Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium

Friedrich, Jochen; Qiao, Yusen; Maichle-Mössmer, Cäcilia; Schelter, Eric J.; Anwander, Reiner

doi:10.1039/c8dt01878b

Title: Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Dalton Transactions

DOI:https://doi.org/10.1039/c8dt01878b· OSTI ID:1540032

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Institut für Anorganische Chemie; Eberhard Karls Universität Tübingen; 72076 Tübingen; Germany
P. Roy and Diana T. Vagelos Laboratories; Department of Chemistry; University of Pennsylvania; Philadelphia; USA

Combined structural/electrochemical/computational studies of ceric Ce[OSi(OtBu)₃]₄and cerous [Ce{OSi(OtBu)₃}₄][K(2.2.2-crypt)] suggest a redox-modulated coordination switch of a tris(tert-butoxy)siloxy ligand.

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Research Organization:: Univ. of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0017259

OSTI ID:: 1540032

Journal Information:: Dalton Transactions, Vol. 47, Issue 30; ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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