Evolution of structure and dynamics of thermo-reversible nanoparticle gels—A combined XPCS and rheology study

Bahadur, Divya; Zhang, Qingteng; Dufresne, Eric M.; Grybos, Pawel; Kmon, Piotr; Leheny, Robert L.; Maj, Piotr; Narayanan, Suresh; Szczygiel, Robert; Swan, James W.; Sandy, Alec; Ramakrishnan, Subramanian

doi:10.1063/1.5111521

Title: Evolution of structure and dynamics of thermo-reversible nanoparticle gels—A combined XPCS and rheology study

Journal Article · Mon Sep 09 00:00:00 EDT 2019 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.5111521· OSTI ID:1574926

^[1];

^[2];

^[2]; Grybos, Pawel ^[3]; Kmon, Piotr ^[3]; Leheny, Robert L. ^[4]; Maj, Piotr ^[3]; Narayanan, Suresh ^[2]; Szczygiel, Robert ^[3]; Swan, James W. ^[5]; Sandy, Alec ^[2];

^[1]

Florida A & M Univ.-Florida State Univ. (FAMU-FSU), Tallahassee, FL (United States). College of Engineering
Argonne National Lab. (ANL), Argonne, IL (United States)
AGH Univ. of Science and Technology, Krakow (Poland)
Johns Hopkins Univ., Baltimore, MD (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

A combined X-ray photon correlation spectroscopy and rheology report is carried out to capture the evolution of structure, fast particle-scale dynamics, and moduli (elastic and loss) at early times of gel formation near the fluid-gel boundary of a suspension of nanoparticles. The system is made up of moderately concentrated suspensions of octadecyl silica in decalin (φ = 0.2) undergoing thermoreversible gelation. Near the gel boundary, the rate of gel formation is very sensitive to changes in attraction strength. Yet, we find that at different attraction strengths, the system goes through identical intermediate states of microscopic and macroscopic behavior, even though the absolute time needed to form a gel varies by orders of magnitude. We identify a single dimensionless time parameter, t_w/t_g, where t_w is the wait time following the quench and t_g is the rheologically determined gel time, that captures the similarity in gel formation at a range of attraction strengths. Following a temperature quench below the gel boundary, the system is initially fluidlike and forms diffusive clusters (similar to 8.5 times the particle diameter). After a lag-time, t_L, clusters aggregate to form a network like structure which is characterized by the onset of mechanical rigidity and a rapid growth in microscopic relaxation times. At t_g, the Baxter parameter obtained from adhesive hard sphere fits of the structure factor attains a constant value corresponding to the theoretical percolation boundary, thus demonstrating that gelation is percolation driven.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1574926

Alternate ID(s):: OSTI ID: 1560761

Journal Information:: Journal of Chemical Physics, Vol. 151, Issue 10; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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References (80)

Dynamical arrest in dense short-ranged attractive colloids Foffi, G.; Sciortino, F.; Zaccarelli, E. Journal of Physics: Condensed Matter, Vol. 16, Issue 38 https://doi.org/10.1088/0953-8984/16/38/002	journal	September 2004
Controlled growth of monodisperse silica spheres in the micron size range Stöber, Werner; Fink, Arthur; Bohn, Ernst Journal of Colloid and Interface Science, Vol. 26, Issue 1, p. 62-69 https://doi.org/10.1016/0021-9797(68)90272-5	journal	January 1968
A micro-mechanical study of coarsening and rheology of colloidal gels: Cage building, cage hopping, and Smoluchowski's ratchet Zia, Roseanna N.; Landrum, Benjamin J.; Russel, William B. Journal of Rheology, Vol. 58, Issue 5 https://doi.org/10.1122/1.4892115	journal	September 2014
Role of shear-induced dynamical heterogeneity in the nonlinear rheology of colloidal gels Hsiao, Lilian C.; Kang, Heekyoung; Ahn, Kyung Hyun Soft Matter, Vol. 10, Issue 46 https://doi.org/10.1039/c4sm01375a	journal	January 2014
Microstructural regimes of colloidal rod suspensions, gels, and glasses Solomon, Michael J.; Spicer, Patrick T. Soft Matter, Vol. 6, Issue 7 https://doi.org/10.1039/b918281k	journal	January 2010
Structure and dynamics of colloidal depletion gels: Coincidence of transitions and heterogeneity Dibble, Clare J.; Kogan, Michael; Solomon, Michael J. Physical Review E, Vol. 74, Issue 4 https://doi.org/10.1103/physreve.74.041403	journal	October 2006
Extended corresponding-states behavior for particles with variable range attractions Noro, Massimo G.; Frenkel, Daan The Journal of Chemical Physics, Vol. 113, Issue 8 https://doi.org/10.1063/1.1288684	journal	August 2000
Viscoelasticity of a colloidal gel during dynamical arrest: Evolution through the critical gel and comparison with a soft colloidal glass Negi, Ajay Singh; Redmon, Carissa G.; Ramakrishnan, Subramanian Journal of Rheology, Vol. 58, Issue 5 https://doi.org/10.1122/1.4883675	journal	September 2014
Preparation and characterization of spherical monodisperse silica dispersions in nonaqueous solvents Van Helden, A. K.; Jansen, J. W.; Vrij, A. Journal of Colloid and Interface Science, Vol. 81, Issue 2 https://doi.org/10.1016/0021-9797(81)90417-3	journal	June 1981
Multiple Glassy States in a Simple Model System Pham, K. N. Science, Vol. 296, Issue 5565 https://doi.org/10.1126/science.1068238	journal	April 2002
Characterizing nanoparticle interactions: Linking models to experiments Ramakrishnan, S.; Zukoski, C. F. The Journal of Chemical Physics, Vol. 113, Issue 3 https://doi.org/10.1063/1.481901	journal	July 2000
Aging in short-ranged attractive colloids: A numerical study Foffi, G.; Zaccarelli, E.; Buldyrev, S. The Journal of Chemical Physics, Vol. 120, Issue 18 https://doi.org/10.1063/1.1695326	journal	May 2004
Gelation as arrested phase separation in short-ranged attractive colloid–polymer mixtures Zaccarelli, Emanuela; Lu, Peter J.; Ciulla, Fabio Journal of Physics: Condensed Matter, Vol. 20, Issue 49 https://doi.org/10.1088/0953-8984/20/49/494242	journal	November 2008
Structural origins of dynamical heterogeneity in colloidal gels Dibble, Clare J.; Kogan, Michael; Solomon, Michael J. Physical Review E, Vol. 77, Issue 5 https://doi.org/10.1103/physreve.77.050401	journal	May 2008
Simulation Method of Colloidal Suspensions with Hydrodynamic Interactions: Fluid Particle Dynamics Tanaka, Hajime; Araki, Takeaki Physical Review Letters, Vol. 85, Issue 6 https://doi.org/10.1103/physrevlett.85.1338	journal	August 2000
Clustering and Mechanics in Dense Depletion and Thermal Gels ^† Ramakrishnan, S.; Gopalakrishnan, V.; Zukoski, C. F. Langmuir, Vol. 21, Issue 22 https://doi.org/10.1021/la050830w	journal	October 2005
The effect of attractions on the local structure of liquids and colloidal fluids Taffs, Jade; Malins, Alex; Williams, Stephen R. The Journal of Chemical Physics, Vol. 133, Issue 24 https://doi.org/10.1063/1.3516210	journal	December 2010
Quantifying the Reversible Association of Thermosensitive Nanoparticles Zaccone, Alessio; Crassous, Jerome J.; Béri, Benjamin Physical Review Letters, Vol. 107, Issue 16 https://doi.org/10.1103/physrevlett.107.168303	journal	October 2011
Gel Transition in Adhesive Hard-Sphere Colloidal Dispersions: The Role of Gravitational Effects Kim, Jung Min; Fang, Jun; Eberle, Aaron P. R. Physical Review Letters, Vol. 110, Issue 20 https://doi.org/10.1103/physrevlett.110.208302	journal	May 2013
Elasticity and clustering in concentrated depletion gels Ramakrishnan, S.; Chen, Y. -L.; Schweizer, K. S. Physical Review E, Vol. 70, Issue 4 https://doi.org/10.1103/physreve.70.040401	journal	October 2004
32k Channel Readout IC for Single Photon Counting Pixel Detectors with Pitch, Dead Time of 85 ns, Offset Spread and 2% rms Gain Spread Grybos, P.; Kmon, P.; Maj, P. IEEE Transactions on Nuclear Science, Vol. 63, Issue 2 https://doi.org/10.1109/tns.2016.2523260	journal	April 2016
Preparation of monodisperse silica particles: Control of size and mass fraction Bogush, G. H.; Tracy, M. A.; Zukoski, C. F. Journal of Non-Crystalline Solids, Vol. 104, Issue 1, p. 95-106 https://doi.org/10.1016/0022-3093(88)90187-1	journal	August 1988
On the solid–fluid interface of adhesive spheres Marr, D. W.; Gast, A. P. The Journal of Chemical Physics, Vol. 99, Issue 3 https://doi.org/10.1063/1.465265	journal	August 1993
Phase separation dynamics in colloid–polymer mixtures: the effect of interaction range Zhang, Isla; Royall, C. Patrick; Faers, Malcolm A. Soft Matter, Vol. 9, Issue 6 https://doi.org/10.1039/c2sm27119b	journal	January 2013
Length scale dependence of dynamical heterogeneity in a colloidal fractal gel Duri, A.; Cipelletti, L. Europhysics Letters (EPL), Vol. 76, Issue 5 https://doi.org/10.1209/epl/i2006-10357-4	journal	December 2006
Dynamic structure of thermoreversible colloidal gels of adhesive spheres Solomon, Michael J.; Varadan, Priya Physical Review E, Vol. 63, Issue 5 https://doi.org/10.1103/physreve.63.051402	journal	April 2001
Dynamical heterogeneities close to a colloidal gel Puertas, Antonio M.; Fuchs, Matthias; Cates, Michael E. The Journal of Chemical Physics, Vol. 121, Issue 6 https://doi.org/10.1063/1.1768936	journal	January 2004
Decay of density fluctuations in gels Martin, James E.; Wilcoxon, Jess; Odinek, Judy Physical Review A, Vol. 43, Issue 2 https://doi.org/10.1103/physreva.43.858	journal	January 1991
Structural and rheological evolution of silica nanoparticle gels Cao, X. J.; Cummins, H. Z.; Morris, J. F. Soft Matter, Vol. 6, Issue 21 https://doi.org/10.1039/c0sm00433b	journal	January 2010
Structural and microscopic relaxations in a colloidal glass Augusto de Melo Marques, Flavio; Angelini, Roberta; Zaccarelli, Emanuela Soft Matter, Vol. 11, Issue 3 https://doi.org/10.1039/c4sm02010c	journal	January 2015
Structure of colloidal gels at intermediate concentrations: the role of competing interactions Capellmann, Ronja F.; Valadez-Pérez, Néstor E.; Simon, Benedikt Soft Matter, Vol. 12, Issue 46 https://doi.org/10.1039/c6sm01822j	journal	January 2016
Gelation of particles with short-range attraction Lu, Peter J.; Zaccarelli, Emanuela; Ciulla, Fabio Nature, Vol. 453, Issue 7194 https://doi.org/10.1038/nature06931	journal	May 2008
Ultralow-angle dynamic light scattering with a charge coupled device camera based multispeckle, multitau correlator Cipelletti, Luca; Weitz, D. A. Review of Scientific Instruments, Vol. 70, Issue 8 https://doi.org/10.1063/1.1149894	journal	August 1999
Phase diagram of the adhesive hard sphere fluid Miller, Mark A.; Frenkel, Daan The Journal of Chemical Physics, Vol. 121, Issue 1 https://doi.org/10.1063/1.1758693	journal	January 2004
Critical exponents for the sol-gel transition Martin, James E.; Wilcoxon, Jess; Adolf, Douglas Physical Review A, Vol. 36, Issue 4 https://doi.org/10.1103/physreva.36.1803	journal	August 1987
Role of isostaticity and load-bearing microstructure in the elasticity of yielded colloidal gels Hsiao, L. C.; Newman, R. S.; Glotzer, S. C. Proceedings of the National Academy of Sciences, Vol. 109, Issue 40 https://doi.org/10.1073/pnas.1206742109	journal	September 2012
Intermittent dynamics and hyper-aging in dense colloidal gelsThis paper was originally presented as a poster at the Faraday Discussion 123 meeting. Bissig, Hugo; Romer, Sara; Cipelletti, Luca PhysChemComm, Vol. 6, Issue 5 https://doi.org/10.1039/b211806h	journal	March 2003
Hydrodynamic and interparticle potential effects on aggregation of colloidal particles Cao, X. J.; Cummins, H. Z.; Morris, J. F. Journal of Colloid and Interface Science, Vol. 368, Issue 1 https://doi.org/10.1016/j.jcis.2011.11.050	journal	February 2012
Interplay between Spinodal Decomposition and Glass Formation in Proteins Exhibiting Short-Range Attractions Cardinaux, Frédéric; Gibaud, Thomas; Stradner, Anna Physical Review Letters, Vol. 99, Issue 11 https://doi.org/10.1103/physrevlett.99.118301	journal	September 2007
Design and characterization of an undulator beamline optimized for small-angle coherent X-ray scattering at the Advanced Photon Source Sandy, A. R.; Lurio, L. B.; Mochrie, S. G. J. Journal of Synchrotron Radiation, Vol. 6, Issue 6 https://doi.org/10.1107/s0909049599009590	journal	November 1999
On the viscosity of adhesive hard sphere dispersions: Critical scaling and the role of rigid contacts Wang, Gang; Fiore, Andrew M.; Swan, James W. Journal of Rheology, Vol. 63, Issue 2 https://doi.org/10.1122/1.5063362	journal	March 2019
Gel formation and aging in weakly attractive nanocolloid suspensions at intermediate concentrations Guo, Hongyu; Ramakrishnan, S.; Harden, James L. The Journal of Chemical Physics, Vol. 135, Issue 15 https://doi.org/10.1063/1.3653380	journal	October 2011
Percolation behaviour of permeable and of adhesive spheres Chiew, Y. C.; Glandt, E. D. Journal of Physics A: Mathematical and General, Vol. 16, Issue 11 https://doi.org/10.1088/0305-4470/16/11/026	journal	August 1983
Connecting nanoscale motion and rheology of gel-forming colloidal suspensions Guo, Hongyu; Ramakrishnan, S.; Harden, James L. Physical Review E, Vol. 81, Issue 5 https://doi.org/10.1103/physreve.81.050401	journal	May 2010
Colloidal gelation with variable attraction energy Zaccone, Alessio; Crassous, Jérôme J.; Ballauff, Matthias The Journal of Chemical Physics, Vol. 138, Issue 10 https://doi.org/10.1063/1.4794695	journal	March 2013
Entropic barriers, activated hopping, and the glass transition in colloidal suspensions Schweizer, Kenneth S.; Saltzman, Erica J. The Journal of Chemical Physics, Vol. 119, Issue 2 https://doi.org/10.1063/1.1578632	journal	July 2003
Colloidal glasses and gels: The interplay of bonding and caging Zaccarelli, E.; Poon, W. C. K. Proceedings of the National Academy of Sciences, Vol. 106, Issue 36 https://doi.org/10.1073/pnas.0902294106	journal	August 2009
Noise on photon correlation data: I. Auto-correlation Schätzel, Klaus Quantum Optics: Journal of the European Optical Society Part B, Vol. 2, Issue 6 https://doi.org/10.1088/0954-8998/2/6/505	journal	December 1990
Linking self-assembly, rheology, and gel transition in attractive colloids Zaccone, A.; Winter, H. H.; Siebenbürger, M. Journal of Rheology, Vol. 58, Issue 5 https://doi.org/10.1122/1.4878838	journal	September 2014
Microstructure and Rheology of Thermoreversible Nanoparticle Gels Ramakrishnan, S.; Zukoski, C. F. Langmuir, Vol. 22, Issue 18 https://doi.org/10.1021/la060168j	journal	August 2006
Dynamical Arrest Transition in Nanoparticle Dispersions with Short-Range Interactions Eberle, Aaron P. R.; Wagner, Norman J.; Castañeda-Priego, Ramón Physical Review Letters, Vol. 106, Issue 10 https://doi.org/10.1103/physrevlett.106.105704	journal	March 2011
Higher-order glass-transition singularities in colloidal systems with attractive interactions Dawson, K.; Foffi, G.; Fuchs, M. Physical Review E, Vol. 63, Issue 1 https://doi.org/10.1103/physreve.63.011401	journal	December 2000
Viscoelastic properties of colloidal gels Rueb, C. J.; Zukoski, C. F. Journal of Rheology, Vol. 41, Issue 2 https://doi.org/10.1122/1.550812	journal	March 1997
Nonergodicity transitions in colloidal suspensions with attractive interactions Bergenholtz, J.; Fuchs, M. Physical Review E, Vol. 59, Issue 5 https://doi.org/10.1103/physreve.59.5706	journal	May 1999
Fast multi-tau real-time software correlator for dynamic light scattering Magatti, Davide; Ferri, Fabio Applied Optics, Vol. 40, Issue 24 https://doi.org/10.1364/ao.40.004011	journal	January 2001
Microscopic theory of gelation and elasticity in polymer–particle suspensions Chen, Yeng-Long; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 120, Issue 15 https://doi.org/10.1063/1.1683077	journal	April 2004
Arrested demixing opens route to bigels Varrato, F.; Di Michele, L.; Belushkin, M. Proceedings of the National Academy of Sciences, Vol. 109, Issue 47 https://doi.org/10.1073/pnas.1214971109	journal	November 2012
Dynamical arrest in adhesive hard-sphere dispersions driven by rigidity percolation Valadez-Pérez, Néstor E.; Liu, Yun; Eberle, Aaron P. R. Physical Review E, Vol. 88, Issue 6 https://doi.org/10.1103/physreve.88.060302	journal	December 2013
Direct observation of a local structural mechanism for dynamic arrest Patrick Royall, C.; Williams, Stephen R.; Ohtsuka, Takehiro Nature Materials, Vol. 7, Issue 7 https://doi.org/10.1038/nmat2219	journal	June 2008
Attractions in sterically stabilized silica dispersions Jansen, J. W.; de Kruif, C. G.; Vrij, A. Journal of Colloid and Interface Science, Vol. 114, Issue 2 https://doi.org/10.1016/0021-9797(86)90432-7	journal	December 1986
Absence of Scaling for the Intermediate Scattering Function of a Hard-Sphere Suspension: Static and Dynamic X-Ray Scattering from Concentrated Polystyrene Latex Spheres Lurio, L. B.; Lumma, D.; Sandy, A. R. Physical Review Letters, Vol. 84, Issue 4 https://doi.org/10.1103/physrevlett.84.785	journal	January 2000
Dynamical Arrest, Percolation, Gelation, and Glass Formation in Model Nanoparticle Dispersions with Thermoreversible Adhesive Interactions Eberle, Aaron P. R.; Castañeda-Priego, Ramón; Kim, Jung M. Langmuir, Vol. 28, Issue 3 https://doi.org/10.1021/la2035054	journal	January 2012
Submillisecond X-ray photon correlation spectroscopy from a pixel array detector with fast dual gating and no readout dead-time Zhang, Qingteng; Dufresne, Eric M.; Grybos, Pawel Journal of Synchrotron Radiation, Vol. 23, Issue 3 https://doi.org/10.1107/s1600577516005166	journal	April 2016
The rheology and microstructure of an aging thermoreversible colloidal gel Gordon, Melissa B.; Kloxin, Christopher J.; Wagner, Norman J. Journal of Rheology, Vol. 61, Issue 1 https://doi.org/10.1122/1.4966039	journal	January 2017
Phase Diagram of a Model Adhesive Hard-Sphere Dispersion Verduin, Henk; Dhont, Jan K. G. Journal of Colloid and Interface Science, Vol. 172, Issue 2 https://doi.org/10.1006/jcis.1995.1273	journal	June 1995
Dynamics of concentrated colloidal suspensions: diffusion, aggregation and gelation Romer, S.; Urban, C.; Bissig, H. Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 359, Issue 1782 https://doi.org/10.1098/rsta.2000.0812	journal	May 2001
Linear viscoelasticity of attractive colloidal dispersions Varga, Zsigmond; Swan, James W. Journal of Rheology, Vol. 59, Issue 5 https://doi.org/10.1122/1.4928951	journal	September 2015
The vibrational motions of particle gels Dawson, K.; Foffi, G.; Zaccarelli, E. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 183-185 https://doi.org/10.1016/s0927-7757(01)00528-3	journal	July 2001
Gel transitions in colloidal suspensions Bergenholtz, J.; Fuchs, M. Journal of Physics: Condensed Matter, Vol. 11, Issue 50 https://doi.org/10.1088/0953-8984/11/50/310	journal	December 1999
Attractions in sterically stabilized silica dispersions Jansen, J. W.; de Kruif, C. G.; Vrij, A. Journal of Colloid and Interface Science, Vol. 114, Issue 2 https://doi.org/10.1016/0021-9797(86)90434-0	journal	December 1986
Attractions in sterically stabilized silica dispersions Jansen, J. W.; de Kruif, C. G.; Vrij, A. Journal of Colloid and Interface Science, Vol. 114, Issue 2 https://doi.org/10.1016/0021-9797(86)90435-2	journal	December 1986
Attractions in sterically stabilized silica dispersions Jansen, J. W.; de Kruif, C. G.; Vrij, A. Journal of Colloid and Interface Science, Vol. 114, Issue 2 https://doi.org/10.1016/0021-9797(86)90433-9	journal	December 1986
How a liquid becomes a glass both on cooling and on heating Lu, Xinhui; Mochrie, S. G. J.; Narayanan, S. arXiv https://doi.org/10.48550/arxiv.0708.3663	text	January 2007
Gelation as arrested phase separation in short-ranged attractive colloid-polymer mixtures Zaccarelli, Emanuela; Lu, Peter J.; Ciulla, Fabio arXiv https://doi.org/10.48550/arxiv.0810.4239	text	January 2008
The effect of attractions on the local structure of liquids and colloidal fluids Taffs, Jade; Malins, Alex; Williams, Stephen R. arXiv https://doi.org/10.48550/arxiv.1101.1644	text	January 2011
Colloidal gelation with variable attraction energy Zaccone, Alessio; Crassous, Jerome J.; Ballauff, Matthias arXiv https://doi.org/10.48550/arxiv.1304.1410	text	January 2013
Extended corresponding-states behavior for particles with variable range attractions Noro, Massimo G.; Frenkel, Daan arXiv https://doi.org/10.48550/arxiv.cond-mat/0004033	text	January 2000
Aging in short-ranged attractive colloids: A numerical study Foffi, G.; Zaccarelli, E.; Buldyrev, S. arXiv https://doi.org/10.48550/arxiv.cond-mat/0311621	text	January 2003
Dynamical heterogeneities close to a colloidal gel Puertas, Antonio M.; Fuchs, Matthias; Cates, Michael E. arXiv https://doi.org/10.48550/arxiv.cond-mat/0412364	text	January 2004
Structure and dynamics of colloidal depletion gels: coincidence of transitions and heterogeneity Dibble, C. J.; Kogan, M.; Solomon, M. J. arXiv https://doi.org/10.48550/arxiv.cond-mat/0606127	text	January 2006

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