Pathways for practical high-energy long-cycling lithium metal batteries

Liu, Jun; Bao, Zhenan; Cui, Yi; Dufek, Eric J.; Goodenough, John B.; Khalifah, Peter; Li, Qiuyan; Liaw, Bor Yann; Liu, Ping; Manthiram, Arumugam; Meng, Y. Shirley; Subramanian, Venkat R.; Toney, Michael F.; Viswanathan, Vilayanur V.; Whittingham, M. Stanley; Xiao, Jie; Xu, Wu; Yang, Jihui; Yang, Xiao-Qing; Zhang, Ji-Guang

doi:10.1038/s41560-019-0338-x

Title: Pathways for practical high-energy long-cycling lithium metal batteries

Journal Article · Mon Feb 25 00:00:00 EST 2019 · Nature Energy

DOI:https://doi.org/10.1038/s41560-019-0338-x· OSTI ID:1498872

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^[8]; Viswanathan, Vilayanur V. ^[1];

^[9]; Xiao, Jie ^[1];

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^[10]; Yang, Xiao-Qing ^[5];

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Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environment Directorate
Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
Idaho National Lab. (INL), Idaho Falls, ID (United States). Clean Energy and Transportation Division
Univ. of Texas, Austin, TX (United States). Dept. of Mechanical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
Univ. of California, San Diego, CA (United States). Dept. of NanoEngineering
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environment Directorate; Univ. of Washington, Seattle, WA (United States). College of Engineering
SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource
Binghamton Univ., NY (United States). Dept. of Materials Science and Engineering
Univ. of Washington, Seattle, WA (United States). College of Engineering

State-of-the-art lithium (Li)-ion batteries are approaching their specific energy limits yet are challenged by the ever-increasing demand of today’s energy storage and power applications, especially for electric vehicles. Li metal is considered an ultimate anode material for future high-energy rechargeable batteries when combined with existing or emerging high-capacity cathode materials. However, much current research focuses on the battery materials level, and there have been very few accounts of cell design principles. Here we discuss crucial conditions needed to achieve a specific energy higher than 350 Wh kg-1, up to 500 Wh kg-1, for rechargeable Li metal batteries using high-nickel-content lithium nickel manganese cobalt oxides as cathode materials. We also provide an analysis of key factors such as cathode loading, electrolyte amount and Li foil thickness that impact the cell-level cycle life. Furthermore, we identify several important strategies to reduce electrolyte-Li reaction, protect Li surfaces and stabilize anode architectures for long-cycling high-specific-energy cells.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Idaho National Lab. (INL), Idaho Falls, ID (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: SC0012704; AC02-05CH11231; AC07-05ID14517

OSTI ID:: 1498872

Alternate ID(s):: OSTI ID: 1559963

Report Number(s):: BNL-211347-2019-JAAM; INL/JOU-17-43532-Rev000

Journal Information:: Nature Energy, Vol. 4, Issue 3; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 1628 works

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Promoting the Transformation of Li ₂ S ₂ to Li ₂ S: Significantly Increasing Utilization of Active Materials for High‐Sulfur‐Loading Li–S Batteries Yang, Xiaofei; Gao, Xuejie; Sun, Qian Advanced Materials, Vol. 31, Issue 25 https://doi.org/10.1002/adma.201901220	journal	April 2019
Dendrite‐Free Potassium Metal Anodes in a Carbonate Electrolyte Liu, Pengcheng; Wang, Yixian; Gu, Qilin Advanced Materials, Vol. 32, Issue 7 https://doi.org/10.1002/adma.201906735	journal	November 2019
Enhanced Surface Interactions Enable Fast Li ⁺ Conduction in Oxide/Polymer Composite Electrolyte Wu, Nan; Chien, Po‐Hsiu; Qian, Yumin Angewandte Chemie, Vol. 132, Issue 10 https://doi.org/10.1002/ange.201914478	journal	January 2020
Improving Lithium‐Metal Battery Performance under the Conditions of Lean Electrolyte through MoS ₂ Coating Cha, Eunho; Lee, Hongkyung; Choi, Wonbong ChemElectroChem, Vol. 7, Issue 4 https://doi.org/10.1002/celc.201901735	journal	January 2020
Chemically Prelithiated Hard‐Carbon Anode for High Power and High Capacity Li‐Ion Batteries Shen, Yifei; Qian, Jiangfeng; Yang, Hanxi Small, Vol. 16, Issue 7 https://doi.org/10.1002/smll.201907602	journal	January 2020
Biomacromolecules enabled dendrite-free lithium metal battery and its origin revealed by cryo-electron microscopy Ju, Zhijin; Nai, Jianwei; Wang, Yao Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14358-1	journal	January 2020
Efficient and robust lithium metal electrodes enabled by synergistic surface activation–passivation of copper frameworks Yun, Jonghyeok; Won, Eun-Seo; Shin, Hyun-Seop Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta08779f	journal	January 2019
Covalent organic framework-based ultrathin crystalline porous film: manipulating uniformity of fluoride distribution for stabilizing lithium metal anode Zhao, Zedong; Chen, Wuji; Impeng, Sarawoot Journal of Materials Chemistry A, Vol. 8, Issue 6 https://doi.org/10.1039/c9ta13384d	journal	January 2020
Hot Formation for Improved Low Temperature Cycling of Anode-Free Lithium Metal Batteries Genovese, Matthew; Louli, A. J.; Weber, Rochelle Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0661914jes	journal	January 2019
Using Triethyl Phosphate to Increase the Solubility of LiNO ₃ in Carbonate Electrolytes for Improving the Performance of the Lithium Metal Anode Brown, Zachary L.; Heiskanen, Satu; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 166, Issue 12 https://doi.org/10.1149/2.0991912jes	journal	January 2019
Safety Issues in Lithium Ion Batteries: Materials and Cell Design Wu, Xiangkun; Song, Kaifang; Zhang, Xiaoyan Frontiers in Energy Research, Vol. 7 https://doi.org/10.3389/fenrg.2019.00065	journal	July 2019
Microscopic Properties of Na and Li—A First Principle Study of Metal Battery Anode Materials Gaissmaier, Daniel; Borg, Matthias; Fantauzzi, Donato Karlsruhe https://doi.org/10.5445/ir/1000105617	text	January 2020
Innenrücktitelbild: A Sustainable Solid Electrolyte Interphase for High‐Energy‐Density Lithium Metal Batteries Under Practical Conditions (Angew. Chem. 8/2020) Zhang, Xue‐Qiang; Li, Tao; Li, Bo‐Quan Angewandte Chemie, Vol. 132, Issue 8 https://doi.org/10.1002/ange.202000869	journal	January 2020
Enhanced Surface Interactions Enable Fast Li ⁺ Conduction in Oxide/Polymer Composite Electrolyte Wu, Nan; Chien, Po‐Hsiu; Qian, Yumin Angewandte Chemie International Edition, Vol. 59, Issue 10 https://doi.org/10.1002/anie.201914478	journal	January 2020
Inside Back Cover: A Sustainable Solid Electrolyte Interphase for High‐Energy‐Density Lithium Metal Batteries Under Practical Conditions (Angew. Chem. Int. Ed. 8/2020) Zhang, Xue‐Qiang; Li, Tao; Li, Bo‐Quan Angewandte Chemie International Edition, Vol. 59, Issue 8 https://doi.org/10.1002/anie.202000869	journal	February 2020
Cover Feature: Improving Lithium‐Metal Battery Performance under the Conditions of Lean Electrolyte through MoS ₂ Coating (ChemElectroChem 4/2020) Cha, Eunho; Lee, Hongkyung; Choi, Wonbong ChemElectroChem, Vol. 7, Issue 4 https://doi.org/10.1002/celc.202000133	journal	January 2020
Mechanical rolling formation of interpenetrated lithium metal/lithium tin alloy foil for ultrahigh-rate battery anode Wan, Mintao; Kang, Sujin; Wang, Li Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14550-3	journal	February 2020
Tailored Solid Polymer Electrolytes by Montmorillonite with High Ionic Conductivity for Lithium-Ion Batteries Zhao, Yingjian; Wang, Yong Nanoscale Research Letters, Vol. 14, Issue 1 https://doi.org/10.1186/s11671-019-3210-9	journal	December 2019

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Title: Pathways for practical high-energy long-cycling lithium metal batteries

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