Exploratory studies into 3 d /4 f cluster formation with fully bridge-substituted calix[4]arenes
Abstract
Calix[4]arenes are extremely versatile ligands that are capable of supporting the formation of a wide variety of polymetallic clusters of paramagnetic metal ions. One can exert influence over cluster formation through alteration of the calix[4]arene framework and subsequent ‘expansion’ of the lower-rim polyphenolic binding site. The present contribution investigates cluster formation with calix[4]arenes substituted at all four methylene bridge positions with furan moieties. Finally, two known cluster types have been isolated with this ligand, the structures of which lend insight into factors that may ultimately preclude the formation of mixed-metal species.
- Authors:
-
- Heriot-Watt Univ., Edinburgh (United Kingdom). Inst. of Chemical Sciences
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Univ. of Edinburgh, (United Kingdom). EaStCHEM School of Chemistry
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1571103
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Supramolecular Chemistry
- Additional Journal Information:
- Journal Volume: 30; Journal Issue: 5-6; Journal ID: ISSN 1061-0278
- Publisher:
- Taylor & Francis
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Calixarenes; coordination chemistry; clusters; synthesis; crystallography
Citation Formats
Fong, Angela, McCormick, Laura, Teat, Simon J., Brechin, Euan K., and Dalgarno, Scott J. Exploratory studies into 3 d /4 f cluster formation with fully bridge-substituted calix[4]arenes. United States: N. p., 2018.
Web. doi:10.1080/10610278.2018.1430894.
Fong, Angela, McCormick, Laura, Teat, Simon J., Brechin, Euan K., & Dalgarno, Scott J. Exploratory studies into 3 d /4 f cluster formation with fully bridge-substituted calix[4]arenes. United States. https://doi.org/10.1080/10610278.2018.1430894
Fong, Angela, McCormick, Laura, Teat, Simon J., Brechin, Euan K., and Dalgarno, Scott J. 2018.
"Exploratory studies into 3 d /4 f cluster formation with fully bridge-substituted calix[4]arenes". United States. https://doi.org/10.1080/10610278.2018.1430894. https://www.osti.gov/servlets/purl/1571103.
@article{osti_1571103,
title = {Exploratory studies into 3 d /4 f cluster formation with fully bridge-substituted calix[4]arenes},
author = {Fong, Angela and McCormick, Laura and Teat, Simon J. and Brechin, Euan K. and Dalgarno, Scott J.},
abstractNote = {Calix[4]arenes are extremely versatile ligands that are capable of supporting the formation of a wide variety of polymetallic clusters of paramagnetic metal ions. One can exert influence over cluster formation through alteration of the calix[4]arene framework and subsequent ‘expansion’ of the lower-rim polyphenolic binding site. The present contribution investigates cluster formation with calix[4]arenes substituted at all four methylene bridge positions with furan moieties. Finally, two known cluster types have been isolated with this ligand, the structures of which lend insight into factors that may ultimately preclude the formation of mixed-metal species.},
doi = {10.1080/10610278.2018.1430894},
url = {https://www.osti.gov/biblio/1571103},
journal = {Supramolecular Chemistry},
issn = {1061-0278},
number = 5-6,
volume = 30,
place = {United States},
year = {Thu Feb 01 00:00:00 EST 2018},
month = {Thu Feb 01 00:00:00 EST 2018}
}
Web of Science
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Works referencing / citing this record:
Enantiomerization Barrier of all-cis C-Me-tetrahydroxy p-tert -butylcalix[4]arene and Atropisomeric Equilibrium of its Tetraacetoxy Derivatives: Enantiomerization Barrier of all-cis C-Me-tetrahydroxy p-tert -butylcalix[4]arene and Atropisomeric Equilibrium of its Tetraacetoxy Derivatives
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Optical and Vapor Sensing Properties of Calix[4]arene Langmuir-Blodgett Thin Films with Host–Guest Principles
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