skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: “Patterning with loops” to dynamically reconfigure polymer gels

Abstract

Modeling shape changes in gels that arise from the thermally or mechanically induced unfolding (and refolding) of embedded loops.

Authors:
 [1];  [1]; ORCiD logo [1]
  1. Chemical Engineering Department; University of Pittsburgh; Pittsburgh; USA
Publication Date:
Research Org.:
Univ. of Pittsburgh, PA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1540082
DOE Contract Number:  
FG02-90ER45438
Resource Type:
Journal Article
Journal Name:
Soft Matter
Additional Journal Information:
Journal Volume: 14; Journal Issue: 17; Journal ID: ISSN 1744-683X
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Materials Science; Physics; Polymer Science

Citation Formats

Biswas, Santidan, Yashin, Victor V., and Balazs, Anna C. “Patterning with loops” to dynamically reconfigure polymer gels. United States: N. p., 2018. Web. doi:10.1039/c8sm00270c.
Biswas, Santidan, Yashin, Victor V., & Balazs, Anna C. “Patterning with loops” to dynamically reconfigure polymer gels. United States. doi:10.1039/c8sm00270c.
Biswas, Santidan, Yashin, Victor V., and Balazs, Anna C. Mon . "“Patterning with loops” to dynamically reconfigure polymer gels". United States. doi:10.1039/c8sm00270c.
@article{osti_1540082,
title = {“Patterning with loops” to dynamically reconfigure polymer gels},
author = {Biswas, Santidan and Yashin, Victor V. and Balazs, Anna C.},
abstractNote = {Modeling shape changes in gels that arise from the thermally or mechanically induced unfolding (and refolding) of embedded loops.},
doi = {10.1039/c8sm00270c},
journal = {Soft Matter},
issn = {1744-683X},
number = 17,
volume = 14,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Dynamic force sensing of filamin revealed in single-molecule experiments
journal, November 2012

  • Rognoni, L.; Stigler, J.; Pelz, B.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 48
  • DOI: 10.1073/pnas.1211274109

Semibatch monomer addition as a general method to tune and enhance the mechanics of polymer networks via loop-defect control
journal, April 2017

  • Gu, Yuwei; Kawamoto, Ken; Zhong, Mingjiang
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 19
  • DOI: 10.1073/pnas.1620985114

Quantifying the impact of molecular defects on polymer network elasticity
journal, September 2016


Modular Domain Structure:  A Biomimetic Strategy for Advanced Polymeric Materials
journal, February 2004

  • Guan, Zhibin; Roland, Jason T.; Bai, Jane Z.
  • Journal of the American Chemical Society, Vol. 126, Issue 7
  • DOI: 10.1021/ja039127p

Direct correlation of single-molecule properties with bulk mechanical performance for the biomimetic design of polymers
journal, September 2014

  • Chung, Jaeyoon; Kushner, Aaron M.; Weisman, Adam C.
  • Nature Materials, Vol. 13, Issue 11
  • DOI: 10.1038/nmat4090

Softening of bulk modulus and negative Poisson’s ratio near the volume phase transition of polymer gels
journal, March 1991

  • Hirotsu, Shunsuke
  • The Journal of Chemical Physics, Vol. 94, Issue 5
  • DOI: 10.1063/1.460672

Chemomechanical-force-induced folding–unfolding directly controls distinct fluorescence dual-color switching
journal, January 2017

  • Chen, Jian; Ziegler, Adam W.; Zhao, Baoming
  • Chemical Communications, Vol. 53, Issue 36
  • DOI: 10.1039/C7CC01643C

DNA sequence–directed shape change of photopatterned hydrogels via high-degree swelling
journal, September 2017


Models for the specific adhesion of cells to cells
journal, May 1978


Modeling the response of dual cross-linked nanoparticle networks to mechanical deformation
journal, January 2013

  • Iyer, Balaji V. S.; Salib, Isaac G.; Yashin, Victor V.
  • Soft Matter, Vol. 9, Issue 1
  • DOI: 10.1039/C2SM27121D

Strain recovery and self-healing in dual cross-linked nanoparticle networks
journal, January 2013

  • Iyer, Balaji V. S.; Yashin, Victor V.; Kowalewski, Tomasz
  • Polymer Chemistry, Vol. 4, Issue 18
  • DOI: 10.1039/c3py00075c

Modeling polymer grafted nanoparticle networks reinforced by high-strength chains
journal, January 2014

  • Hamer, Matthew J.; Iyer, Balaji V. S.; Yashin, Victor V.
  • Soft Matter, Vol. 10, Issue 9
  • DOI: 10.1039/C3SM52300D

Designing Mechanomutable Composites: Reconfiguring the Structure of Nanoparticle Networks through Mechanical Deformation
journal, July 2014

  • Hamer, Matthew J.; Iyer, Balaji V. S.; Yashin, Victor V.
  • Nano Letters, Vol. 14, Issue 8
  • DOI: 10.1021/nl501871e

Ductility, toughness and strain recovery in self-healing dual cross-linked nanoparticle networks studied by computer simulations
journal, January 2015


Using Torsion for Controllable Reconfiguration of Binary Nanoparticle Networks
journal, February 2017


Pattern Formation and Shape Changes in Self-Oscillating Polymer Gels
journal, November 2006


Theoretical and computational modeling of self-oscillating polymer gels
journal, March 2007

  • Yashin, Victor V.; Balazs, Anna C.
  • The Journal of Chemical Physics, Vol. 126, Issue 12
  • DOI: 10.1063/1.2672951

Three-dimensional model for chemoresponsive polymer gels undergoing the Belousov-Zhabotinsky reaction
journal, October 2008


A constitutive model for compressible elastomeric solids
journal, September 1996


Modeling autonomously oscillating chemo-responsive gels
journal, January 2010


Mechano-chemical oscillations and waves in reactive gels
journal, May 2012


Global signaling of localized impact in chemo-responsive gels
journal, January 2009

  • Kuksenok, Olga; Yashin, Victor V.; Balazs, Anna C.
  • Soft Matter, Vol. 5, Issue 9
  • DOI: 10.1039/b821838b

Controlling chemical oscillations in heterogeneous Belousov-Zhabotinsky gels via mechanical strain
journal, April 2009


Computational Design of Active, Self-Reinforcing Gels
journal, May 2010

  • Yashin, Victor V.; Kuksenok, Olga; Balazs, Anna C.
  • The Journal of Physical Chemistry B, Vol. 114, Issue 19
  • DOI: 10.1021/jp101009h

Mechanical Resuscitation of Chemical Oscillations in Belousov-Zhabotinsky Gels
journal, March 2012

  • Chen, Irene Chou; Kuksenok, Olga; Yashin, Victor V.
  • Advanced Functional Materials, Vol. 22, Issue 12
  • DOI: 10.1002/adfm.201103036

UV patternable thin film chemistry for shape and functionally versatile self-oscillating gels
journal, January 2013

  • Yuan, Peixi; Kuksenok, Olga; Gross, Dustin E.
  • Soft Matter, Vol. 9, Issue 4
  • DOI: 10.1039/C2SM27100A

Modeling the Photoinduced Reconfiguration and Directed Motion of Polymer Gels
journal, July 2013

  • Kuksenok, Olga; Balazs, Anna C.
  • Advanced Functional Materials, Vol. 23, Issue 36
  • DOI: 10.1002/adfm.201203876

Designing Dual-functionalized Gels for Self-reconfiguration and Autonomous Motion
journal, April 2015

  • Kuksenok, Olga; Balazs, Anna C.
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep09569

Stimuli-responsive behavior of composites integrating thermo-responsive gels with photo-responsive fibers
journal, January 2016

  • Kuksenok, Olga; Balazs, Anna C.
  • Materials Horizons, Vol. 3, Issue 1
  • DOI: 10.1039/C5MH00212E

Synthetic homeostatic materials with chemo-mechano-chemical self-regulation
journal, July 2012

  • He, Ximin; Aizenberg, Michael; Kuksenok, Olga
  • Nature, Vol. 487, Issue 7406, p. 214-218
  • DOI: 10.1038/nature11223

Kinetics of solvent absorption and permeation through a highly swellable elastomeric network: Solvent Absorption and Permeation
journal, December 2002

  • Barrière, Benoît; Leibler, Ludwik
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 41, Issue 2
  • DOI: 10.1002/polb.10341

Gel Dynamics
journal, May 2009


Stackable, Covalently Fused Gels: Repair and Composite Formation
journal, January 2015

  • Yong, Xin; Simakova, Antonina; Averick, Saadyah
  • Macromolecules, Vol. 48, Issue 4
  • DOI: 10.1021/ma502367f

Combining ATRP and FRP Gels: Soft Gluing of Polymeric Materials for the Fabrication of Stackable Gels
journal, May 2017

  • Beziau, Antoine; de Menezes, Rafael; Biswas, Santidan
  • Polymers, Vol. 9, Issue 12
  • DOI: 10.3390/polym9060186

Analysis of Bi-Metal Thermostats
journal, January 1925


Shape-Morphing Materials from Stimuli-Responsive Hydrogel Hybrids
journal, January 2017


Biomimetic 4D printing
journal, January 2016

  • Sydney Gladman, A.; Matsumoto, Elisabetta A.; Nuzzo, Ralph G.
  • Nature Materials, Vol. 15, Issue 4
  • DOI: 10.1038/nmat4544

Instabilities and Pattern Transformation in Periodic, Porous Elastoplastic Solid Coatings
journal, December 2008

  • Singamaneni, Srikanth; Bertoldi, Katia; Chang, Sehoon
  • ACS Applied Materials & Interfaces, Vol. 1, Issue 1
  • DOI: 10.1021/am800078f

Buckling into single-handed chiral structures from pH-sensitive hydrogel membranes
journal, June 2016