Fabrication of a Pillared ZSM-5 Framework for Shape Selectivity of Ethane Dehydroaromatization

Ye, Jiahui; Bai, Lei; Liu, Baoyu; Tian, Hanjing; Hu, Jianli; Polo Garzon, Felipe; Mayes, Richard; Wu, Zili; Fang, Yanxiong

doi:10.1021/acs.iecr.8b04965

Title: Fabrication of a Pillared ZSM-5 Framework for Shape Selectivity of Ethane Dehydroaromatization

Journal Article · Fri Apr 05 00:00:00 EDT 2019 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.8b04965· OSTI ID:1543195

Ye, Jiahui ^[1]; Bai, Lei ^[2]; Liu, Baoyu ^[3]; Tian, Hanjing ^[2]; Hu, Jianli ^[2];

^[4];

^[4]; Fang, Yanxiong ^[3]

Guangdong Univ of Technology, Guangzhou (China); West Virginia Univ., Morgantown, WV (United States)
West Virginia Univ., Morgantown, WV (United States)
Guangdong Univ of Technology, Guangzhou (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Ethane, the second major component of shale gas, is a prospective raw feedstock to valuable chemicals and fuels. Innovative pillared ZSM-5 with various lamellar thicknesses and Si/Al ratios were successfully synthesized with the dual-template method; 0.67 wt % Mo were dispersed over these lamellar ZSM-5, and evaluated for ethane dehydroaromatization. The influence of zeolite morphology and the texture property for the reduction/acidity nature of MoOx species were investigated by X-ray diffraction, scanning electron microscopy, N2-sorption, H2-temperature programmed reduction/oxidation, and NH3-temperature-programmed desorption. The high concentration of acidic sites not only increases ethane conversion and aromatic selectivity, but intensely induces surface coking. Therefore, a moderate Si/Al ratio is utilized to balance catalytic reactivity and stability. Thicker zeolite layers with a long diffusion path exhibited fair ethane conversion, but high aromatization yield. It is of significant importance that the lamellar Mo/MFI catalyst, with Si/Al = 50 and 210 nm layer thickness, demonstrated excellent regenerability during a multicycle reaction/oxidation operation, which could be a promising system for industrial optimization and process deployment.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1543195

Journal Information:: Industrial and Engineering Chemistry Research, Vol. 58, Issue 17; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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