An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research

Jahrman, Evan P.; Holden, William M.; Ditter, Alexander Scott; Mortensen, Devon R.; Seidler, Gerald T.; Fister, Timothy T.; Kozimor, Stosh Anthony; Piper, Louis F. J.; Rana, Jatinkumar; Hyatt, Neil C.; Stennett, Martin C.

doi:10.1063/1.5049383

Title: An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research

Journal Article · Wed Feb 27 00:00:00 EST 2019 · Review of Scientific Instruments

DOI:https://doi.org/10.1063/1.5049383· OSTI ID:1542825

^[1];

^[2]; Mortensen, Devon R. ^[3];

^[1]; Fister, Timothy T. ^[4];

^[5];

^[6]; Rana, Jatinkumar ^[6]; Hyatt, Neil C. ^[7]; Stennett, Martin C. ^[7]

Univ. of Washington, Seattle, WA (United States)
Univ. of Washington, Seattle, WA (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Washington, Seattle, WA (United States); easyXAFS LLC, Renton, WA (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Binghamton Univ., Binghamton, NY (United States)
The Univ. of Sheffield, Sheffield (United Kingdom)

X-ray absorption fine structure (XAFS) and x-ray emission spectroscopy (XES) are advanced x-ray spectroscopies that impact a wide range of disciplines. Furthermore, unlike the majority of other spectroscopic methods, XAFS and XES are accompanied by an unusual access model, wherein the dominant use of the technique is for premier research studies at world-class facilities, i.e., synchrotron x-ray light sources. In this paper, we report the design and performance of an improved XAFS and XES spectrometer based on the general conceptual design of Seidler et al. [Rev. Sci. Instrum. 85, 113906 (2014)]. New developments include reduced mechanical degrees of freedom, much-increased flux, and a wider Bragg angle range to enable extended x-ray absorption fine structure (EXAFS) measurement and analysis for the first time with this type of modern laboratory XAFS configuration. This instrument enables a new class of routine applications that are incompatible with the mission and access model of the synchrotron light sources. To illustrate this, we provide numerous examples of x-ray absorption near edge structure (XANES), EXAFS, and XES results for a variety of problems and energy ranges. Highlights include XAFS and XES measurements of battery electrode materials, EXAFS of Ni with full modeling of results to validate monochromator performance, valence-to-core XES for 3d transition metal compounds, and uranium XANES and XES for different oxidation states. Taken en masse, these results further support the growing perspective that modern laboratory-based XAFS and XES have the potential to develop a new branch of analytical chemistry.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: 89233218CNA000001

OSTI ID:: 1542825

Report Number(s):: LA-UR-18-26355

Journal Information:: Review of Scientific Instruments, Vol. 90, Issue 2; ISSN 0034-6748

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 55 works

Citation information provided by
Web of Science

References (98)

Rapid Mapping of Lithiation Dynamics in Transition Metal Oxide Particles with Operando X-ray Absorption Spectroscopy Nowack, Lea; Grolimund, Daniel; Samson, Vallerie Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep21479	journal	February 2016
Preparation, characterisation and dissolution of a CeO2 analogue for UO2 nuclear fuel Stennett, Martin C.; Corkhill, Claire L.; Marshall, Luke A. Journal of Nuclear Materials, Vol. 432, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2012.07.038	journal	January 2013
A compact dispersive refocusing Rowland circle X-ray emission spectrometer for laboratory, synchrotron, and XFEL applications Holden, William M.; Hoidn, Oliver R.; Ditter, Alexander S. Review of Scientific Instruments, Vol. 88, Issue 7 https://doi.org/10.1063/1.4994739	journal	July 2017
On the Oxidation State of Manganese Ions in Li-Ion Battery Electrolyte Solutions Banerjee, Anjan; Shilina, Yuliya; Ziv, Baruch Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b10781	journal	January 2017
First Structural Characterization of a Protactinium(V) Single Oxo Bond in Aqueous Media Le Naour, Claire; Trubert, Didier; Di Giandomenico, Maria V. Inorganic Chemistry, Vol. 44, Issue 25 https://doi.org/10.1021/ic0512330	journal	December 2005
Robust optic alignment in a tilt-free implementation of the Rowland circle spectrometer Mortensen, Devon R.; Seidler, Gerald T. Journal of Electron Spectroscopy and Related Phenomena, Vol. 215 https://doi.org/10.1016/j.elspec.2016.11.006	journal	February 2017
Observing Solvation Dynamics with Simultaneous Femtosecond X-ray Emission Spectroscopy and X-ray Scattering Haldrup, Kristoffer; Gawelda, Wojciech; Abela, Rafael The Journal of Physical Chemistry B, Vol. 120, Issue 6 https://doi.org/10.1021/acs.jpcb.5b12471	journal	February 2016
High-resolution Laue-type DuMond curved crystal spectrometer Szlachetko, M.; Berset, M.; Dousse, J. -Cl. Review of Scientific Instruments, Vol. 84, Issue 9 https://doi.org/10.1063/1.4821621	journal	September 2013
Benchmark results and theoretical treatments for valence-to-core x-ray emission spectroscopy in transition metal compounds Mortensen, D. R.; Seidler, G. T.; Kas, Joshua J. Physical Review B, Vol. 96, Issue 12 https://doi.org/10.1103/physrevb.96.125136	journal	September 2017
Simultaneous Speciation, Structure, and Equilibrium Constant Determination in the Ni ²⁺ –EDTA–CN ^– Ternary System via High-Resolution Laboratory X-ray Absorption Fine Structure Spectroscopy and Theoretical Calculations Bajnóczi, Éva G.; Németh, Zoltán; Vankó, György Inorganic Chemistry, Vol. 56, Issue 22 https://doi.org/10.1021/acs.inorgchem.7b02311	journal	November 2017
Laboratory EXAFS spectrometer with a bent crystal, a solid‐state detector, and a fast detection system Tohji, Kazuyuki; Udagawa, Yasuo; Kawasaki, Tsutomu Review of Scientific Instruments, Vol. 54, Issue 11 https://doi.org/10.1063/1.1137288	journal	November 1983
Tunable laboratory extended x‐ray absorption fine structure system Cohen, G. G.; Fischer, D. A.; Colbert, J. Review of Scientific Instruments, Vol. 51, Issue 3 https://doi.org/10.1063/1.1136199	journal	March 1980
Comparative Study of f-Element Electronic Structure across a Series of Multimetallic Actinide and Lanthanoid-Actinide Complexes Possessing Redox-Active Bridging Ligands Schelter, Eric J.; Wu, Ruilian; Veauthier, Jacqueline M. Inorganic Chemistry, Vol. 49, Issue 4 https://doi.org/10.1021/ic9024475	journal	February 2010
Valence to Core X-ray Emission Spectroscopy Gallo, Erik; Glatzel, Pieter Advanced Materials, Vol. 26, Issue 46 https://doi.org/10.1002/adma.201304994	journal	May 2014
High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information Glatzel, Pieter; Bergmann, Uwe Coordination Chemistry Reviews, Vol. 249, Issue 1-2 https://doi.org/10.1016/j.ccr.2004.04.011	journal	January 2005
Experimentally Quantifying Small-Molecule Bond Activation Using Valence-to-Core X-ray Emission Spectroscopy Pollock, Christopher J.; Grubel, Katarzyna; Holland, Patrick L. Journal of the American Chemical Society, Vol. 135, Issue 32 https://doi.org/10.1021/ja3116247	journal	July 2013
Hard x-ray emission spectroscopy: a powerful tool for the characterization of magnetic semiconductors Rovezzi, M.; Glatzel, P. Semiconductor Science and Technology, Vol. 29, Issue 2 https://doi.org/10.1088/0268-1242/29/2/023002	journal	January 2014
Ce K edge XAS of ceria-based redox materials under realistic conditions for the two-step solar thermochemical dissociation of water and/or CO ₂ Rothensteiner, Matthäus; Sala, Simone; Bonk, Alexander Physical Chemistry Chemical Physics, Vol. 17, Issue 40 https://doi.org/10.1039/c5cp03179f	journal	January 2015
A laboratory-based hard x-ray monochromator for high-resolution x-ray emission spectroscopy and x-ray absorption near edge structure measurements Seidler, G. T.; Mortensen, D. R.; Remesnik, A. J. Review of Scientific Instruments, Vol. 85, Issue 11 https://doi.org/10.1063/1.4901599	journal	November 2014
XANES studies of rare earth metals and compounds Upadhyaya, G. K.; Shah, Galav; Gupta, S. N. Physica B: Condensed Matter, Vol. 208-209 https://doi.org/10.1016/0921-4526(94)01015-s	journal	March 1995
Kβ Emission and K Absorption Spectra of Sulfur in MnS Sugiura, Chikara; Gohshi, Yohichi; Suzuki, Isao Japanese Journal of Applied Physics, Vol. 11, Issue 6 https://doi.org/10.1143/jjap.11.911	journal	June 1972
Laboratory von Hámos X-ray spectroscopy for routine sample characterization Németh, Zoltán; Szlachetko, Jakub; Bajnóczi, Éva G. Review of Scientific Instruments, Vol. 87, Issue 10 https://doi.org/10.1063/1.4964098	journal	October 2016
Probing Surface Defects of InP Quantum Dots Using Phosphorus Kα and Kβ X-ray Emission Spectroscopy Stein, Jennifer L.; Holden, William M.; Venkatesh, Amrit Chemistry of Materials, Vol. 30, Issue 18 https://doi.org/10.1021/acs.chemmater.8b02590	journal	August 2018
Sulfur $K β$ x-ray emission spectra and electronic structures of some metal sulfides Sugiura, Chikara; Gohshi, Yohichi; Suzuki, Isao Physical Review B, Vol. 10, Issue 2 https://doi.org/10.1103/physrevb.10.338	journal	July 1974
A rule for chemical shifts of X-ray absorption edges Agarwal, B. K.; Verma, L. P. Journal of Physics C: Solid State Physics, Vol. 3, Issue 3 https://doi.org/10.1088/0022-3719/3/3/007	journal	March 1970
X-ray fluorescent spectrometer with linear position sensitive detector Dolgih, V. E.; Cherkashenko, V. M.; Kurmaev, E. Z. Nuclear Instruments and Methods in Physics Research, Vol. 224, Issue 1-2 https://doi.org/10.1016/0167-5087(84)90455-1	journal	July 1984
XANES investigation of the role of cerium compounds as corrosion inhibitors for aluminum Davenport, A. J.; Isaacs, H. S.; Kendig, M. W. Corrosion Science, Vol. 32, Issue 5-6 https://doi.org/10.1016/0010-938x(91)90113-4	journal	January 1991
Sulfur Speciation in Biochars by Very High Resolution Benchtop Kα X-ray Emission Spectroscopy Holden, William M.; Seidler, Gerald T.; Cheah, Singfoong The Journal of Physical Chemistry A, Vol. 122, Issue 23 https://doi.org/10.1021/acs.jpca.8b02816	journal	May 2018
Determination of the As(III)/As(V) Ratio in Soil by X-ray Absorption Near-edge Structure (XANES) and Its Application to the Arsenic Distribution between Soil and Water Takahashi, Yoshio; Ohtaku, Naoya; Mitsunobu, Satoshi Analytical Sciences, Vol. 19, Issue 6 https://doi.org/10.2116/analsci.19.891	journal	January 2003
High energy-resolution x-ray spectroscopy at ultra-high dilution with spherically bent crystal analyzers of 0.5 m radius Rovezzi, Mauro; Lapras, Christophe; Manceau, Alain Review of Scientific Instruments, Vol. 88, Issue 1 https://doi.org/10.1063/1.4974100	journal	January 2017
Study of the Capacity Fading Mechanism for Fe-Substituted LiCoO[sub 2] Positive Electrode McLaren, Victoria L.; West, Anthony R.; Tabuchi, Mitsuharu Journal of The Electrochemical Society, Vol. 151, Issue 5 https://doi.org/10.1149/1.1688796	journal	January 2004
X-ray emission spectra and valence state of sulphur atoms of YBa ₂ ((CuO) _1-x (NiS) _x ) ₃ O _{4- delta} Yarmoshenko, Yu M.; Trofimova, V. A.; Dolgih, V. E. Journal of Physics: Condensed Matter, Vol. 7, Issue 1 https://doi.org/10.1088/0953-8984/7/1/018	journal	January 1995
Variable Rowland radius laboratory vacuum surface-sensitive x-ray absorption fine structure spectrometer Yuryev, Yu. N.; Lee, Hwack-Joo; Park, Hyun-Min Review of Scientific Instruments, Vol. 78, Issue 2 https://doi.org/10.1063/1.2669591	journal	February 2007
Comparison of EXAFS foil spectra from around the world Kelly, S. D.; Bare, S. R.; Greenlay, N. Journal of Physics: Conference Series, Vol. 190 https://doi.org/10.1088/1742-6596/190/1/012032	journal	November 2009
Arsenic Speciation and Phytoavailability in Contaminated Soils Using a Sequential Extraction Procedure and XANES Spectroscopy Niazi, Nabeel K.; Singh, Balwant; Shah, Pushan Environmental Science & Technology, Vol. 45, Issue 17 https://doi.org/10.1021/es201677z	journal	September 2011
Predicting XAFS scattering path cumulants and XAFS spectra for metals (Cu, Ni, Fe, Ti, Au) using molecular dynamics simulations Karolewski, M. A.; Cavell, R. G.; Gordon, R. A. Journal of Synchrotron Radiation, Vol. 20, Issue 4 https://doi.org/10.1107/s0909049513010303	journal	May 2013
4-1: Invited Paper: Role of Phosphorus Oxidation in Controlling the Luminescent Properties of Indium Phosphide Quantum Dots Cossairt, Brandi M.; Stein, Jennifer L.; Holden, William M. SID Symposium Digest of Technical Papers, Vol. 49, Issue 1 https://doi.org/10.1002/sdtp.12481	journal	May 2018
Local Structure and L ₁ - and L ₃ -Edge X-ray Absorption Near Edge Structure of Late Lanthanide Elements (Ho, Er, Yb) in Their Complex Oxides Asakura, Hiroyuki; Shishido, Tetsuya; Teramura, Kentaro The Journal of Physical Chemistry C, Vol. 119, Issue 15 https://doi.org/10.1021/acs.jpcc.5b01138	journal	April 2015
A novel von Hamos spectrometer for efficient X-ray emission spectroscopy in the laboratory Anklamm, Lars; Schlesiger, Christopher; Malzer, Wolfgang Review of Scientific Instruments, Vol. 85, Issue 5 https://doi.org/10.1063/1.4875986	journal	May 2014
Laboratory x‐ray spectrometer for EXAFS and XANES measurements Williams, Arthur Review of Scientific Instruments, Vol. 54, Issue 2 https://doi.org/10.1063/1.1137344	journal	February 1983
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott The Journal of Physical Chemistry Letters, Vol. 4, Issue 19 https://doi.org/10.1021/jz401763d	journal	September 2013
Mesoporous LaMnO3+δ perovskite from spray−pyrolysis with superior performance for oxygen reduction reaction and Zn−air battery Kuai, Long; Kan, Erjie; Cao, Wei Nano Energy, Vol. 43 https://doi.org/10.1016/j.nanoen.2017.11.018	journal	January 2018
A wide-range, single-axis, vacuum two-crystal spectrometer for fluorescent X-ray analysis Gohshi, Yohichi; Hukao, Yoshiro; Hori, Kohei Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 27, Issue 3 https://doi.org/10.1016/0584-8547(72)80016-8	journal	March 1972
Development of a laboratory EXAFS facility Knapp, G. S.; Chen, Haydn; Klippert, T. E. Review of Scientific Instruments, Vol. 49, Issue 12 https://doi.org/10.1063/1.1135340	journal	December 1978
XANES study on the valence transitions in cerium oxide nanoparticles Zhang, Jing; Wu, Ziyu; Liu, Tao Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/s0909049500016022	journal	March 2001
Speciation using X-ray absorption fine structure (XAFS) Gaur, A.; Shrivastava, B. D. Review Journal of Chemistry, Vol. 5, Issue 4 https://doi.org/10.1134/s2079978015040032	journal	October 2015
Synthesis, Cation Distribution, and Electrochemical Properties of Fe-Substituted Li[sub 2]MnO[sub 3] as a Novel 4 V Positive Electrode Material Tabuchi, Mitsuharu; Nakashima, Akiko; Shigemura, Hikari Journal of The Electrochemical Society, Vol. 149, Issue 5 https://doi.org/10.1149/1.1462791	journal	January 2002
X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor Lancaster, K. M.; Roemelt, M.; Ettenhuber, P. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1206445	journal	November 2011
Laboratory-based micro-X-ray fluorescence setup using a von Hamos crystal spectrometer and a focused beam X-ray tube Kayser, Y.; Błachucki, W.; Dousse, J. -Cl. Review of Scientific Instruments, Vol. 85, Issue 4 https://doi.org/10.1063/1.4869340	journal	April 2014
Determination of Hexavalent Chromium Fractions in Plastics Using Laboratory-Based, High-Resolution X-ray Emission Spectroscopy Jahrman, Evan P.; Seidler, Gerald T.; Sieber, John R. Analytical Chemistry, Vol. 90, Issue 11 https://doi.org/10.1021/acs.analchem.8b00302	journal	April 2018
In Situ XAFS and NMR Study of Rhodium-Catalyzed Dehydrogenation of Dimethylamine Borane Chen, Yongsheng; Fulton, John L.; Linehan, John C. Journal of the American Chemical Society, Vol. 127, Issue 10 https://doi.org/10.1021/ja0437050	journal	March 2005
Johann and Johansson focussing arrangements; Analytical analysis Lu, Kung‐quan; Stern, E. A. Laboratory EXAFS Facilities-1980: University of Washington Workshop, AIP Conference Proceedings https://doi.org/10.1063/1.32243	conference	January 1980
Nitrogenase MoFe-Protein at 1.16 A Resolution: A Central Ligand in the FeMo-Cofactor Einsle, O. Science, Vol. 297, Issue 5587 https://doi.org/10.1126/science.1073877	journal	September 2002
Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex Padamati, Sandeep K.; Angelone, Davide; Draksharapu, Apparao Journal of the American Chemical Society, Vol. 139, Issue 25 https://doi.org/10.1021/jacs.7b04158	journal	June 2017
Redox-Active vs Redox-Innocent: A Comparison of Uranium Complexes Containing Diamine Ligands Pattenaude, Scott A.; Mullane, Kimberly C.; Schelter, Eric J. Inorganic Chemistry, Vol. 57, Issue 11 https://doi.org/10.1021/acs.inorgchem.8b00663	journal	May 2018
A laboratory EXAFS spectrometer in transmission dispersive mode Lecante, P.; Jaud, J.; Mosset, A. Review of Scientific Instruments, Vol. 65, Issue 4 https://doi.org/10.1063/1.1144909	journal	April 1994
Synthesis and Structure of (Ph ₄ P) ₂ MCl ₆ (M = Ti, Zr, Hf, Th, U, Np, Pu) Minasian, Stefan G.; Boland, Kevin S.; Feller, Russell K. Inorganic Chemistry, Vol. 51, Issue 10 https://doi.org/10.1021/ic300179d	journal	May 2012
Aminophosphines as Versatile Precursors for the Synthesis of Metal Phosphide Nanocrystals Mundy, M. Elizabeth; Ung, David; Lai, Nathan L. Chemistry of Materials, Vol. 30, Issue 15 https://doi.org/10.1021/acs.chemmater.8b02206	journal	July 2018
Comparison of XANES Analyses and Extractions To Determine Chromium Speciation in Contaminated Soils Szulczewski, Melanie D.; Helmke, Philip A.; Bleam, William F. Environmental Science & Technology, Vol. 31, Issue 10 https://doi.org/10.1021/es9701772	journal	October 1997
Fluorescence detection of exafs: Sensitivity enhancement for dilute species and thin films Jaklevic, J.; Kirby, J. A.; Klein, M. P. Solid State Communications, Vol. 23, Issue 9 https://doi.org/10.1016/0038-1098(77)90548-8	journal	September 1977
Arsenic in the marine and aquatic environments: Analysis, occurrence, and significance Penrose, W. R.; Woolson, E. A. C R C Critical Reviews in Environmental Control, Vol. 4, Issue 1-4 https://doi.org/10.1080/10643387409381621	journal	January 1974
XAFS spectroscopy by an X-ray tube based spectrometer using a novel type of HOPG mosaic crystal and optimized image processing Schlesiger, C.; Anklamm, L.; Stiel, H. Journal of Analytical Atomic Spectrometry, Vol. 30, Issue 5 https://doi.org/10.1039/c4ja00303a	journal	January 2015
Benchtop Nonresonant X-ray Emission Spectroscopy: Coming Soon to Laboratories and XAS Beamlines Near You? Mortensen, Devon R.; Seidler, Gerald T.; Ditter, Alexander S. Journal of Physics: Conference Series, Vol. 712 https://doi.org/10.1088/1742-6596/712/1/012036	journal	May 2016
Versatile curved crystal spectrometer for laboratory extended x‐ray absorption fine structure measurements Thulke, W.; Haensel, R.; Rabe, P. Review of Scientific Instruments, Vol. 54, Issue 3 https://doi.org/10.1063/1.1137383	journal	March 1983
In Situ high pressure, high temperature XAFS studies of Cu-based catalysts during methanol synthesis Clausen, Bjerne S.; Topsøe, Henrik Catalysis Today, Vol. 9, Issue 1-2 https://doi.org/10.1016/0920-5861(91)85023-2	journal	March 1991
Chemical effects in the Kβ X-ray emission spectra of sulfur Kavčič, M.; Dousse, J. -Cl.; Szlachetko, J. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 260, Issue 2 https://doi.org/10.1016/j.nimb.2007.04.290	journal	July 2007
X-ray emission spectra of YSr2Cu3O7−δ containing sulphate and phosphate groups Yarmoshenko, Yu. M.; Trofimova, V. A.; Kurmaev, E. Z. Physica C: Superconductivity, Vol. 224, Issue 3-4 https://doi.org/10.1016/0921-4534(94)90268-2	journal	May 1994
Scanning X-ray spectrometer for high-resolution Compton profile measurements at ESRF Suortti, P.; Buslaps, T.; Fajardo, P. Journal of Synchrotron Radiation, Vol. 6, Issue 2 https://doi.org/10.1107/s0909049599000291	journal	March 1999
Laboratory-scale X-ray absorption spectroscopy approach for actinide research: Experiment at the uranium L3-edge Bès, R.; Ahopelto, T.; Honkanen, A. -P. Journal of Nuclear Materials, Vol. 507 https://doi.org/10.1016/j.jnucmat.2018.04.034	journal	August 2018
Tetrahalide Complexes of the [U(NR) ₂ ] ²⁺ Ion: Synthesis, Theory, and Chlorine K-Edge X-ray Absorption Spectroscopy Spencer, Liam P.; Yang, Ping; Minasian, Stefan G. Journal of the American Chemical Society, Vol. 135, Issue 6 https://doi.org/10.1021/ja310575j	journal	January 2013
Coordination Chemistry of Trivalent Lanthanide and Actinide Ions in Dilute and Concentrated Chloride Solutions Allen, P. G.; Bucher, J. J.; Shuh, D. K. Inorganic Chemistry, Vol. 39, Issue 3 https://doi.org/10.1021/ic9905953	journal	February 2000
Chemical Effects in High-Resolution Nickel K.ALPHA. X-Ray Fluorescence Spectra Kawai, Jun; Ohta, Michiharu; Konishi, Tokuzo Analytical Sciences, Vol. 21, Issue 7 https://doi.org/10.2116/analsci.21.865	journal	January 2005
Characterization of U/Pu particles originating from the nuclear weapon accidents at Palomares, Spain, 1966 and Thule, Greenland, 1968 Lind, O. C.; Salbu, B.; Janssens, K. Science of The Total Environment, Vol. 376, Issue 1-3 https://doi.org/10.1016/j.scitotenv.2006.11.050	journal	April 2007
Direct Detection of Oxygen Ligation to the Mn4Ca Cluster of Photosystem II by X-ray Emission Spectroscopy Pushkar, Yulia; Long, Xi; Glatzel, Pieter Angewandte Chemie International Edition, Vol. 49, Issue 4 https://doi.org/10.1002/anie.200905366	journal	December 2009
Observation of iron spin-states using tabletop x-ray emission spectroscopy and microcalorimeter sensors Joe, Y. I.; O’Neil, G. C.; Miaja-Avila, L. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 49, Issue 2 https://doi.org/10.1088/0953-4075/49/2/024003	journal	December 2015
Vacuum formed temporary spherically and toroidally bent crystal analyzers for x-ray absorption and x-ray emission spectroscopy Jahrman, Evan P.; Holden, William M.; Ditter, Alexander S. Review of Scientific Instruments, Vol. 90, Issue 1 https://doi.org/10.1063/1.5057231	journal	January 2019
X‐ray filter assembly for fluorescence measurements of x‐ray absorption fine structure Stern, Edward A.; Heald, Steve M. Review of Scientific Instruments, Vol. 50, Issue 12 https://doi.org/10.1063/1.1135763	journal	December 1979
Structure and Electrochemical Properties of LiFe[sub x]Mn[sub 2−x]O[sub 4] (0≤x≤0.5) Spinel as 5 V Electrode Material for Lithium Batteries Shigemura, H.; Sakaebe, H.; Kageyama, H. Journal of The Electrochemical Society, Vol. 148, Issue 7 https://doi.org/10.1149/1.1377593	journal	January 2001
High average power, highly brilliant laser-produced plasma source for soft X-ray spectroscopy Mantouvalou, Ioanna; Witte, Katharina; Grötzsch, Daniel Review of Scientific Instruments, Vol. 86, Issue 3 https://doi.org/10.1063/1.4916193	journal	March 2015
Methods and Protocols for Electrochemical Energy Storage Materials Research Talaie, Elahe; Bonnick, Patrick; Sun, Xiaoqi Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b02726	journal	November 2016
A Modern Laboratory XAFS Cookbook Seidler, Gt; Mortensen, Dr; Ditter, As Journal of Physics: Conference Series, Vol. 712 https://doi.org/10.1088/1742-6596/712/1/012015	journal	May 2016
XANES Evidence for Oxidation of Cr(III) to Cr(VI) by Mn-Oxides in a Lateritic Regolith Developed on Serpentinized Ultramafic Rocks of New Caledonia Fandeur, Dik; Juillot, Farid; Morin, Guillaume Environmental Science & Technology, Vol. 43, Issue 19 https://doi.org/10.1021/es900498r	journal	October 2009
An inelastic X-ray scattering spectrometer at LNLS Tirao, G.; Stutz, G.; Cusatis, C. Journal of Synchrotron Radiation, Vol. 11, Issue 4 https://doi.org/10.1107/s0909049504010386	journal	June 2004
High-resolution von Hamos crystal X-ray spectrometer Hoszowska, J.; Dousse, J. -Cl.; Kern, J. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 376, Issue 1 https://doi.org/10.1016/0168-9002(96)00262-8	journal	June 1996
Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of the Nature of a Bound Ligand Pollock, Christopher J.; DeBeer, Serena Journal of the American Chemical Society, Vol. 133, Issue 14 https://doi.org/10.1021/ja200560z	journal	April 2011
Thermal treatment of simulant plutonium contaminated materials from the Sellafield site by vitrification in a blast-furnace slag Hyatt, N. C.; Schwarz, R. R.; Bingham, P. A. Journal of Nuclear Materials, Vol. 444, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2013.08.019	journal	January 2014
Possibility of sulphur-oxygen substitution in YBa2Cu3O6+xSy analyzed by means of X-ray emission spectroscopy Yarmoshenko, Yu. M.; Trofimova, V. A.; Elokhina, L. V. Journal of Physics and Chemistry of Solids, Vol. 54, Issue 10 https://doi.org/10.1016/0022-3697(93)90169-r	journal	October 1993
High-resolution large-acceptance analyzer for x-ray fluorescence and Raman spectroscopy Bergmann, Uwe; Cramer, Stephen P. SPIE's International Symposium on Optical Science, Engineering, and Instrumentation, SPIE Proceedings https://doi.org/10.1117/12.332507	conference	December 1998
Spin crossover and iron-rich silicate melt in the Earth’s deep mantle Nomura, Ryuichi; Ozawa, Haruka; Tateno, Shigehiko Nature, Vol. 473, Issue 7346 https://doi.org/10.1038/nature09940	journal	April 2011
Direct Detection of Oxygen Ligation to the Mn4Ca Cluster of Photosystem II by X-ray Emission Spectroscopy Pushkar, Yulia; Long, Xi; Glatzel, Pieter Angewandte Chemie, Vol. 122, Issue 4 https://doi.org/10.1002/ange.200905366	journal	December 2009
Fluorescence detection of EXAFS: Sensitivity enhancement for dilute species and thin films Jaklevic, J.; Kirby, J. A.; Klein, M. P. Solid State Communications, Vol. 88, Issue 11-12 https://doi.org/10.1016/0038-1098(93)90303-5	journal	December 1993
Rapid mapping of lithiation dynamics in transition metal oxide particles with operando X-ray absorption spectroscopy Nowack, Lea; Grolimund, Daniel; Samson, Vallerie ETH Zurich https://doi.org/10.3929/ethz-a-010820347	text	January 2016
Rapid mapping of lithiation dynamics in transition metal oxide particles with operando X-ray absorption spectroscopy Marone, Federica; Grolimund, Daniel; Wood, Vanessa ETH Zurich https://doi.org/10.3929/ethz-b-000114146	text	January 2016
First Structural Characterization of a Protactinium(V) Single Oxo Bond in Aqueous Media. Le Naour, Claire; Trubert, Didier; Di Giandomenico, Maria V. ChemInform, Vol. 37, Issue 9 https://doi.org/10.1002/chin.200609014	journal	February 2006
High energy-resolution x-ray spectroscopy at ultra-high dilution with spherically bent crystal analyzers of 0.5 m radius Rovezzi, Mauro; Lapras, Christophe; Manceau, Alain arXiv https://doi.org/10.48550/arxiv.1609.08894	text	January 2016
A Compact Dispersive Refocusing Rowland Circle X-ray Emission Spectrometer for Laboratory, Synchrotron, and XFEL Applications Holden, William M.; Hoidn, Oliver R.; Ditter, Alexander S. arXiv https://doi.org/10.48550/arxiv.1704.07496	text	January 2017
Benchmark Results and Theoretical Treatments for Valence-to-Core X-ray Emission Spectroscopy in Transition Metal Compounds Mortensen, D. R.; Seidler, G. T.; Kas, J. J. arXiv https://doi.org/10.48550/arxiv.1706.09054	text	January 2017
Rapid Mapping of Lithiation Dynamics in Transition Metal Oxide Particles with Operando X-ray Absorption Spectroscopy Nowack, Lea; Grolimund, Daniel; Samson, Vallerie Nature Publishing Group https://doi.org/10.5167/uzh-128248	text	January 2016

Cited By (6)

Interface Engineering V ₂ O ₅ Nanofibers for High‐Energy and Durable Supercapacitors Bi, Wenchao; Wang, Jichao; Jahrman, Evan P. Small, Vol. 15, Issue 31 https://doi.org/10.1002/smll.201901747	journal	June 2019
A wavelength‐dispersive X‐ray spectrometer for in/ex situ resonant inelastic X‐ray scattering studies Mei, Bingbao; Gu, Songqi; Du, Xianlong X-Ray Spectrometry, Vol. 49, Issue 1 https://doi.org/10.1002/xrs.3132	journal	April 2019
Laboratory EXAFS determined structure of the stable complexes in the ternary Ni( ii )–EDTA–CN ⁻ system Németh, Zoltán; Bajnóczi, Éva G.; Csilla, Bogdán Physical Chemistry Chemical Physics, Vol. 21, Issue 18 https://doi.org/10.1039/c9cp00982e	journal	January 2019
In-house setup for laboratory-based x-ray absorption fine structure spectroscopy measurements Zeeshan, F.; Hoszowska, J.; Loperetti-Tornay, L. Review of Scientific Instruments, Vol. 90, Issue 7 https://doi.org/10.1063/1.5094873	journal	July 2019
Laboratory-Based X-ray Absorption Spectroscopy on a Working Pouch Cell Battery at Industrially-Relevant Charging Rates Jahrman, Evan P.; Pellerin, Lisa A.; Ditter, Alexander S. Journal of The Electrochemical Society, Vol. 166, Issue 12 https://doi.org/10.1149/2.0721912jes	journal	January 2019
A Feasibility Investigation of Laboratory Based X-ray Absorption Spectroscopy in Support of Nuclear Waste Management Mottram, L. M.; Wilkins, M. C. Dixon; Blackburn, L. R. MRS Advances, Vol. 5, Issue 1-2 https://doi.org/10.1557/adv.2020.44	journal	January 2020

Similar Records

Development of synchrotron x-ray micro-spectroscopic techniques and application to problems in low temperature geochemistry. Progress report

Technical Report · Fri Oct 01 00:00:00 EDT 1993 · OSTI ID:1542825

Combined in situ X-ray absorption and diffuse reflectance infrared spectroscopy: An attractive tool for catalytic investigations

Journal Article · · Nuclear Instruments and Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and Associated Equipment · OSTI ID:1542825

Marinkovic, N. S.; Wang, Q.; Barrio, L.; +4 more

Combined in Situ X-ray absorption and diffuse reflectance infraredspectroscopy: An attractive tool for catalytic investigations

Journal Article · Wed Nov 24 00:00:00 EST 2010 · Nuclear Instruments and Methods in Physics Research A · OSTI ID:1542825

Marinkovic, N S; Ehrlich, S; Wang, Q; +2 more

Related Subjects

47 OTHER INSTRUMENTATION
Inorganic and Physical Chemistry
XAS
XAFS
XES

Title: An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research

Citation Formats

References (98)

Cited By (6)

Similar Records

Related Subjects