Secondary building units as the turning point in the development of the reticular chemistry of MOFs

Kalmutzki, Markus J.; Hanikel, Nikita; Yaghi, Omar M.

doi:10.1126/sciadv.aat9180

Title: Secondary building units as the turning point in the development of the reticular chemistry of MOFs

Journal Article · Fri Oct 05 00:00:00 EDT 2018 · Science Advances

DOI:https://doi.org/10.1126/sciadv.aat9180· OSTI ID:1571939

^[1]; Hanikel, Nikita ^[1];

^[2]

Univ. of California, Berkeley, CA (United States). Dept. of Chemistry, Kavli Energy NanoScience Inst., and Berkeley Global Science Inst.; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
Univ. of California, Berkeley, CA (United States). Dept. of Chemistry, Kavli Energy NanoScience Inst., and Berkeley Global Science Inst.; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division; King Abdulaziz City for Science and Technology, Riyadh (Saudi Arabia)

The secondary building unit (SBU) approach was a turning point in the discovery of permanently porous metal-organic frameworks (MOFs) and in launching the field of reticular chemistry. In contrast to the single-metal nodes known in coordination networks, the polynuclear nature of SBUs allows these structures to serve as rigid, directional, and stable building units in the design of robust crystalline materials with predetermined structures and properties. This concept has also enabled the development of MOFs with ultra-high porosity and structural complexity. The architectural, mechanical, and chemical stability of MOFs imparted by their SBUs also gives rise to unique framework chemistry. All of this chemistry –including ligand, linker, metal exchange, and metallation reactions, as well as precisely controlled formation of ordered vacancies– is carried out with full retention of the MOF structure, crystallinity, and porosity. The unique chemical nature of SBUs makes MOFs useful in many applications including gas and vapor adsorption, separation processes, and SBU-mediated catalysis. In essence, the SBU approach realizes a long-standing dream of scientists by bringing molecular chemistry (both organic and inorganic) to extended solid-state structures. This contribution highlights the importance of the SBUs in the development of MOFs and points to the tremendous potential still to be harnessed.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1571939

Journal Information:: Science Advances, Vol. 4, Issue 10; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 382 works

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