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Title: Facile Extraction of Wheat Straw by Deep Eutectic Solvent (DES) to Produce Lignin Nanoparticles

Abstract

A detailed investigation of choline chloride-lactic acid (ChCl-LA)-based deep eutectic solvent (DES) extraction of lignin nanoparticles from herbaceous biomass (wheat straw) was conducted. It was found that DES can extract high purity lignin (up to 94.8%) with a high yield (up to 81.5% from air-dried samples and 85.9% from oven-dried samples) from wheat straw. The cleavages of ether bonds in lignin, as well as the linkages between lignin and hemicelluloses during DES treatments at different conditions, were analyzed. The effects of reaction time, treatment temperature and water content in wheat straw on lignin yield, purity, and chemical structure were determined. The water content in biomass was found to affect the hydrogen bond interaction between lignin and DES, which was a key factor influencing the lignin extraction yield and chemical properties of separated lignin. The lignin extracted from wheat straw by DES consists of well-dispersed nanoparticles with a narrow size distribution peaking at 70-90 nm. The mechanism of ChCl-LA-based DES depolymerization and extraction of lignin from wheat straw is discussed.

Authors:
 [1];  [2];  [1];  [3];  [1]
  1. Washington State University
  2. BATTELLE (PACIFIC NW LAB)
  3. WASHINGTON STATE UNIV
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1556914
Report Number(s):
PNNL-SA-144469
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
ACS Sustainable Chemistry & Engineering
Additional Journal Information:
Journal Volume: 7; Journal Issue: 12
Country of Publication:
United States
Language:
English

Citation Formats

Lou, Rui, Ma, Ruoshui, Lin, Kuan-ting, Ahamed, Aftab C., and Zhang, Xiao. Facile Extraction of Wheat Straw by Deep Eutectic Solvent (DES) to Produce Lignin Nanoparticles. United States: N. p., 2019. Web. doi:10.1021/acssuschemeng.8b05816.
Lou, Rui, Ma, Ruoshui, Lin, Kuan-ting, Ahamed, Aftab C., & Zhang, Xiao. Facile Extraction of Wheat Straw by Deep Eutectic Solvent (DES) to Produce Lignin Nanoparticles. United States. doi:10.1021/acssuschemeng.8b05816.
Lou, Rui, Ma, Ruoshui, Lin, Kuan-ting, Ahamed, Aftab C., and Zhang, Xiao. Mon . "Facile Extraction of Wheat Straw by Deep Eutectic Solvent (DES) to Produce Lignin Nanoparticles". United States. doi:10.1021/acssuschemeng.8b05816.
@article{osti_1556914,
title = {Facile Extraction of Wheat Straw by Deep Eutectic Solvent (DES) to Produce Lignin Nanoparticles},
author = {Lou, Rui and Ma, Ruoshui and Lin, Kuan-ting and Ahamed, Aftab C. and Zhang, Xiao},
abstractNote = {A detailed investigation of choline chloride-lactic acid (ChCl-LA)-based deep eutectic solvent (DES) extraction of lignin nanoparticles from herbaceous biomass (wheat straw) was conducted. It was found that DES can extract high purity lignin (up to 94.8%) with a high yield (up to 81.5% from air-dried samples and 85.9% from oven-dried samples) from wheat straw. The cleavages of ether bonds in lignin, as well as the linkages between lignin and hemicelluloses during DES treatments at different conditions, were analyzed. The effects of reaction time, treatment temperature and water content in wheat straw on lignin yield, purity, and chemical structure were determined. The water content in biomass was found to affect the hydrogen bond interaction between lignin and DES, which was a key factor influencing the lignin extraction yield and chemical properties of separated lignin. The lignin extracted from wheat straw by DES consists of well-dispersed nanoparticles with a narrow size distribution peaking at 70-90 nm. The mechanism of ChCl-LA-based DES depolymerization and extraction of lignin from wheat straw is discussed.},
doi = {10.1021/acssuschemeng.8b05816},
journal = {ACS Sustainable Chemistry & Engineering},
number = 12,
volume = 7,
place = {United States},
year = {2019},
month = {6}
}