skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Structural analysis of the initial lithiation of NiO thin film electrodes

Abstract

Our results reveal that conversion reactions and structural changes in NiO thin film electrodes begin near the theoretical lithiation potential.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [1];  [3]; ORCiD logo [4];  [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [5]
  1. Department of Materials Science and Engineering; Northwestern University; Evanston; USA
  2. Chemical Sciences and Engineering Division; Argonne National Laboratory; Lemont; USA
  3. NUANCE Center; Northwestern University; Evanston; USA; Department of Mechanical Engineering
  4. X-ray Science Division; Argonne National Laboratory; Lemont; USA
  5. Department of Materials Science and Engineering; Northwestern University; Evanston; USA; Department of Physics and Astronomy, Northwestern University
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES); Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1566649
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Volume: 21; Journal Issue: 17; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
energy storage (including batteries and capacitors), charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Evmenenko, Guennadi, Fister, Timothy T., Castro, Fernando C., Chen, Xinqi, Lee, Byeongdu, Buchholz, D. Bruce, Dravid, Vinayak P., Fenter, Paul, and Bedzyk, Michael J. Structural analysis of the initial lithiation of NiO thin film electrodes. United States: N. p., 2019. Web. doi:10.1039/c9cp01527b.
Evmenenko, Guennadi, Fister, Timothy T., Castro, Fernando C., Chen, Xinqi, Lee, Byeongdu, Buchholz, D. Bruce, Dravid, Vinayak P., Fenter, Paul, & Bedzyk, Michael J. Structural analysis of the initial lithiation of NiO thin film electrodes. United States. https://doi.org/10.1039/c9cp01527b
Evmenenko, Guennadi, Fister, Timothy T., Castro, Fernando C., Chen, Xinqi, Lee, Byeongdu, Buchholz, D. Bruce, Dravid, Vinayak P., Fenter, Paul, and Bedzyk, Michael J. Tue . "Structural analysis of the initial lithiation of NiO thin film electrodes". United States. https://doi.org/10.1039/c9cp01527b.
@article{osti_1566649,
title = {Structural analysis of the initial lithiation of NiO thin film electrodes},
author = {Evmenenko, Guennadi and Fister, Timothy T. and Castro, Fernando C. and Chen, Xinqi and Lee, Byeongdu and Buchholz, D. Bruce and Dravid, Vinayak P. and Fenter, Paul and Bedzyk, Michael J.},
abstractNote = {Our results reveal that conversion reactions and structural changes in NiO thin film electrodes begin near the theoretical lithiation potential.},
doi = {10.1039/c9cp01527b},
url = {https://www.osti.gov/biblio/1566649}, journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
issn = {1463-9076},
number = 17,
volume = 21,
place = {United States},
year = {2019},
month = {1}
}

Works referenced in this record:

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004


Enhancing the performances of Li-ion batteries by carbon-coating: present and future
journal, January 2012


Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014


Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015


Surface and interface sciences of Li-ion batteries
journal, December 2017


Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000


Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011


Ultimate Limits to Intercalation Reactions for Lithium Batteries
journal, October 2014


A critical review-promises and barriers of conversion electrodes for Li-ion batteries
journal, April 2017


High-Capacity Anode Materials for Lithium-Ion Batteries: Choice of Elements and Structures for Active Particles
journal, October 2013


Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides
journal, January 2004


Thermodynamic analysis on energy densities of batteries
journal, January 2011


Revealing the Conversion Mechanism of Transition Metal Oxide Electrodes during Lithiation from First-Principles
journal, October 2017


Particle Size Effects on the Electrochemical Performance of Copper Oxides toward Lithium
journal, January 2001


Highly ordered mesoporous NiO anode material for lithium ion batteries with an excellent electrochemical performance
journal, January 2011


NiO nanomaterials: controlled fabrication, formation mechanism and the application in lithium-ion battery
journal, January 2012


Mesoporous NiO nanosheet networks as high performance anodes for Li ion batteries
journal, January 2013


Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
journal, March 2013


Nanostructured NiO electrode for high rate Li-ion batteries
journal, January 2011


NiO nanocone array electrode with high capacity and rate capability for Li-ion batteries
journal, January 2011


Ultrathin nickel oxide nanosheets for enhanced sodium and lithium storage
journal, January 2015


Electrochemical study of NiO nanosheets: toward the understanding of capacity fading
journal, February 2017


NiGa 2 O 4 /rGO Composite as Long-Cycle-Life Anode Material for Lithium-Ion Batteries
journal, January 2019


Morphological Evolution of Multilayer Ni/NiO Thin Film Electrodes during Lithiation
journal, July 2016


Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics
journal, January 2017


p-Type semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer bulk-heterojunction solar cells
journal, February 2008


Structural and Electrical Functionality of NiO Interfacial Films in Bulk Heterojunction Organic Solar Cells
journal, April 2011


Design and performance of the 33-BM beamline at the Advanced Photon Source
journal, September 2011

  • Karapetrova, Evguenia; Ice, Gene; Tischler, Jonathan
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1
  • https://doi.org/10.1016/j.nima.2010.12.159

Real-Time Observations of Interfacial Lithiation in a Metal Silicide Thin Film
journal, October 2012


Co-refinement of multiple-contrast neutron/X-ray reflectivity data using MOTOFIT
journal, March 2006


Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009


The defect structure of nickel oxide surfaces as revealed by photoelectron spectroscopy
journal, January 1984

  • Roberts, M. Wyn; Smart, Roger St C.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 80, Issue 11
  • https://doi.org/10.1039/f19848002957

Advanced grazing-incidence techniques for modern soft-matter materials analysis
journal, January 2015


Anomalous Surface Reflection of X Rays
journal, September 1963


Scattering functions of polyhedra
journal, March 2015


XPS depth profile analysis of non-stoichiometric NiO films
journal, January 2004


New interpretations of XPS spectra of nickel metal and oxides
journal, May 2006


Sputter reduction of oxides by ion bombardment during Auger depth profile analysis
journal, August 1990


Examining Solid Electrolyte Interphase Formation on Crystalline Silicon Electrodes: Influence of Electrochemical Preparation and Ambient Exposure Conditions
journal, September 2012


XPS and UPS studies on electronic structure of Li2O
journal, December 2000


Distribution of intercalated lithium in V2O5 thin films determined by SIMS depth profiling
journal, January 2006


White lines and d -band occupancy for the 3 d transition-metal oxides and lithium transition-metal oxides
journal, June 2004


Structure and Bonding at Ni–ZrO 2 (Cubic) Interfaces Formed by the Reduction of a NiO–ZrO 2 (Cubic) Composite
journal, September 1997


A study on capacity fading of lithium-ion battery with manganese spinel positive electrode during cycling
journal, April 2006


Effect of SEI on Capacity Losses of Spinel Lithium Manganese Oxide/Graphite Batteries Stored at 60°C
journal, January 2010


Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013


Oxidation state of cross-over manganese species on the graphite electrode of lithium-ion cells
journal, January 2014


Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
journal, December 2016


Effect of Manganese Contamination on the Solid-Electrolyte-Interphase Properties in Li-Ion Batteries
journal, January 2013


Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Batteries
journal, January 2014


Molecular Probes Reveal Chemical Selectivity of the Solid–Electrolyte Interphase
journal, August 2018