Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants

Barroux, Hugo; Jiang, Tengfei; Paul, Camille; Massuyeau, Florian; Génois, Romain; Gordon, Elijah E.; Whangbo, Myung-Hwan; Jobic, Stéphane; Gautier, Romain

doi:10.1002/chem.201605707

Title: Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants

Journal Article · Thu Jan 26 00:00:00 EST 2017 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201605707· OSTI ID:1543479

Barroux, Hugo ^[1]; Jiang, Tengfei ^[1]; Paul, Camille ^[1]; Massuyeau, Florian ^[1]; Génois, Romain ^[1]; Gordon, Elijah E. ^[2]; Whangbo, Myung-Hwan ^[2]; Jobic, Stéphane ^[1]; Gautier, Romain ^[1]

Centre National de la Recherche Scientifique (CNRS), Nantes Cedex (France)
North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry

Abstract The physical properties of doped multifunctional compounds are commonly tuned by controlling the amount of dopants, but this control is limited because all the properties are influenced simultaneously by this single parameter. Here, we present a strategy that enables the fine‐tuning of a specific combination of properties by controlling the reduction of dopants. The feasibility of this approach was demonstrated by optimizing the near‐IR photoluminescence of strontium titanate SrTiO ₃ :Ni for potential applications in biomedicine for a range of absorbance in the visible/near‐IR region. We discussed how material properties, such as luminescence, conductivity, or photocatalytic properties can be designed by carefully controlling the ratio of dopants in different oxidation states.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1543479

Alternate ID(s):: OSTI ID: 1400466

Journal Information:: Chemistry - A European Journal, Vol. 23, Issue 13; ISSN 0947-6539

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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Cited By (1)

Transformation of Perovskite BaBiO ₃ into Layered BaBiO _2.5 Crystals Featuring Unusual Chemical Bonding and Luminescence Li, Hong; Zhao, Qing; Liu, Bo-Mei Chemistry - A European Journal, Vol. 24, Issue 35 https://doi.org/10.1002/chem.201801257	journal	May 2018

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36 MATERIALS SCIENCE
chemistry
biomedicine
dopants
luminescence
multifunctional materials
visible/near-IR absorption