Electrophoretic and potentiometric signatures of multistage CaCO3 nucleation

Prus, Marzena; Szymanek, Karolina; Mills, Jennifer; Lammers, Laura Nielsen; Piasecki, Wojciech; Kedra-Królik, Karolina; Zarzycki, Piotr

doi:10.1016/j.jcis.2019.03.002

Title: Electrophoretic and potentiometric signatures of multistage CaCO3 nucleation

Journal Article · Wed May 01 00:00:00 EDT 2019 · Journal of Colloid and Interface Science

DOI:https://doi.org/10.1016/j.jcis.2019.03.002· OSTI ID:1569471

Prus, Marzena ^[1]; Szymanek, Karolina ^[2];

^[3]; Lammers, Laura Nielsen ^[3]; Piasecki, Wojciech ^[2]; Kedra-Królik, Karolina ^[1];

^[4]

Polish Academy of Sciences (PAS), Warsaw (Poland). Inst. of Physical Chemistry
Józef Piłsudski Univ. of Physical Education, Warsaw (Poland). Dept. of Chemistry and Biochemistry
Univ. of California, Berkeley, CA (United States). Dept. of Environmental Science, Policy and Management
Polish Academy of Sciences (PAS), Warsaw (Poland). Inst. of Physical Chemistry; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Energy Geosciences Division

HYPOTHESIS:Calcium carbonate nucleation is often a complex and multistep process that is difficult to follow in situ. The time-resolved electrochemical and electrophoretic methods can provide a new insight into the nucleation pathway. EXPERIMENTS:Here, we used a combination of speciation calculations with time-resolved electrophoretic and potentiometric methods to monitor calcium carbonate precipitation from a slightly supersaturated solution. FINDINGS:After an initial mixing period of three minutes in which metastable CaCO₃ phases may have nucleated and subsequently dissolved due to locally-high supersaturations, bulk solution pH and Ca²⁺ concentrations stabilize before decreasing in tandem with the precipitation of a CaCO₃ phase. After an hour, the precipitate is dominated by calcite that grows at the expense of dissolving vaterite. The time-dependent electrokinetic potential shows analogous signatures of multistage nucleation process: initial rapid changes in ζ-potential are followed by much slower equilibration starting about one hour after reagents are mixed. The changes in ζ-potential, solution pH, saturation indexes, and particle morphology are consistent with vaterite to calcite transformation via dissolution of the former and recrystallization of the latter. These findings highlight the potential use of ζ-potential measurements for monitoring polymorphic transformations of carbonate phases in-situ.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1569471

Alternate ID(s):: OSTI ID: 1635998

Journal Information:: Journal of Colloid and Interface Science, Vol. 544, Issue C; ISSN 0021-9797

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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Data for: Electrophoretic and Potentiometric Signatures of Multistage CaCO3 Nucleation Zarzycki, Piotr https://doi.org/10.17632/378hc9p267.1 The current record is supplemented by this dataset	dataset	January 2019
Data for: Electrophoretic and Potentiometric Signatures of Multistage CaCO3 Nucleation Zarzycki, Piotr https://doi.org/10.17632/378hc9p267 The current record is supplemented by this dataset	dataset	January 2019

Title: Electrophoretic and potentiometric signatures of multistage CaCO3 nucleation

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