.

Authors:
; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1595952
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 142; Journal Issue: 1
Country of Publication:
United States
Language:
English

Citation Formats

Kim, In Soo, Ahn, Sol, Vermeulen, Nicolaas, Webber, Thomas, Gallington, Leighanne C., Chapman, Karena W., Penn, R. Lee, Hupp, Joseph T., Farha, Omar K., Notestein, Justin M., and Martinson, Alex B. F. The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Post-Modification. United States: N. p., 2020. Web. doi:10.1021/jacs.9b10034.
Kim, In Soo, Ahn, Sol, Vermeulen, Nicolaas, Webber, Thomas, Gallington, Leighanne C., Chapman, Karena W., Penn, R. Lee, Hupp, Joseph T., Farha, Omar K., Notestein, Justin M., & Martinson, Alex B. F. The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Post-Modification. United States. doi:10.1021/jacs.9b10034.
Kim, In Soo, Ahn, Sol, Vermeulen, Nicolaas, Webber, Thomas, Gallington, Leighanne C., Chapman, Karena W., Penn, R. Lee, Hupp, Joseph T., Farha, Omar K., Notestein, Justin M., and Martinson, Alex B. F. Wed . "The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Post-Modification". United States. doi:10.1021/jacs.9b10034.
@article{osti_1595952,
title = {The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Post-Modification},
author = {Kim, In Soo and Ahn, Sol and Vermeulen, Nicolaas and Webber, Thomas and Gallington, Leighanne C. and Chapman, Karena W. and Penn, R. Lee and Hupp, Joseph T. and Farha, Omar K. and Notestein, Justin M. and Martinson, Alex B. F.},
abstractNote = {The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.},
doi = {10.1021/jacs.9b10034},
journal = {Journal of the American Chemical Society},
number = 1,
volume = 142,
place = {United States},
year = {2020},
month = {1}
}