Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective
- University of South Carolina
- Savannah River National Laboratory,
- Clemson University
- The French Alternative Energies and Atomic Energy Commission (CEA), Gif-sur-Yvette, France
- BATTELLE (PACIFIC NW LAB)
- Alfred University
- University of Florida
- Colorado State University
This perspective focuses on the synthesis, characterization and modeling of three classes of hierarchical materials with potential for sequestering radionuclides: nanoparticles, porous frameworks and crystalline salt inclusion phases. The scientific impact of hierarchical structures and the development of the underlying crystal chemistry is discussed as laying the groundwork for the design, local structure control, and synthesis of new forms of matter with tailored properties. This requires development of the necessary scientific understanding of such complex structures through integrated synthesis, characterization, and modeling studies that can allow their purposeful creation and properties. The ultimate practical aim is to provide the means to create novel structure types that can simultaneously sequester multiple radionuclides. The result will lead to the creation of safe and efficient, long lasting waste forms for fission products and transuranic elements that are the products of nuclear materials processing waste streams. The generation of the scientific base for working toward that goal is presented.
- Research Organization:
- Energy Frontier Research Centers (EFRC) (United States). Center for Hierarchical Waste Form Materials (CHWM); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1557695
- Report Number(s):
- PNNL-SA-136250
- Journal Information:
- Chemistry of Materials, Vol. 30, Issue 14
- Country of Publication:
- United States
- Language:
- English
Similar Records
A physics-based mesoscale phase-field model for predicting the uptake kinetics of radionuclides in hierarchical nuclear wasteform materials
Polymer/inorganic nanocomposites with tailored hierarchical structure as advanced dielectric materials