An experimental investigation into the reduced mobilities of lanthanide cations using high-resolution ion mobility mass spectrometry
Abstract
Reduced mobilities for ground-state electronic configurations of the complete lanthanide series of cations, excluding promethium, have been measured. These values were obtained using an ion mobility mass spectrometer that utilizes a 2 m drift tube to generate high-resolution ion mobility data. In all cases, lanthanide cations were generated using pulsed-laser vaporization of either a metal rod or foil target. The mobilities of Eu+, Gd+, Yb+, and Lu+ have been previously examined and these data are also included. All other lanthanide cation mobilities, measured in He, are reported here for the first time. A discussion of the observed trends in the mobilities of the lanthanide series is also provided.
- Authors:
-
- Nevada National Security Site, Special Technologies Laboratory, National Security Technologies, LLC
- Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, USA
- Publication Date:
- Research Org.:
- Nevada National Security Site/National Security Technologies, LLC
- Sponsoring Org.:
- USDOE; USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation Research and Development (NA-22)
- OSTI Identifier:
- 1560377
- Report Number(s):
- DOE/NV/25946-3318
Journal ID: ISSN 1387-3806
- DOE Contract Number:
- DE-AC52-06NA25946
- Resource Type:
- Journal Article
- Journal Name:
- International Journal of Mass Spectrometry
- Additional Journal Information:
- Journal Volume: 423; Journal Issue: C; Journal ID: ISSN 1387-3806
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS; 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; High-resolution ion mobility, collision cross section, lanthanide cations, pulsed laser vaporization
Citation Formats
Manard, Manuel J., and Kemper, Paul R. An experimental investigation into the reduced mobilities of lanthanide cations using high-resolution ion mobility mass spectrometry. United States: N. p., 2017.
Web. doi:10.1016/j.ijms.2017.10.010.
Manard, Manuel J., & Kemper, Paul R. An experimental investigation into the reduced mobilities of lanthanide cations using high-resolution ion mobility mass spectrometry. United States. https://doi.org/10.1016/j.ijms.2017.10.010
Manard, Manuel J., and Kemper, Paul R. 2017.
"An experimental investigation into the reduced mobilities of lanthanide cations using high-resolution ion mobility mass spectrometry". United States. https://doi.org/10.1016/j.ijms.2017.10.010.
@article{osti_1560377,
title = {An experimental investigation into the reduced mobilities of lanthanide cations using high-resolution ion mobility mass spectrometry},
author = {Manard, Manuel J. and Kemper, Paul R.},
abstractNote = {Reduced mobilities for ground-state electronic configurations of the complete lanthanide series of cations, excluding promethium, have been measured. These values were obtained using an ion mobility mass spectrometer that utilizes a 2 m drift tube to generate high-resolution ion mobility data. In all cases, lanthanide cations were generated using pulsed-laser vaporization of either a metal rod or foil target. The mobilities of Eu+, Gd+, Yb+, and Lu+ have been previously examined and these data are also included. All other lanthanide cation mobilities, measured in He, are reported here for the first time. A discussion of the observed trends in the mobilities of the lanthanide series is also provided.},
doi = {10.1016/j.ijms.2017.10.010},
url = {https://www.osti.gov/biblio/1560377},
journal = {International Journal of Mass Spectrometry},
issn = {1387-3806},
number = C,
volume = 423,
place = {United States},
year = {Fri Dec 01 00:00:00 EST 2017},
month = {Fri Dec 01 00:00:00 EST 2017}
}
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