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Title: Bivalence Mn 5O 8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage

Abstract

Aqueous electrochemical energy storage devices have attracted significant attention owing to their high safety, low cost and environmental friendliness. However, their applications have been limited by a narrow potential window (~1.23 V), beyond which the hydrogen and oxygen evolution reactions occur. Here we report the formation of layered Mn 5O 8 pseudocapacitor electrode material with a well-ordered hydroxylated interphase. A symmetric full cell using such electrodes demonstrates a stable potential window of 3.0 V in an aqueous electrolyte, as well as high energy and power performance, nearly 100% coulombic efficiency and 85% energy efficiency after 25,000 charge–discharge cycles. The interplay between hydroxylated interphase on the surface and the unique bivalence structure of Mn 5O 8 suppresses the gas evolution reactions, offers a two-electron charge transfer via Mn 2+/Mn 4+ redox couple, and provides facile pathway for Na-ion transport via intra-/inter-layer defects of Mn 5O 8.

Authors:
 [1];  [1];  [2];  [3];  [2]; ORCiD logo [3];  [4]; ORCiD logo [5]; ORCiD logo [1]
  1. Univ. of New Hampshire, Durham, NH (United States)
  2. Univ. of Pittsburgh, PA (United States)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  5. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Univ. of New Hampshire, Durham, NH (United States); Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1594578
Alternate Identifier(s):
OSTI ID: 1328373; OSTI ID: 1337640; OSTI ID: 1377589
Report Number(s):
BNL-112679-2016-JA; BNL-113277-2016-JA
Journal ID: ISSN 2041-1723
Grant/Contract Number:  
SC0010286; SC00112704; AC02-05CH11231
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; Mn5O8; aqueous sodium-ion storage; Center for Functional Nanomaterials; 29 ENERGY PLANNING, POLICY, AND ECONOMY; Mn5O8

Citation Formats

Shan, Xiaoqiang, Charles, Daniel S., Lei, Yinkai, Qiao, Ruimin, Wang, Guofeng, Yang, Wanli, Feygenson, Mikhail, Su, Dong, and Teng, Xiaowei. Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage. United States: N. p., 2016. Web. doi:10.1038/ncomms13370.
Shan, Xiaoqiang, Charles, Daniel S., Lei, Yinkai, Qiao, Ruimin, Wang, Guofeng, Yang, Wanli, Feygenson, Mikhail, Su, Dong, & Teng, Xiaowei. Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage. United States. doi:10.1038/ncomms13370.
Shan, Xiaoqiang, Charles, Daniel S., Lei, Yinkai, Qiao, Ruimin, Wang, Guofeng, Yang, Wanli, Feygenson, Mikhail, Su, Dong, and Teng, Xiaowei. Tue . "Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage". United States. doi:10.1038/ncomms13370. https://www.osti.gov/servlets/purl/1594578.
@article{osti_1594578,
title = {Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage},
author = {Shan, Xiaoqiang and Charles, Daniel S. and Lei, Yinkai and Qiao, Ruimin and Wang, Guofeng and Yang, Wanli and Feygenson, Mikhail and Su, Dong and Teng, Xiaowei},
abstractNote = {Aqueous electrochemical energy storage devices have attracted significant attention owing to their high safety, low cost and environmental friendliness. However, their applications have been limited by a narrow potential window (~1.23 V), beyond which the hydrogen and oxygen evolution reactions occur. Here we report the formation of layered Mn5O8 pseudocapacitor electrode material with a well-ordered hydroxylated interphase. A symmetric full cell using such electrodes demonstrates a stable potential window of 3.0 V in an aqueous electrolyte, as well as high energy and power performance, nearly 100% coulombic efficiency and 85% energy efficiency after 25,000 charge–discharge cycles. The interplay between hydroxylated interphase on the surface and the unique bivalence structure of Mn5O8 suppresses the gas evolution reactions, offers a two-electron charge transfer via Mn2+/Mn4+ redox couple, and provides facile pathway for Na-ion transport via intra-/inter-layer defects of Mn5O8.},
doi = {10.1038/ncomms13370},
journal = {Nature Communications},
issn = {2041-1723},
number = 1,
volume = 7,
place = {United States},
year = {2016},
month = {11}
}

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