Metal phosphide catalysts and methods for making the same and uses thereof
Patent
·
OSTI ID:1568591
The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.
- Research Organization:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC36-08GO28308
- Assignee:
- Alliance for Sustainable Energy, LLC (Golden, CO)
- Patent Number(s):
- 10,350,583
- Application Number:
- 15/458,397
- OSTI ID:
- 1568591
- Country of Publication:
- United States
- Language:
- English
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