Understanding the Lithium Storage Mechanism of Ti3C2Tx MXene

Cheng, Renfei; Hu, Tao; Zhang, Hui; Wang, Chunmei; Hu, Minmin; Yang, Jinxing; Cui, Cong; Guang, Tianjia; Li, Changji; Shi, Chao; Hou, Pengxiang; Wang, Xiaohui

doi:10.1021/acs.jpcc.8b10790

Title: Understanding the Lithium Storage Mechanism of Ti₃C₂T_x MXene

Journal Article · Fri Dec 21 00:00:00 EST 2018 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.8b10790· OSTI ID:1577332

Cheng, Renfei ^[1]; Hu, Tao ^[2]; Zhang, Hui ^[3]; Wang, Chunmei ^[1]; Hu, Minmin ^[1]; Yang, Jinxing ^[1]; Cui, Cong ^[1]; Guang, Tianjia ^[1]; Li, Changji ^[4]; Shi, Chao ^[4]; Hou, Pengxiang ^[4];

^[4]

Chinese Academy of Sciences, Shenyang (China); Univ. of Science and Technology of China, Shenyang (China)
Chinese Academy of Sciences, Shenyang (China); Univ. of Chinese Academy of Sciences, Beijing (China); Suzhou Univ. of Science and Technology, Suzhou (China)
Monash Univ., Clayton, VIC (Australia)
Chinese Academy of Sciences, Shenyang (China)

MXenes, as an emerging family of conductive two-dimensional materials, hold promise for late-model electrode materials in Li-ion batteries. A primary challenge hindering the development of MXenes as electrode materials is that a complete understanding of the intrinsic storage mechanism underlying the charge/discharge behavior remains elusive. This article presents two key discoveries: first, the characteristics of the Ti₃C₂T_x structure can be modified systematically by calcination in various atmospheres, and second, these structural changes greatly affect Li-ion storage behavior, which reveals the mechanism for lithium storage in Ti₃C₂T_x MXene. Specifically, via ammonization, the interlayer spacing gets dilated and uniform, giving rise to only one redox couple. In stark contrast, there are two well-recognized redox couples corresponding to two interlayer spacings in pristine Ti₃C₂T_x MXene, in which Li-ion (de)intercalation occurs between interlayers in a sequential manner as evidenced by ex situ X-ray diffraction (XRD). Notably, the XRD diffraction peaks shift hardly in the whole range of charge/discharge voltage, indicating a zero-strain feature upon Li-ion (de)intercalation. Moreover, the diffusion-controlled contribution percentage to capacity inversely depends on the scan rate. The understanding suggests a new design principle of the MXene anode: reduced lateral size to shorten the diffusion path and dilated interlayer spacing.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1577332

Journal Information:: Journal of Physical Chemistry. C, Vol. 123, Issue 2; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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