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Title: Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake

Abstract

Alkylamine modified MOF prepared with a less polar solvent (cyclohexane) has a higher alkylamine loading amount and higher CO 2uptake than when prepared in a more polar solvent (dichloromethane).

Authors:
 [1];  [1]; ORCiD logo [2];  [3];  [4]; ORCiD logo [2]; ORCiD logo [3]
  1. Department of Chemistry; Texas A&M University; College Station; USA
  2. Department of Chemical and Biomolecular Engineering; National University of Singapore; Singapore
  3. Department of Chemistry; Texas A&M University; College Station; USA; Department of Materials Science and Engineering
  4. Profusa, Inc.; South San Francisco; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Texas A & M Univ., College Station, TX (United States); Univ. of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1566647
DOE Contract Number:  
FE0026472; SC0001015
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 7; Journal Issue: 13; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, and Zhou, Hong-Cai. Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake. United States: N. p., 2019. Web. doi:10.1039/c8ta11300a.
Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, & Zhou, Hong-Cai. Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake. United States. doi:10.1039/c8ta11300a.
Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, and Zhou, Hong-Cai. Tue . "Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake". United States. doi:10.1039/c8ta11300a.
@article{osti_1566647,
title = {Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake},
author = {Li, Hao and Wang, Kecheng and Hu, Zhigang and Chen, Ying-Pin and Verdegaal, Wolfgang and Zhao, Dan and Zhou, Hong-Cai},
abstractNote = {Alkylamine modified MOF prepared with a less polar solvent (cyclohexane) has a higher alkylamine loading amount and higher CO2uptake than when prepared in a more polar solvent (dichloromethane).},
doi = {10.1039/c8ta11300a},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 13,
volume = 7,
place = {United States},
year = {2019},
month = {1}
}

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