Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Supported cluster catalysts synthesized to be small, simple, selective, and stable

Journal Article · · Faraday Discussions
DOI:https://doi.org/10.1039/c8fd00076j· OSTI ID:1540050
 [1];  [1];  [2];  [3];  [3];  [2]
  1. Department of Chemical Engineering; University of California; Davis; USA; Department of Materials Science and Engineering
  2. Department of Chemical Engineering; University of California; Davis; USA
  3. Key Laboratory of Applied Chemistry of Zhejiang Province; Department of Chemistry; Zhejiang University; Hangzhou 310028; China

Molecular metal complexes on supports have drawn wide attention as catalysts offering new properties and opportunities for precise synthesis to make uniform catalytic species that can be understood in depth.

Research Organization:
Univ. of California, Davis, CA (United States); Univ. of Minnesota, Minneapolis, MN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-04ER15513; SC0012702
OSTI ID:
1540050
Journal Information:
Faraday Discussions, Vol. 208; ISSN 1359-6640
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (46)

Atomically dispersed supported metal catalysts: perspectives and suggestions for future research journal January 2017
Molecular Metal Catalysts on Supports: Organometallic Chemistry Meets Surface Science journal July 2014
Genesis of a Cerium Oxide Supported Gold Catalyst for CO Oxidation: Transformation of Mononuclear Gold Complexes into Clusters as Characterized by X-Ray Absorption Spectroscopy journal January 2009
Small Gold Clusters Formed in Solution Give Reaction Turnover Numbers of 107 at Room Temperature journal December 2012
Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation journal November 2009
Stable Rhodium Pair Sites on MgO: Influence of Ligands and Rhodium Nuclearity on Catalysis of Ethylene Hydrogenation and H–D Exchange in the Reaction of H 2 with D 2 journal December 2017
Rhodium pair-sites on magnesium oxide: Synthesis, characterization, and catalysis of ethylene hydrogenation journal June 2016
Surface-Mediated Synthesis of Dimeric Rhodium Catalysts on MgO: Tracking Changes in the Nuclearity and Ligand Environment of the Catalytically Active Sites by X-ray Absorption and Infrared Spectroscopies journal December 2012
Tuning Catalytic Selectivity: Zeolite- and Magnesium Oxide-Supported Molecular Rhodium Catalysts for Hydrogenation of 1,3-Butadiene journal September 2012
Metal-assisted hydroformylation on a SiO2-attached rhodium dimer. In situ EXAFS and FT-IR observations of the dynamic behaviors of the dimer site journal December 1990
Stable iridium dinuclear heterogeneous catalysts supported on metal-oxide substrate for solar water oxidation journal March 2018
Conversion of Methane to Methanol with a Bent Mono(μ-oxo)dinickel Anchored on the Internal Surfaces of Micropores journal July 2014
Selective anaerobic oxidation of methane enables direct synthesis of methanol journal May 2017
Bisdiphenylphosphinomethane in dinuclear complexes journal May 1988
Compartmental ligands: routes to homo- and hetero-dinuclear complexes journal January 1979
The crystal and molecular structures of dichromium tetraacetate dihydrate and dirhodium tetraacetate dihydrate journal August 1971
Hexarhodium Clusters in NaY Zeolite:  Characterization by Infrared and Extended X-ray Absorption Fine Structure Spectroscopies journal December 1997
MgO-Supported Rh 6 and Ir 6 :  Structural Characterization during the Catalysis of Ethene Hydrogenation journal June 2003
Role of Cluster Size in Catalysis:  Spectroscopic Investigation of γ-Al 2 O 3 -Supported Ir 4 and Ir 6 during Ethene Hydrogenation journal June 2003
Synthesis and Structure of Tetrairidium Clusters on TiO 2 Powder:  Characterization by Infrared and Extended X-ray Absorption Fine Structure Spectroscopies journal February 2002
Dialing in single-site reactivity of a supported calixarene-protected tetrairidium cluster catalyst journal January 2017
Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts journal March 2018
Atomic Resolution of the Structure of a Metal-Support Interface: Triosmium Clusters on MgO(110) journal November 2010
Ir 6 Clusters Compartmentalized in the Supercages of Zeolite NaY: Direct Imaging of a Catalyst with Aberration-Corrected Scanning Transmission Electron Microscopy journal October 2011
Real-Time Characterization of Formation and Breakup of Iridium Clusters in Highly Dealuminated Zeolite Y journal August 2008
Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts journal March 2016
Atomically Resolved Site-Isolated Catalyst on MgO: Mononuclear Osmium Dicarbonyls formed from Os 3 (CO) 12 journal July 2012
Organometallic chemistry on the basic magnesium oxide surface: formation of [HIr4(CO)11]-, [Ir6(CO)15]2-, and [Ir8(CO)22]2- journal June 1992
Hydrogen Activation and Metal Hydride Formation Trigger Cluster Formation from Supported Iridium Complexes journal March 2012
Dynamic Structural Changes in a Molecular Zeolite-Supported Iridium Catalyst for Ethene Hydrogenation journal November 2009
Zeolite-Supported Rhodium Complexes and Clusters: Switching Catalytic Selectivity by Controlling Structures of Essentially Molecular Species journal April 2011
Observation of ligand effects during alkene hydrogenation catalysed by supported metal clusters journal February 2002
Catalysis by Oxide-Supported Clusters of Iridium and Rhodium:  Hydrogenation of Ethene, Propene, and Toluene journal February 2006
Water oxidation surface mechanisms replicated by a totally inorganic tetraruthenium-oxo molecular complex journal March 2013
Structure, properties and reactivity of polyoxometalates: a theoretical perspective journal January 2012
Catalytic Consequences of Composition in Polyoxometalate Clusters with Keggin Structure journal October 2007
Mechanistic Consequences of Composition in Acid Catalysis by Polyoxometalate Keggin Clusters journal August 2008
Crystalline metal-organic frameworks (MOFs): synthesis, structure and function journal December 2013
Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis journal May 2016
Destruction of chemical warfare agents using metal–organic frameworks journal March 2015
Presence versus Proximity: The Role of Pendant Amines in the Catalytic Hydrolysis of a Nerve Agent Simulant journal January 2018
Tracking Iridium Atoms with Electron Microscopy: First Steps of Metal Nanocluster Formation in One-Dimensional Zeolite Channels journal December 2011
A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores journal May 2017
Sinter-resistant metal nanoparticle catalysts achieved by immobilization within zeolite crystals via seed-directed growth journal July 2018
A “Smart” Catalyst: Sinter-Resistant Supported Iridium Clusters Visualized with Electron Microscopy journal April 2012
Studies of Iridium Nanoparticles Using Density Functional Theory Calculations journal November 2005

Similar Records

Supported cluster catalysts synthesized to be small, simple, selective, and stable
Journal Article · 2018 · Faraday Discussions · OSTI ID:1454302

Supported Metal Pair-Site Catalysts
Journal Article · 2020 · ACS Catalysis · OSTI ID:1777959

Related Subjects