Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Phosphorene oxides as a promising cathode material for sealed non-aqueous Li–oxygen batteries

Journal Article · · Journal of Materials Chemistry. A
DOI:https://doi.org/10.1039/c8ta01218k· OSTI ID:1543818
 [1];  [2];  [3]
  1. State Key Laboratory for Mechanical Behavior of Materials; Xi'an Jiaotong University; Xi'an; China; Materials Science Division
  2. State Key Laboratory for Mechanical Behavior of Materials; Xi'an Jiaotong University; Xi'an; China; Collaborative Innovation Center of Suzhou Nano Science and Technology
  3. Materials Science Division; Lawrence Berkeley National Laboratory; Berkeley; USA

A fully sealed Li–O battery based on a phosphorene oxide cathode is demonstrated with high specific capacity, energy density and anisotropic diffusivity.

Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)
Sponsoring Organization:
USDOE Office of Science (SC)
OSTI ID:
1543818
Journal Information:
Journal of Materials Chemistry. A, Vol. 6, Issue 17; ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (72)

A Reversible and Higher-Rate Li-O2 Battery journal July 2012
Li–O2 and Li–S batteries with high energy storage journal January 2012
A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery journal January 1996
Review on Li–air batteries—Opportunities, limitations and perspective journal February 2011
Lithium−Air Battery: Promise and Challenges journal June 2010
The Influence of Catalysts on Discharge and Charge Voltages of Rechargeable Li–Oxygen Batteries journal January 2010
Elucidating the Mechanism of Oxygen Reduction for Lithium-Air Battery Applications journal November 2009
A Critical Review of Li∕Air Batteries journal January 2012
Challenges in the development of advanced Li-ion batteries: a review journal January 2011
Study on lithium/air secondary batteries—Stability of NASICON-type lithium ion conducting glass–ceramics with water journal April 2009
A study on lithium/air secondary batteries—Stability of NASICON-type glass ceramics in acid solutions journal September 2010
Theoretical Energy Density of Li–Air Batteries journal January 2008
Investigation of the O2 Electrochemistry in a Polymer Electrolyte Solid-State Cell journal March 2011
Electrical conductivity in Li 2 O 2 and its role in determining capacity limitations in non-aqueous Li-O 2 batteries journal December 2011
High energy lithium–oxygen batteries – transport barriers and thermodynamics journal January 2012
Charge transport in lithium peroxide: relevance for rechargeable metal–air batteries journal January 2013
Discharge characteristic of a non-aqueous electrolyte Li/O2 battery journal February 2010
On the Mechanism of Nonaqueous Li–O 2 Electrochemistry on C and Its Kinetic Overpotentials: Some Implications for Li–Air Batteries journal November 2012
Characterization of the Lithium/Oxygen Organic Electrolyte Battery journal January 2002
Oxygen Transport Properties of Organic Electrolytes and Performance of Lithium/Oxygen Battery journal January 2003
Optimization of Nonaqueous Electrolytes for Primary Lithium/Air Batteries Operated in Ambient Environment journal January 2009
Ambient operation of Li/Air batteries journal July 2010
Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes journal January 2010
Reactions in the Rechargeable Lithium–O 2 Battery with Alkyl Carbonate Electrolytes journal May 2011
A lithium–oxygen battery based on lithium superoxide journal January 2016
Anion-redox nanolithia cathodes for Li-ion batteries journal July 2016
Black phosphorus field-effect transistors journal March 2014
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility journal March 2014
Ultrafast and Directional Diffusion of Lithium in Phosphorene for High-Performance Lithium-Ion Battery journal February 2015
Pristine and defect-containing phosphorene as promising anode materials for rechargeable Li batteries journal January 2015
The potential application of phosphorene as an anode material in Li-ion batteries journal January 2014
First-Principles Study of Phosphorene and Graphene Heterostructure as Anode Materials for Rechargeable Li Batteries journal December 2015
Formation of Stable Phosphorus–Carbon Bond for Enhanced Performance in Black Phosphorus Nanoparticle–Graphite Composite Battery Anodes journal July 2014
Phosphorene as a Polysulfide Immobilizer and Catalyst in High-Performance Lithium-Sulfur Batteries journal October 2016
Phosphorene as a promising anchoring material for lithium–sulfur batteries: a computational study journal January 2016
Entrapment of Polysulfides by a Black-Phosphorus-Modified Separator for Lithium-Sulfur Batteries journal September 2016
Bandgap Engineering of Phosphorene by Laser Oxidation toward Functional 2D Materials journal September 2015
Projector augmented-wave method journal December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Generalized Gradient Approximation Made Simple journal October 1996
Erratum: “Hybrid functionals based on a screened Coulomb potential” [J. Chem. Phys. 118, 8207 (2003)] journal June 2006
Semiempirical GGA-type density functional constructed with a long-range dispersion correction journal January 2006
Special points for Brillouin-zone integrations journal June 1976
A climbing image nudged elastic band method for finding saddle points and minimum energy paths journal December 2000
A fast and robust algorithm for Bader decomposition of charge density journal June 2006
Implicit solvation model for density-functional study of nanocrystal surfaces and reaction pathways journal February 2014
Phosphorene oxide: stability and electronic properties of a novel two-dimensional material journal January 2015
Oxygen Defects in Phosphorene journal January 2015
Experimental and theoretical investigations of the X-ray absorption near edge spectra (XANES) of P4O6 and P4O6X (X  O, S, Se) journal August 1997
Creating a Stable Oxide at the Surface of Black Phosphorus journal June 2015
Architecture of graphdiyne nanoscale films journal January 2010
Epitaxial Growth of Single Layer Blue Phosphorus: A New Phase of Two-Dimensional Phosphorus journal July 2016
Penta-graphene: A Promising Anode Material as the Li/Na-Ion Battery with Both Extremely High Theoretical Capacity and Fast Charge/Discharge Rate journal December 2016
Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries journal August 2014
Metallic VS 2 Monolayer: A Promising 2D Anode Material for Lithium Ion Batteries journal November 2013
Correcting density functional theory for accurate predictions of compound enthalpies of formation: Fitted elemental-phase reference energies journal March 2012
Density functional theory study of Li binding to graphene journal January 2016
Enhanced Li Adsorption and Diffusion on MoS2 Zigzag Nanoribbons by Edge Effects: A Computational Study journal August 2012
Edge Effects on the Characteristics of Li Diffusion in Graphene journal August 2010
Predicting Crystal Structures with Data Mining of Quantum Calculations journal September 2003
First principles computational materials design for energy storage materials in lithium ion batteries journal January 2009
Blue Phosphorene/MS 2 (M = Nb, Ta) Heterostructures As Promising Flexible Anodes for Lithium-Ion Batteries journal May 2016
Could Borophene Be Used as a Promising Anode Material for High-Performance Lithium Ion Battery? journal August 2016
Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries journal June 2012
Density Functional Investigation on Li 2 MnO 3 journal October 2012
Communications: Elementary oxygen electrode reactions in the aprotic Li-air battery journal February 2010
The chemistry of graphene oxide journal January 2010
Water Dynamics in Graphite Oxide Investigated with Neutron Scattering journal November 2006
A new structural model for graphite oxide journal April 1998
Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst journal August 2011
Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries journal January 2013
Self-Assembled TiO 2 –Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion journal March 2009