Design of Ultrastiff Organosilicate Hybrid Glasses

Kilic, Karsu I.; Dauskardt, Reinhold H.

doi:10.1002/adfm.201904890

Title: Design of Ultrastiff Organosilicate Hybrid Glasses

Journal Article · Sun Aug 25 00:00:00 EDT 2019 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.201904890· OSTI ID:1800465

Kilic, Karsu I. ^[1];

^[1]

Stanford Univ., CA (United States). Dept. of Materials Science and Engineering

Abstract Hyperconnected hybrid organosilicate glass networks formed by hyperstiff precursor molecules with certain geometrical characteristics can lead to exceptional elastic properties superior to that of fully dense silica. Carbon‐ and silicon‐containing precursors with defined molecular planarity are introduced and a new design strategy where both the network connectivity and the precursor geometry are effectively utilized to enhance elastic properties is proposed. The geometrical features rendering a precursor molecule as hyperstiff are identified through molecular dynamics simulations and constraint analyses by calculating the degree of nonaffine deformations. Nonaffine deformations have not been previously examined for organosilicate hybrid glass networks and are a fundamental new approach to reveal the combined impact of precursor geometry and connectivity on the mechanical behavior of hybrid glass networks.

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Research Organization:: Stanford Univ., CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-07ER46391

OSTI ID:: 1800465

Alternate ID(s):: OSTI ID: 1558721

Journal Information:: Advanced Functional Materials, Vol. 29, Issue 44; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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